Probing Methane Foam Transport in Heterogeneous Porous Media: An Experimental and Numerical Case Study of Permeability-Dependent Rheology and Fluid Diversion at Field Scale

SPE Journal ◽  
2020 ◽  
Vol 25 (04) ◽  
pp. 1697-1710 ◽  
Author(s):  
Yongchao Zeng ◽  
Ridhwan Z. Kamarul Bahrim ◽  
J. A. W. M. Groot ◽  
Sebastien Vincent-Bonnieu ◽  
Jeroen Groenenboom ◽  
...  

Summary This paper advances the understanding of foam transport in heterogeneous porous media for enhanced oil recovery (EOR). Specifically, we investigate the dependence of methane foam rheology on the rock permeability at the laboratory scale and then extend the observations to the field scale with foam modeling techniques and reservoir simulation tools. The oil recovery efficiency of conventional gasflooding, waterflooding, and water-alternating-gas (WAG) processes can be limited by constraints such as bypassing effects (including both viscous fingering and channeling mechanisms) and gravity override. The problem can be more severe if the reservoir is highly fractured or heterogeneously layered in the direction of flow. Foam offers the promise to address the three issues simultaneously by better controlling the mobility of injected fluids. However, limited literature data of foam-flooding experiments were reported using actual reservoir cores at harsh conditions. In this paper, a series of methane (CH4) foam-flooding experiments were conducted in three different actual cores from a proprietary reservoir at an elevated temperature. It is found that foam rheology is significantly correlated with the rock permeability. To quantify the mobility control offered by foam, we calculated the apparent viscosity on the basis of the measured pressure drop at steady state. Interestingly, the apparent viscosity was found to be selectively higher in the high-permeability cores compared with that in the low-permeability zones. We parameterized our system using a texture-implicit-local-equilibrium model (STARS™ simulator, Computer Modelling Group, Calgary, Alberta, Canada) to illustrate the dependence of foam parameters on rock permeability. In addition, we created a two-layered model reservoir using an in-house simulator called modular reservoir simulator (MoReS; Shell Research, Rijswijk, The Netherlands) to elucidate the role of different driving forces for fluid diversion at the field level. We took into consideration the combined effect of gravitational, viscous force, and capillary forces in our simulation. We show that the gravitational forces prevent the gas from sweeping the lower part of the reservoir. However, the poor sweep can be ameliorated by intermittent surfactant injection to generate foam. In addition, the capillary force which hinders the gas (nonwetting phase) from entering the low-permeability region can be effectively leveraged to redistribute the fluids in the porous media, resulting in better sweep efficiency. We conclude that foam if properly designed can effectively improve the conformance of the WAG EOR in the presence of reservoir heterogeneity.

SPE Journal ◽  
2019 ◽  
Vol 25 (01) ◽  
pp. 416-431 ◽  
Author(s):  
Songyan Li ◽  
Qun Wang ◽  
Zhaomin Li

Summary Foam flooding is an important method used to protect oil reservoirs and increase oil production. However, the research on foam fluid is generally focused on aqueous foam, and there are a few studies on the stability mechanism of oil-based foam. In this paper, a compound surfactant consisting of Span® 20 and a fluorochemical surfactant is determined as the formula for oil-based foam. The foam volume and half-life in the bulk phase are measured to be 275 mL and 302 seconds, respectively, at room temperature and atmospheric pressure. The stability mechanism of oil-based foam is proposed by testing the interfacial tension (IFT) and interfacial viscoelasticity. The lowest IFT of 18.5 mN/m and the maximum viscoelasticity modulus of 16.8 mN/m appear at the concentration of 1.0 wt%, resulting in the most-stable oil-based foam. The effect of oil viscosity and temperature on the properties of oil-based foam is studied. The foam stability increases first and then decreases with the rising oil viscosity, and the stability decreases with rising temperature. The apparent viscosity of oil-based foam satisfies the power-law non-Newtonian properties, and this viscosity is much higher than that of the phases of oil and CO2. The flow of oil-based foam in porous media is studied through microscopic-visualization experiments. Bubble division, bubble merging, and bubble deformation occur during oil-based-foam flow in porous media. The oil-recovery efficiency of the oil-based-foam flooding is 78.3%, while the oil-recovery efficiency of CO2 flooding is only 28.2%. The oil recovery is enhanced because oil-based foam reduces CO2 mobility, inhibits gas channeling, and improves sweep efficiency. The results are meaningful for CO2 mobility control and for the application of foam flooding for enhanced oil recovery (EOR).


