Upscaling transport of Bacillus subtilis endospores and phiX174 coliphages in heterogeneous porous media from the column to the field scale

Author(s):  
Thomas Oudega ◽  
Gerhard Lindner ◽  
Julia Derx ◽  
Andreas Farnleitner ◽  
Regina Sommer ◽  
...  

<p>Groundwater contamination and subsequent transport of viruses and bacteria are a major concern in aquifers worldwide. To ascertain the ability of these aquifers to remove pathogens, tracer tests with microbial indicators are carried out. But because these tests are laborious and require special permission, column tests are often done instead. Unfortunately, results from column tests tend to grossly overestimate removal rates λ when compared to the field scale, which can lead to underestimations of groundwater contamination risks. Scale is an important consideration when examining pathogen transport through porous media, as pathogen removal rarely happens by linear processes. Field tests were carried out with Bacillus subtilis endospores and phiX174 coliphages over a distance of 25 m in an alluvial gravel aquifer in Vienna, Austria. The sandy gravel material from the field site was also used in column tests with the same tracers. Both attachment-detachment and Colloid Filtration Theory were used to model these tests. The results show a big difference in removal between the two scales. A comparison with the literature showed a correlation between the heterogeneity (or preferential flow) of the porous media and the difference in removal rates between the column and field scale.</p>

2017 ◽  
Vol 43 (4) ◽  
pp. 1831
Author(s):  
A. Papafotiou ◽  
C. Schütz ◽  
P. Lehmann ◽  
P. Vontobel ◽  
D. Or ◽  
...  

Infiltration and evaporation are governing processes for water exchange between soil and atmosphere. In addition to atmospheric supply or demand, infiltration and evaporation rates are controlled by the material properties of the subsurface and the interplay between capillary, viscous and gravitational forces. This is commonly modeled with semi-empirical approaches using continuum models, such as the Richards equation for unsaturated flow. However, preferential flow phenomena often occur, limiting or even entirely suspending the applicability of continuum-based models. During infiltration, unstable fingers may form in homogeneous or heterogeneous porous media. On the other hand, the evaporation process may be driven by the hydraulic coupling of materials with different hydraulic functions found in heterogeneous systems. To analyze such preferential flow processes, water distribution was monitored in infiltration and evaporation lab experiments using neutron transmission techniques. Measurements were performed in 2D and 3D, using homogeneous and heterogeneous setups. The experimental findings demonstrate the fingering effect in infiltration and how it is influenced by the presence of fine inclusions in coarse background material. During evaporation processes, the hydraulic coupling effect is found to control the evaporation rate, limiting the modeling of water balances between soil and surface based on surface information alone.


Author(s):  
Z. Kanavas ◽  
F. J. Pérez-Reche ◽  
F. Arns ◽  
V. L. Morales

Abstract This work aims to describe the spatial distribution of flow from characteristics of the underlying pore structure in heterogeneous porous media. Thousands of two-dimensional samples of polydispersed granular media are used to (1) obtain the velocity field via direct numerical simulations, and (2) conceptualize the pore network as a graph in each sample. Analysis of the flow field allows us to distinguish preferential from stagnant flow regions and to quantify how channelized the flow is. Then, the graph’s edges are weighted by geometric attributes of their corresponding pores to find the path of minimum resistance of each sample. Overlap between the preferential flow paths and the predicted minimum resistance path determines the accuracy in individual samples. An evolutionary algorithm is employed to determine the “fittest” weighting scheme (here, the channel’s arc length to pore throat ratio) that maximizes accuracy across the entire dataset while minimizing over-parameterization. Finally, the structural similarity of neighboring edges is analyzed to explain the spatial arrangement of preferential flow within the pore network. We find that connected edges within the preferential flow subnetwork are highly similar, while those within the stagnant flow subnetwork are dissimilar. The contrast in similarity between these regions increases with flow channelization, explaining the structural constraints to local flow. The proposed framework may be used for fast characterization of porous media heterogeneity relative to computationally expensive direct numerical simulations. Article Highlights A quantitative assessment of flow channeling is proposed that distinguishes pore-scale flow fields into preferential and stagnant flow regions. Geometry and topology of the pore network are used to predict the spatial distribution of fast flow paths from structural data alone. Local disorder of pore networks provides structural constraints for flow separation into preferential v stagnant regions and informs on their velocity contrast.


