Oxidation of sulphides and rapid weathering in recent landslides
Abstract. Linking together the processes of rapid physical erosion to the resultant chemical dissolution of rock is a crucial step in building an overall deterministic understanding of weathering in mountain belts. Landslides, which are the most volumetrically important geomorphic process at these high rates of erosion, can generate extremely high rates of very localised weathering. To elucidate how this process works we have taken advantage of uniquely intense landsliding, resulting from Typhoon Morakot, in the Taimali river and surrounds in Southern Taiwan. Combining detailed analysis of seepage chemistry with estimates of catchment-by-catchment landslide volumes, we demonstrate that in this setting the primary role of landslides is to introduce fresh, highly labile mineral phases into the surface weathering environment. There, rapid weathering is driven by the oxidation of pyrite and the resultant sulphuric acid-driven dissolution of primarily carbonate rock. The total dissolved load correlates well with dissolved sulphate – the chief product of this style of weathering – in both landslides and streams draining the area (R2 = 0.841 and 0.929 respectively, p < 0.001 in both cases), with solute chemistry in seepage from landslides and catchments affected by significant landsliding governed by the same weathering reactions. Bedrock landslides create conditions for weathering where all mineral phase in a lithology are initially unweathered within landslide deposits, and therefore the most labile phases dominate the weathering at the outset and during a transient period of depletion. This mode of dissolution can strongly alter the overall output of solutes from catchments and their contribution to global chemical cycles if landslide-derived material is retained in catchments for extended periods after mass wasting.