2021 ◽  
Author(s):  
Qichao Lv ◽  
Tongke Zhou ◽  
Xing Zhang ◽  
Xinshu Guo ◽  
Zhaoxia Dong

Abstract CO2 foams have been used for a long time for enhanced oil recovery (EOR) and carbon capture, utilization, and storage. Note that conventional CO2 foam focuses on mobility control and storage of bare CO2. However, this technology has suffered from low storage efficiency and EOR because of foam instability. In this study, the geological storage of CO2 and coal fly ash (CFA) using Pickering foam for EOR was explored. The aim is to obtain an inexpensive method for EOR and storage of greenhouse gases and atmospheric pollutants. The Pickering foam was prepared using Waring blender method. The experiments were conducted to evaluate CO2/liquid interface enhancement by measuring the interfacial tension and interfacial viscoelastic modulus. As per the heterogeneous sandpack flooding experiments, the profile control capacity and the performance of oil displacement using CO2 foam enhanced by CFA were investigated. The amount of storage from dynamic aspects of CO2 and CFA was measured to demonstrate the storage law. The stability of aqueous foam was improved significantly after the addition of CFA. The half-life time of foam stabilized by CFA particles increased by more than about 11 times than that of foam without CFA particles. The interfacial dilatational viscoelastic modulus of CO2/foaming solution increased with CFA particle concentration increasing, indicating the interface transformed from liquid-like to solid-like. Flooding experiments in heterogeneous porous media showed that more produced fluid was displaced from the relatively low-permeability sandpack after the injection of CO2 foam with CFA. The oil recovery by CFA stabilized foam was improved by ~28.3% than that of foam without CFA particles. And the sequestration of CO2 in heterogeneous porous media was enhanced with the addition of CFA to CO2 foam, and the CFA stabilized foam displayed a strong resistance to water erosion for the storage of CO2 and CFA. This work introduces a win–win method for EOR and storage of CO2 and atmospheric pollutant particles. CFA from coal combustion was used as an enhancer for CO2 foam, which improved the interfacial dilatational viscoelasticity of foam film and the dynamic storage of CO2. Furthermore, the storage of CO2 and CFA contributed to improvement in sweep efficiency, and thus EOR.


2020 ◽  
Vol 21 (2) ◽  
pp. 339
Author(s):  
I. Carneiro ◽  
M. Borges ◽  
S. Malta

In this work,we present three-dimensional numerical simulations of water-oil flow in porous media in order to analyze the influence of the heterogeneities in the porosity and permeability fields and, mainly, their relationships upon the phenomenon known in the literature as viscous fingering. For this, typical scenarios of heterogeneous reservoirs submitted to water injection (secondary recovery method) are considered. The results show that the porosity heterogeneities have a markable influence in the flow behavior when the permeability is closely related with porosity, for example, by the Kozeny-Carman (KC) relation.This kind of positive relation leads to a larger oil recovery, as the areas of high permeability(higher flow velocities) are associated with areas of high porosity (higher volume of pores), causing a delay in the breakthrough time. On the other hand, when both fields (porosity and permeability) are heterogeneous but independent of each other the influence of the porosity heterogeneities is smaller and may be negligible.


2018 ◽  
Vol 140 (10) ◽  
Author(s):  
Chuan Lu ◽  
Wei Zhao ◽  
Yongge Liu ◽  
Xiaohu Dong

Oil-in-water (O/W) emulsions are expected to be formed in the process of surfactant flooding for heavy oil reservoirs in order to strengthen the fluidity of heavy oil and enhance oil recovery. However, there is still a lack of detailed understanding of mechanisms and effects involved in the flow of O/W emulsions in porous media. In this study, a pore-scale transparent model packed with glass beads was first used to investigate the transport and retention mechanisms of in situ generated O/W emulsions. Then, a double-sandpack model with different permeabilities was used to further study the effect of in situ formed O/W emulsions on the improvement of sweep efficiency and oil recovery. The pore-scale visualization experiment presented an in situ emulsification process. The in situ formed O/W emulsions could absorb to the surface of pore-throats, and plug pore-throats through mechanisms of capture-plugging (by a single emulsion droplet) and superposition-plugging or annulus-plugging (by multiple emulsion droplets). The double-sandpack experiments proved that the in situ formed O/W emulsion droplets were beneficial for the mobility control in the high permeability sandpack and the oil recovery enhancement in the low permeability sandpack. The size distribution of the produced emulsions proved that larger pressures were capable to displace larger O/W emulsion droplets out of the pore-throat and reduce their retention volumes.