SPE Journal ◽  
2020 ◽  
Vol 25 (04) ◽  
pp. 1697-1710 ◽  
Author(s):  
Yongchao Zeng ◽  
Ridhwan Z. Kamarul Bahrim ◽  
J. A. W. M. Groot ◽  
Sebastien Vincent-Bonnieu ◽  
Jeroen Groenenboom ◽  
...  

Summary This paper advances the understanding of foam transport in heterogeneous porous media for enhanced oil recovery (EOR). Specifically, we investigate the dependence of methane foam rheology on the rock permeability at the laboratory scale and then extend the observations to the field scale with foam modeling techniques and reservoir simulation tools. The oil recovery efficiency of conventional gasflooding, waterflooding, and water-alternating-gas (WAG) processes can be limited by constraints such as bypassing effects (including both viscous fingering and channeling mechanisms) and gravity override. The problem can be more severe if the reservoir is highly fractured or heterogeneously layered in the direction of flow. Foam offers the promise to address the three issues simultaneously by better controlling the mobility of injected fluids. However, limited literature data of foam-flooding experiments were reported using actual reservoir cores at harsh conditions. In this paper, a series of methane (CH4) foam-flooding experiments were conducted in three different actual cores from a proprietary reservoir at an elevated temperature. It is found that foam rheology is significantly correlated with the rock permeability. To quantify the mobility control offered by foam, we calculated the apparent viscosity on the basis of the measured pressure drop at steady state. Interestingly, the apparent viscosity was found to be selectively higher in the high-permeability cores compared with that in the low-permeability zones. We parameterized our system using a texture-implicit-local-equilibrium model (STARS™ simulator, Computer Modelling Group, Calgary, Alberta, Canada) to illustrate the dependence of foam parameters on rock permeability. In addition, we created a two-layered model reservoir using an in-house simulator called modular reservoir simulator (MoReS; Shell Research, Rijswijk, The Netherlands) to elucidate the role of different driving forces for fluid diversion at the field level. We took into consideration the combined effect of gravitational, viscous force, and capillary forces in our simulation. We show that the gravitational forces prevent the gas from sweeping the lower part of the reservoir. However, the poor sweep can be ameliorated by intermittent surfactant injection to generate foam. In addition, the capillary force which hinders the gas (nonwetting phase) from entering the low-permeability region can be effectively leveraged to redistribute the fluids in the porous media, resulting in better sweep efficiency. We conclude that foam if properly designed can effectively improve the conformance of the WAG EOR in the presence of reservoir heterogeneity.


2020 ◽  
Vol 906 ◽  
Author(s):  
Chiyu Xie ◽  
Wenhai Lei ◽  
Matthew T. Balhoff ◽  
Moran Wang ◽  
Shiyi Chen

Abstract


2020 ◽  
Author(s):  
Tiziana Tosco ◽  
Monica Granetto ◽  
Lucia Re ◽  
Aurora Audino ◽  
Luca Serpella ◽  
...  

<p>The use of pesticides in agriculture has numerous advantages but also significant environmental drawbacks; The uncontrolled or excessive use of agrochemicals has progressively contributed to the contamination of environmental matrices, and in particular of soils and groundwater. To contribute solving these issues, an eco-compatible nano-formulation was recently developed by the authors to help controlling the environmental dispersion of Dicamba, a herbicide widely used to control broadleaf weeds; Dicamba is highly soluble and moderately volatile, but is less toxic and persistent compared to other competing herbicides. The proposed nano-formulation was developed using eco-compatible, low-cost materials, including natural clays an biopolymers, with the aim to reduce Dicamba volatilization (thus reducing dispersion in air, and consequently potential impacts on both workers and neighboring crops) and solubility (thus reducing infiltration during and after application, and consequently uncontrolled dispersion in the subsoil).  In this work, the results of laboratory and greenhouse tests are discussed, comparing the efficacy of the nano-formulation against the pure herbicide compound and a commercial Dicamba-based product, in terms of volatilization, mobility in porous media (both saturated and unsaturated) and efficacy in weed control. The column tests results are modeled using colloid transport software (namely MNMs and Hydrus) and used for the development of a preliminary field-scale model of herbicide application and dispersion in the subsoil. The work was developed in the framework of the project Nanograss, co-funded by Compagnia di San Paolo Foundation.</p>


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