Land-to-ocean fluxes and biolability of organic matter eroding along the Beaufort Sea coast near Drew Point, Alaska

2021 ◽  
Author(s):  
Emily Bristol ◽  
Craig Connolly ◽  
Thomas Lorenson ◽  
Bruce Richmond ◽  
Anastasia Ilgen ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Active Layer ◽  
Late Pleistocene ◽  
Coastal Erosion ◽  
Organic Matter Content ◽  
Beaufort Sea ◽  
The Arctic ◽  
Series Data ◽  
Sea Coast

<p>Coastal erosion rates are increasing along the Alaskan Beaufort Sea coast due to increases in wave action, the increasing length of the ice-free season, and warming permafrost. These eroding permafrost coastlines transport organic matter and inorganic nutrients to the Arctic Ocean, likely fueling biological production and CO<sub>2</sub> emissions. To assess the impacts of Arctic coastal erosion on nearshore carbon and nitrogen cycling, we examined geochemical profiles from eroding coastal bluffs and estimated annual organic matter fluxes from 1955 to 2018 for a 9 km stretch of coastline near Drew Point, Alaska. Additionally, we conducted a laboratory incubation experiment to examine dissolved organic carbon (DOC) leaching and biolability from coastal soils/sediments added to seawater.</p><p>Three permafrost cores (4.5 – 7.5 m long) revealed that two distinct horizons compose eroding bluffs near Drew Point: Holocene age, organic-rich (~12-45% total organic carbon; TOC) terrestrial soils and lacustrine sediments, and below, Late Pleistocene age marine sediments with lower organic matter content (~1% TOC), lower carbon to nitrogen ratios, and higher δ<sup>13</sup>C-TOC values. Organic matter stock estimates from the cores, paired with remote sensing time-series data, show that erosional TOC fluxes from this study coastline averaged 1,369 kg C m<sup>−1</sup> yr<sup>−1</sup> during the 21<sup>st</sup> century, nearly double the average flux of the previous half century. Annual TOC flux from this 9 km coastline is now similar to the annual TOC flux from the Kuparuk River, the third largest river draining the North Slope of Alaska.</p><p>Experimental work demonstrates that there are distinct differences in DOC leaching yields and the fraction of biodegradable DOC across soil/sediment horizons. When core samples were submerged in seawater for 24 hours, the Holocene age organic-rich permafrost leached the most DOC in seawater (~6.3 mg DOC g<sup>-1</sup> TOC), compared to active layer soils and Late-Pleistocene marine-derived permafrost (~2.5 mg DOC g<sup>-1</sup> TOC). Filtered leachates were then incubated aerobically in the dark for 26 and 90 days at 20°C to examine biodegradable DOC (i.e. the proportion of DOC lost due to microbial uptake or remineralization). Of this leached DOC, Late Pleistocene permafrost was the most biolabile over 90 days (31 ± 7%), followed by DOC from active layer soils (24 ± 5%) and Holocene-age permafrost (14% ± 3%). If we scale these results to a typical 4 m tall eroding bluff at Drew Point, we expect that ~341 g DOC m<sup>-2 </sup>will rapidly leach, of which ~25% is biodegradable. These results demonstrate that eroding permafrost bluffs are an increasingly important source of biolabile DOC, likely contributing to greenhouse gas emissions and marine production in the coastal environment.</p>

scholarly journals Geochemistry of Coastal Permafrost and Erosion-Driven Organic Matter Fluxes to the Beaufort Sea Near Drew Point, Alaska

2021 ◽  
Vol 8 ◽  
Author(s):  
Emily M. Bristol ◽  
Craig T. Connolly ◽  
Thomas D. Lorenson ◽  
Bruce M. Richmond ◽  
Anastasia G. Ilgen ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Late Pleistocene ◽  
21St Century ◽  
Marine Sediments ◽  
Coastal Erosion ◽  
Beaufort Sea ◽  
The Arctic ◽  
The Holocene ◽  
Kuparuk River