SPE Journal ◽  
1900 ◽  
Vol 25 (02) ◽  
pp. 867-882
Author(s):  
Pengfei Dong ◽  
Maura Puerto ◽  
Guoqing Jian ◽  
Kun Ma ◽  
Khalid Mateen ◽  
...  

Summary The high formation heterogeneity in naturally fractured limestone reservoirs requires mobility control agents to improve sweep efficiency and boost oil recovery. However, typical mobility control agents, such as polymers and gels, are impractical in tight sub-10-md formations due to potential plugging issues. The objective of this study is to demonstrate the feasibility of a low-interfacial-tension (low-IFT) foam process in fractured low-permeability limestone reservoirs and to investigate relevant geochemical interactions. The low-IFT foam process was investigated through coreflood experiments in homogeneous and fractured oil-wet cores with sub-10-md matrix permeability. The performance of a low-IFT foaming formulation and a well-known standard foamer [alpha olefin sulfonate (AOS) C14-16] were compared in terms of the efficiency of oil recovery. The effluent ionic concentrations were measured to understand how the geochemical properties of limestone influenced the low-IFT foam process. Aqueous stability and phase behavior tests with crushed core materials and brines containing various divalent ion concentrations were conducted to interpret the observations in the coreflood experiments. Low-IFT foam process can achieve significant incremental oil recovery in fractured oil-wet limestone reservoirs with sub-10-md matrix permeability. Low-IFT foam flooding in a fractured oil-wet limestone core with 5-md matrix permeability achieved 64% incremental oil recovery compared to waterflooding. In this process, because of the significantly lower capillary entry pressure for surfactant solution compared to gas, the foam primarily diverted surfactant solution from the fracture into the matrix. This selective diversion effect resulted in surfactant or weak foam flooding in the tight matrix and hence improved the invading fluid flow in the matrix. Meanwhile, the low-IFT property of the foaming formulation mobilized the remaining oil in the matrix. This oil mobilization effect of the low-IFT formulation achieved lower remaining oil saturation in the swept zones compared with the formulation lacking low-IFT property with oil. The limestone geochemical instability caused additional challenges for the low-IFT foam process in limestone reservoirs compared to dolomite reservoirs. The reactions of calcite with injected fluids—such as mineral dissolution and the exchange of calcium and magnesium—were found to increase the Ca2+ concentration in the produced fluids. Because the low-IFT foam process is sensitive to brine salinity, the additional Ca2+ may cause potential surfactant precipitation and unfavorable over-optimum conditions. It, therefore, may cause injectivity and phase-trapping issues especially in the homogeneous limestone. Results in this work demonstrated that despite the challenges associated with limestone dissolution, the low-IFT foam process can remarkably extend chemical enhanced oil recovery (EOR) in fractured oil-wet tight reservoirs with matrix permeability as low as 5 md.


SPE Journal ◽  
2018 ◽  
Vol 23 (06) ◽  
pp. 2243-2259 ◽  
Author(s):  
Pengfei Dong ◽  
Maura Puerto ◽  
Guoqing Jian ◽  
Kun Ma ◽  
Khalid Mateen ◽  
...  

Summary Oil recovery in heterogeneous carbonate reservoirs is typically inefficient because of the presence of high-permeability fracture networks and unfavorable capillary forces within the oil-wet matrix. Foam, as a mobility-control agent, has been proposed to mitigate the effect of reservoir heterogeneity by diverting injected fluids from the high-permeability fractured zones into the low-permeability unswept rock matrix, hence improving the sweep efficiency. This paper describes the use of a low-interfacial-tension (low-IFT) foaming formulation to improve oil recovery in highly heterogeneous/fractured oil-wet carbonate reservoirs. This formulation provides both mobility control and oil/water IFT reduction to overcome the unfavorable capillary forces preventing invading fluids from entering an oil-filled matrix. Thus, as expected, the combination of mobility control and low-IFT significantly improves oil recovery compared with either foam or surfactant flooding. A three-component surfactant formulation was tailored using phase-behavior tests with seawater and crude oil from a targeted reservoir. The optimized formulation simultaneously can generate IFT of 10−2 mN/m and strong foam in porous media when oil is present. Foam flooding was investigated in a representative fractured core system, in which a well-defined fracture was created by splitting the core lengthwise and precisely controlling the fracture aperture by applying a specific confining pressure. The foam-flooding experiments reveal that, in an oil-wet fractured Edward Brown dolomite, our low-IFT foaming formulation recovers approximately 72% original oil in place (OOIP), whereas waterflooding recovers only less than 2% OOIP; moreover, the residual oil saturation in the matrix was lowered by more than 20% compared with a foaming formulation lacking a low-IFT property. Coreflood results also indicate that the low-IFT foam diverts primarily the aqueous surfactant solution into the matrix because of (1) mobility reduction caused by foam in the fracture, (2) significantly lower capillary entry pressure for surfactant solution compared with gas, and (3) increasing the water relative permeability in the matrix by decreasing the residual oil. The selective diversion effect of this low-IFT foaming system effectively recovers the trapped oil, which cannot be recovered with single surfactant or high-IFT foaming formulations applied to highly heterogeneous or fractured reservoirs.


