Rodingitization of mafic rocks from Central Evia (Greece) associated with serpentinite exhumation: Evidence from Petrological, Geochemical and Isotopic data
<p>In Central Evia island (Aegean-Greece) serpentinized ultramafic rocks appear as elongated thrust sheets or in the form of olistostromes incorporated within Maestrichtian-Paleocene flysch. These are crosscut by well-developed rodingite dykes that were derived from four main protoliths that include i) Boninites, ii) Island-arc Tholeiitic Basalts and Gabbros, iii) Alkaline basalts and iv) Calc-alkaline basalts. They mainly comprise of minerals that include (hydro)garnet + chlorite + clinopyroxene &#177; vesuvianite. Accessory minerals include spinel &#177; calcite &#177; prehnite &#177; amphibole &#177; orthopyroxene &#177; olivine &#177; quartz &#177; opaque Fe-Ti oxides. Rodingites that were formed at the expense of boninites and island-arc tholeiitic rocks were likely formed within a single rodingitization stage, since garnet is mainly grossular-rich and relict primary clinopyroxene has been preserved. The rodingitization of the alkaline and calc-alkaline basalts seems to have occurred as a multi-stage metasomatic process that occurred during the exhumation of the mafic-ultramafic mantle wedge complex. This resulted in the development of late-stage andradite, vesuvianite and in some cases of chlorite during derodingitization. In this case, successive reaction zones with variability in the participating mineral phases were developed. &#160;Geochemical results reveal remarkable rare earth element (REE) enrichments, especially in the inner zones, likely being the result of successive diffusion and element transfer. Few rodingites are characterized as calcite-bearing, whose stable <sup>13</sup>C-<sup>18</sup>O isotopic data points to the restricted involvement of late-stage mixed hydrothermal and seawater-related carbonation processes.</p>