Accelerating erosion of the Alaska Beaufort Sea coast is increasing inputs of organic matter from land to the Arctic Ocean, and improved estimates of organic matter stocks in eroding coastal permafrost are needed to assess their mobilization rates under contemporary conditions. We collected three permafrost cores (4.5–7.5 m long) along a geomorphic gradient near Drew Point, Alaska, where recent erosion rates average 17.2 m year−1. Down-core patterns indicate that organic-rich soils and lacustrine sediments (12–45% total organic carbon; TOC) in the active layer and upper permafrost accumulated during the Holocene. Deeper permafrost (below 3 m elevation) mainly consists of Late Pleistocene marine sediments with lower organic matter content (∼1% TOC), lower C:N ratios, and higher δ13C values. Radiocarbon-based estimates of organic carbon accumulation rates were 11.3 ± 3.6 g TOC m−2 year−1 during the Holocene and 0.5 ± 0.1 g TOC m−2 year−1 during the Late Pleistocene (12–38 kyr BP). Within relict marine sediments, porewater salinities increased with depth. Elevated salinity near sea level (∼20–37 in thawed samples) inhibited freezing despite year-round temperatures below 0°C. We used organic matter stock estimates from the cores in combination with remote sensing time-series data to estimate carbon fluxes for a 9 km stretch of coastline near Drew Point. Erosional fluxes of TOC averaged 1,369 kg C m−1 year−1 during the 21st century (2002–2018), nearly doubling the average flux of the previous half-century (1955–2002). Our estimate of the 21st century erosional TOC flux year−1 from this 9 km coastline (12,318 metric tons C year−1) is similar to the annual TOC flux from the Kuparuk River, which drains a 8,107 km2 area east of Drew Point and ranks as the third largest river on the North Slope of Alaska. Total nitrogen fluxes via coastal erosion at Drew Point were also quantified, and were similar to those from the Kuparuk River. This study emphasizes that coastal erosion represents a significant pathway for carbon and nitrogen trapped in permafrost to enter modern biogeochemical cycles, where it may fuel food webs and greenhouse gas emissions in the marine environment.

scholarly journals Burial and origin of permafrost organic carbon in the Arctic nearshore zone

2020 ◽  
Author(s):  
Michael Fritz ◽  
Hendrik Grotheer ◽  
Vera Meyer ◽  
Thorsten Riedel ◽  
Gregor Pfalz ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Carbon Cycle ◽  
Coastal Erosion ◽  
Stable Carbon Isotopes ◽  
Carbon Isotopic Composition ◽  
Sediment Traps ◽  
The Arctic ◽  
Nearshore Zone ◽  
Carbon Decomposition

<p>Increasing air and sea surface temperatures at high latitudes lead to accelerated thaw, destabilization, and erosion of perennially frozen soils (i.e., permafrost), which are often rich in organic carbon. Coastal erosion leads to an increased mobilization of organic carbon into the Arctic Ocean that can be converted into greenhouse gases and may therefore contribute to further warming. Carbon decomposition can be limited if organic matter is efficiently deposited on the seafloor, buried in marine sediments and thus removed from the short-term carbon cycle. Basins, canyons and troughs near the coastline can serve as sediment traps and potentially accommodate large quantities of organic carbon along the Arctic coast. Here we use biomarkers (source-specific molecules), stable carbon isotopes (δ<sup>13</sup>C) and radiocarbon (Δ<sup>14</sup>C) to identify the sources of organic carbon in the nearshore zone of the southern Canadian Beaufort Sea. We use an end-member model based on the carbon isotopic composition of bulk organic matter to identify sources of organic carbon. Monte Carlo simulations are applied to quantify the contribution of coastal permafrost erosion to the sedimentary carbon budget. The models suggest that 40% of all carbon released by coastal erosion is efficiently trapped and sequestered in the nearshore zone. We conclude that permafrost coastal erosion releases huge amounts of sediment and organic matter into the nearshore zone. Rapid burial removes large quantities of carbon from the carbon cycle in depositional settings.</p>

scholarly journals Quantitative and Qualitative Composition of Soil Organic Matter in Samples of Ice Complex from Central Yakutia, Eastern Siberia

2018 ◽  
Vol 2018 ◽  
pp. 1-8
Author(s):  
Andrey Shepelev ◽  
Alexander Fedorov ◽  
Alexandra Cherepanova
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Active Layer ◽  
Organic Matter Content ◽  
Matter Content ◽  
Total Carbon ◽  
Biogenic Elements ◽  
Labile Organic Matter ◽  
Total Carbon Content ◽  
Ice Complex