2020 ◽  
Vol 400 ◽  
pp. 38-44
Author(s):  
Hassan Soleimani ◽  
Hassan Ali ◽  
Noorhana Yahya ◽  
Beh Hoe Guan ◽  
Maziyar Sabet ◽  
...  

This article studies the combined effect of spatial heterogeneity and capillary pressure on the saturation of two fluids during the injection of immiscible nanoparticles. Various literature review exhibited that the nanoparticles are helpful in enhancing the oil recovery by varying several mechanisms, like wettability alteration, interfacial tension, disjoining pressure and mobility control. Multiphase modelling of fluids in porous media comprise balance equation formulation, and constitutive relations for both interphase mass transfer and pressure saturation curves. A classical equation of advection-dispersion is normally used to simulate the fluid flow in porous media, but this equation is unable to simulate nanoparticles flow due to the adsorption effect which happens. Several modifications on computational fluid dynamics (CFD) have been made to increase the number of unknown variables. The simulation results indicated the successful transportation of nanoparticles in two phase fluid flow in porous medium which helps in decreasing the wettability of rocks and hence increasing the oil recovery. The saturation, permeability and capillary pressure curves show that the wettability of the rocks increases with the increasing saturation of wetting phase (brine).


2019 ◽  
Vol 17 (3) ◽  
pp. 734-748 ◽  
Author(s):  
Ling-Zhi Hu ◽  
Lin Sun ◽  
Jin-Zhou Zhao ◽  
Peng Wei ◽  
Wan-Fen Pu

AbstractThe formation heterogeneity is considered as one of the major factors limiting the application of foam flooding. In this paper, influences of formation properties, such as permeability, permeability distribution, interlayer, sedimentary rhythm and 3D heterogeneity, on the mobility control capability and oil displacement efficiency of foam flooding, were systematically investigated using 2D homogeneous and 2D/3D heterogeneous models under 120 °C and salinity of 20 × 104 mg/L. The flow resistance of foam was promoted as the permeability increased, which thus resulted in a considerable oil recovery behavior. In the scenario of the vertical heterogeneous formations, it was observed that the permeability of the high-permeable layer was crucial to foam mobility control, and the positive rhythm appeared favorable to improve the foam flooding performance. The additional oil recovery increased to about 40%. The interlayer was favorable for the increases in mobility reduction factor and oil recovery of foam flooding when the low permeability ratio was involved. For the 3D heterogeneous formations, foam could efficiently adjust the areal and vertical heterogeneity through mobility control and gravity segregation, and thus enhancing the oil recovery to 11%–14%. The results derived from this work may provide some insight for the field test designs of foam flooding.


2016 ◽  
Vol 9 (1) ◽  
pp. 29-36
Author(s):  
Chengli Zhang ◽  
Guodong Qu ◽  
Guoqiang Cui ◽  
Mingxing Bai

Enhanced foam flooding is a chemical flooding technology, which is applied to improve the recovery efficiency of oil and gas. The oil displacement agent of enhanced foam flooding is a foam that the polymer and surfactant solution as liquid. In this paper, three-dimensional mathematical model of unsteady flow is established about enhanced foam system in the porous media, and the numerical calculation method is given to study the enhanced foam flooding. The results show that: the unsteady flow of enhanced foam system in porous media exists flow front, the flow foam average density of flow front reach the peak; enhanced foam flooding can form the oil bank in the displacement front and the oil saturation of the oil bank reaches about 0.55, the oil bank can produce effective drive to remain oil and then improve oil recovery.


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