Investigation of organic carbon and nitrogen stock was conducted at depths greater than one meter in the ice complex in central part of Yakutia (Russia). Around 53% of the total organic carbon stock in the upper part of the ice complex is held in the active layer. The protective layer holds 31% and the permafrost layer holds 16%. The distribution of nitrogen over the elementary layers of the ice complex mirrors the percentages for organic carbon stocks given above. The total stock of biogenic elements in the ice complex investigated (0–250 cm) consists of 38.7 ± 0.2 kg/m2 of organic carbon and 2.13 ± 0.01 kg/m2 of nitrogen. The prevalent amount is carbon detritus, 40% of the total carbon content in the active layer. The share of labile carbon accounts 18%, that is 2 times less than carbon detritus. In the next two layers, the content of the components decreases and varies from 2% to 12%. The low labile organic matter content in the protective and permafrost layers indicates the development of the ice complex proceeded under conditions with poorly formed organic material.

Characteristics of organic carbon in surface sediments of Laptev Sea shelf

2020 ◽  
Author(s):  
Irina Oberemok ◽  
Elena Gershelis ◽  
Andrey Grin’ko ◽  
Alexey Ruban ◽  
Elizaveta Klevantseva ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Coastal Erosion ◽  
Surface Sediments ◽  
Oxygen Index ◽  
Outer Shelf ◽  
The Arctic ◽  
Laptev Sea ◽  
Shelf Sediments ◽  
The Laptev Sea

<p>Accelerating coastal erosion and enhancing river sediment discharge are expected to greatly increase the delivery of terrestrial organic carbon (terrOC) to the Arctic Ocean. Remobilized terrOC may be buried in shallow or outer shelf sediments, degraded and translocated to the deeper basins, or remineralized in the water column causing a positive feedback to amplified global warming. The East Siberian Arctic Shelf (ESAS), represented by the Laptev Sea, the East Siberian Sea, and the Russian part of the Chukchi Sea, is the widest and shallowest continental shelf of the World Ocean. In the current study, we investigated surface sediment samples collected across the Laptev Sea shelf (from the coastline to the outer shelf) during the Arctic expedition onboard the Russian <em>R/V Academician M. Keldysh</em> during fall 2018.</p><p>We analyzed 16 samples for bulk (TOC, <em>δ</em>13C) and molecular (distribution and concentration of n-alkanes and PAHs) parameters. We also performed Rock-Eval (RE) analysis in order to compare its results with the signatures provided by traditional geochemical tracers and thereby to gain new insights into the sources of organic matter in modern surface sediments. In addition, a grain-size analysis was carried out to reveal hydrodynamic control on the organic carbon transport across the studied transect. Using a combination of traditional molecular interpretations (performed in this study and published earlier) and RE parameters (Hydrogen index, Oxygen index and T<sub>peak</sub>) we attempted to distinguish riverine input and coastal erosion and disentangle processes of terrOC degradation and its replacement with fresh/marine OC during cross-shelf transport. Overall, a strong decrease of terrigenous contribution to the sedimentary organic carbon was observed on molecular level with increasing distance from the coast. According to the RE data, intensive terrOC degradation takes place in the shallow and mid-shelf sediments which is traced by sharply increasing oxygen index. The clear correlation between OI and the clay content points toward the perception that mineral matrix do not seem to be such good protector as expected, and intensive microbial degradation of the sedimentary organic matter contained in fine particles occurs during repeated resuspension.</p><p>This research is supported by Russian Science Foundation, project # 19-77-00067.</p>

Mobilization of aged carbon via meltwater floods and coastal erosion in the Canadian Arctic during the last deglaciation

2021 ◽  
Author(s):  
Junjie Wu ◽  
Gesine Mollenhauer ◽  
Ruediger Stein ◽  
Jens Hefter ◽  
Kirsten Fahl ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Coastal Erosion ◽  
Drainage System ◽  
Beaufort Sea ◽  
Sediment Flux ◽  
Biological Degradation ◽  
Last Deglaciation ◽  
Marine Organic Matter ◽  
Ocean Carbon

<p>It is consensus that the deglacial changes in ocean carbon storage and circulation play a role in regulating atmospheric CO<sub>2</sub>. However, emerging evidence suggests that the rapid deglacial CO<sub>2</sub> rises can in part be attributed to large quantities of pre-aged carbon being released from degrading permafrost. In this study, we apply a radiocarbon approach on both terrestrial compounds (high molecular weight fatty acids; HWM-FA) and bulk organic carbon from a well-studied core ARA04C/37 from the Canadian Beaufort Sea. Based on our records, substantial amounts of ancient carbon were supplied from land to the ocean during the mid-late deglaciation (14.5-10 cal. kyr BP) by frequent high sediment flux events. Because the core location is strongly influenced by the Mackenzie River discharge, sediments only contain minor contributions from marine organic matter, allowing to consider mainly two terrestrial sources to explain the characteristics of bulk sedimentary organic matter. The terrestrial HMW-FA are taken to represent the biospheric carbon, and their age differences from the bulk organic carbon are explained by petrogenic carbon input. During the Younger Dryas, ice-sheet melting and meltwater outbursts enhanced petrogenic carbon contributions, suggesting a major source in the hinterland drainage system. During the rapid sea-level rise (meltwater pulses 1a and 1b), the very old organic carbon and comparable ages between biospheric carbon and bulk organic carbon indicate the occurrence of permafrost carbon remobilization primarily via coastal erosion while petrogenic carbon from the drainage system was found negligible. Remobilized ancient permafrost carbon is commonly regarded to be highly bioavailable, while petrogenic carbon is likely more recalcitrant to biological degradation. Our records thus suggest that the release of ancient carbon to the Beaufort Sea had the strongest impact on the atmospheric CO<sub>2</sub> level and contributed to its rapid increases during the B/A and Pre-Boreal when permafrost deposits along the coast were eroded.</p>

Landscape-driven carbon export from small coastal permafrost watersheds

2020 ◽  
Author(s):  
Niek Speetjens ◽  
George Tanski ◽  
Victoria Martin ◽  
Julia Wagner ◽  
Andreas Richter ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Active Layer ◽  
Stream Water ◽  
Qualitative Change ◽  
High Arctic ◽  
The Arctic ◽  
Climate Projections ◽  
Stable Water Isotopes ◽  
Landscape Units

<p>Ongoing climate warming in the western Canadian Arctic is leading to thawing of permafrost soils and subsequent mobilization of its organic matter (OM) pool. Part of this mobilized terrestrial OM enters the aquatic system as dissolved organic matter (DOM) and is laterally transported from land to sea. Mobilized DOM is an important source of nutrients for ecosystems as it is available for microbial breakdown, the consequent turnover of the dissolved organic carbon (DOC) fraction of DOM serving as a potential source of greenhouse gases. We are beginning to understand spatial controls on the release of DOM as well as the quantities and fate of this material in large arctic rivers, but these processes remain systematically understudied in small, high-arctic watersheds, despite the fact that these particular watersheds experience strongest warming.</p><p>We sampled soil (active layer and permafrost) and water (porewater and stream water) from two small catchments along the Yukon coast, Canada, during the summers of 2018 and 2019. We assessed the organic carbon quantity (using DOC and soil OC content), quality (d<sup>13</sup>C-DOC, C/N ratios and optical properties including components modelled with EEMs-PARAFAC), the turnover of DOM through incubation experiments as well as nutrients and stable water isotopes. We classify and compare different landscape units by quantitative and qualitative change across gradients from soil stocks down to the catchment outflow.</p><p>Our results show that substantial variation in DOC concentrations exists among various landscape units as well as between active layer and permafrost. We find high soil carbon stocks and leaching potentials from these coastal tundra soils. Moreover, we find that permafrost DOM is utilized rapidly upon thaw. Using remote sensing-based landscape classification, we are planning to upscale carbon and nutrient fluxes for the panarctic coastal zone to account for small yet numerous high-arctic watersheds in lateral terrestrial OM transfer from land to sea Under current climate projections and with continued permafrost thaw altered lateral fluxes may have profound impacts on the arctic aquatic ecosystem and arctic carbon cycling.</p>

scholarly journals Geophysical imaging of permafrost in the SW Svalbard – the result of two high arctic expeditions to Spitsbergen

2020 ◽  
Author(s):  
Mariusz Majdanski ◽  
Artur Marciniak ◽  
Bartosz Owoc ◽  
Wojciech Dobiński ◽  
Tomasz Wawrzyniak ◽  
...  
Keyword(s):  
Surface Waves ◽  
Active Layer ◽  
High Arctic ◽  
The Arctic ◽  
Seismic Profiles ◽  
Frozen Ground ◽  
Near Surface ◽  
Seismic Processing ◽  
Reflection Seismic ◽  
Sea Coast

<p>The Arctic regions are the place of the fastest observed climate change. One of the indicators of such evolution are changes occurring in the glaciers and the subsurface in the permafrost. The active layer of the permafrost as the shallowest one is well measured by multiple geophysical techniques and in-situ measurements.</p><p>Two high arctic expeditions have been organized to use seismic methods to recognize the shape of the permafrost in two seasons: with the unfrozen ground (October 2017) and frozen ground (April 2018). Two seismic profiles have been designed to visualize the shape of permafrost between the sea coast and the slope of the mountain, and at the front of a retreating glacier. For measurements, a stand-alone seismic stations has been used with accelerated weight drop with in-house modifications and timing system. Seismic profiles were acquired in a time-lapse manner and were supported with GPR and ERT measurements, and continuous temperature monitoring in shallow boreholes.</p><p>Joint interpretation of seismic and auxiliary data using Multichannel analysis of surface waves, First arrival travel-time tomography and Reflection imaging show clear seasonal changes affecting the active layer where P-wave velocities are changing from 3500 to 5200 m/s. This confirms the laboratory measurements showing doubling the seismic velocity of water-filled high-porosity rocks when frozen. The same laboratory study shows significant (>10%) increase of velocity in frozen low porosity rocks, that should be easily visible in seismic.</p><p>In the reflection seismic processing, the most critical part was a detailed front mute to eliminate refracted arrivals spoiling wide-angle near-surface reflections. Those long offset refractions were however used to estimate near-surface velocities further used in reflection processing. In the reflection seismic image, a horizontal reflection was traced at the depth of 120 m at the sea coast deepening to the depth of 300 m near the mountain.</p><p>Additionally, an optimal set of seismic parameters has been established, clearly showing a significantly higher signal to noise ratio in case of frozen ground conditions even with the snow cover. Moreover, logistics in the frozen conditions are much easier and a lack of surface waves recorded in the snow buried geophones makes the seismic processing simpler.</p><p>Acknowledgements               </p><p>This research was funded by the National Science Centre, Poland (NCN) Grant UMO-2015/21/B/ST10/02509.</p>

scholarly journals Permafrost-Affected Soils of the Russian Arctic and their Carbon Pools

2014 ◽  
Vol 6 (1) ◽  
pp. 619-655
Author(s):  
S. Zubrzycki ◽  
L. Kutzbach ◽  
E.-M. Pfeiffer
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Carbon Sink ◽  
Global Climate ◽  
Fundamental Property ◽  
Climate System ◽  
The Arctic ◽  
Quaternary Period ◽  
Permafrost Regions

Abstract. Permafrost-affected soils have accumulated enormous pools of organic matter during the Quaternary Period. The area occupied by these soils amounts to more than 8.6 million km2, which is about 27% of all land areas north of 50° N. Therefore, permafrost-affected soils are considered to be one of the most important cryosphere elements within the climate system. Due to the cryopedogenic processes that form these particular soils and the overlying vegetation that is adapted to the arctic climate, organic matter has accumulated to the present extent of up to 1024 Pg (1 Pg = 1015 g = 1 Gt) of soil organic carbon stored within the uppermost three meters of ground. Considering the observed progressive climate change and the projected polar amplification, permafrost-affected soils will undergo fundamental property changes. Higher turnover and mineralization rates of the organic matter are consequences of these changes, which are expected to result in an increased release of climate-relevant trace gases into the atmosphere. As a result, permafrost regions with their distinctive soils are likely to trigger an important tipping point within the global climate system, with additional political and social implications. The controversy of whether permafrost regions continue accumulating carbon or already function as a carbon source remains open until today. An increased focus on this subject matter, especially in underrepresented Siberian regions, could contribute to a more robust estimation of the soil organic carbon pool of permafrost regions and at the same time improve the understanding of the carbon sink and source functions of permafrost-affected soils.

scholarly journals Impacts of vinasse and methods of sugarcane harvesting on the availability of K and carbon stock of an Argisol

Revista CERES ◽  
2016 ◽  
Vol 63 (1) ◽  
pp. 95-102 ◽  
Author(s):  
Claudinei Alberto Cardin ◽  
Carlos Henrique dos Santos ◽  
Marcos Antonio Escarmínio
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Carbon Stock ◽  
Organic Matter Content ◽  
Matter Content ◽  
Total Carbon ◽  
Native Forest ◽  
Mean Values ◽  
Tropical Regions ◽  
Soil Carbon Stock

ABSTRACT Soils of tropical regions are more weathered and in need of conservation managements to maintain and improve the quality of its components. The objective of this study was to evaluate the availability of K, the organic matter content and the stock of total carbon of an Argisol after vinasse application and manual and mechanized harvesting of burnt and raw sugarcane, in western São Paulo.The data collection was done in the 2012/2013 harvest, in a bioenergy company in Presidente Prudente/SP. The research was arranged out following a split-plot scheme in a 5x5 factorial design, characterized by four management systems: without vinasse application and harvest without burning; with vinasse application and harvest without burning; with vinasse application and harvest after burning; without vinasse application and harvest after burning; plus native forest, and five soil sampling depths (0-10 10-20, 20-30, 30-40, 40-50 cm), with four replications. In each treatment, the K content in the soil and accumulated in the remaining dry biomass in the area, the levels of organic matter, organic carbon and soil carbon stock were determined. The mean values were compared by Tukey test. The vinasse application associated with the harvest without burning increased the K content in soil layers up to 40 cm deep. The managements without vinasse application and manual harvest after burning, and without vinasse application with mechanical harvesting without burning did not increase the levels of organic matter, organic carbon and stock of total soil organic carbon, while the vinasse application and harvest after burning and without burning increased the levels of these attributes in the depth of 0-10 cm.

Constant current chronopotentiometric stripping characterisation of organic matter in seawater from the northern Adriatic, Croatia

2014 ◽  
Vol 11 (2) ◽  
pp. 158 ◽  
Author(s):  
Slađana Strmečki ◽  
Jelena Dautović ◽  
Marta Plavšić
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Seasonal Changes ◽  
Electrochemical Techniques ◽  
Organic Matter Content ◽  
Matter Content ◽  
Constant Current ◽  
Po River ◽  
Northern Adriatic ◽  
Catalytically Active

Environmental context We determined seasonal changes in the organic matter content of the northern Adriatic with newly applied electrochemical techniques able to measure catalytically active organics. The inflow of the Po River and its nutrient load are responsible for the observed changes in the type and concentrations of organic matter in the area. Abstract Catalytically active polysaccharides (Cat PSs) and nitrogen-containing polymeric organic material (N-POM) were determined in seawater from the northern Adriatic station ST101. Catalytically active organics were measured by applying electrochemical methods of adsorptive transfer chronopotentiometric stripping with medium exchange and chronopotentiometric stripping in unmodified seawater. Their concentrations were expressed in milligrams per cubic decimetre–3--> of equivalents of the model calibrating substances, polysaccharide xanthan and protein human serum albumin. The optimal electroanalytical conditions for determination of Cat PSs in seawater were evaluated and defined. Seasonal changes of Cat PSs and N-POM were observed during the period 2011–2013. The highest values were determined in the spring–summer period and the lowest in winter. Cat PSs and N-POM were present in both the dissolved and particulate organic carbon fractions. Cat PSs and N-POM showed a statistically significant positive correlation with the concentrations of surface-active substances. A weak but statistically significant correlation was found between Cat PSs and dissolved organic carbon concentrations. Copper complexing capacities in the period 2011–2013 were in the range of 41–130nmoldm–3.

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