scholarly journals An X-ray micro-tomographic study of the pore space, permeability and percolation threshold of young sea ice

2021 ◽  
Vol 15 (8) ◽  
pp. 4047-4072
Author(s):  
Sönke Maus ◽  
Martin Schneebeli ◽  
Andreas Wiegmann
Keyword(s):  
Sea Ice ◽  
Pore Space ◽  
Permeability Transition ◽  
Hydraulic Permeability ◽  
X Ray ◽  
Model Studies ◽  
Vertical Permeability ◽  
Porosity And Permeability ◽  
Brine Volume

Abstract. The hydraulic permeability of sea ice is an important property that influences the role of sea ice in the environment in many ways. As it is difficult to measure, so far not many observations exist, and the quality of deduced empirical relationships between porosity and permeability is unknown. The present work presents a study of the permeability of young sea ice based on the combination of brine extraction in a centrifuge, X-ray micro-tomographic imaging and direct numerical simulations. The approach is new for sea ice. It allows us to relate the permeability and percolation properties explicitly to characteristic properties of the sea ice pore space, in particular to pore size and connectivity metrics. For the young sea ice from the present field study we obtain a brine volume of 2 % to 3 % as a threshold for the vertical permeability (transition to impermeable sea ice). We are able to relate this transition to the necking of brine pores at a critical pore throat diameter of ≈0.07 mm, being consistent with some limited pore analysis from earlier studies. Our optimal estimate of critical brine porosity is half the value of 5 % proposed in earlier work and frequently adopted in sea ice model studies and applications. By placing our results in the broader context of earlier studies, we conclude that the present threshold is more significant in that our centrifuge experiments and high-resolution 3D image analysis enable us to more accurately identify the threshold below which fluid connectivity ceases by examining the brine inclusion microstructure on finer scales than were previously possible. We also find some evidence that the sea ice pore space should be described by directed rather than isotropic percolation. Our revised porosity threshold is valid for the permeability of young columnar sea ice dominated by primary pores. For older sea ice containing wider secondary brine channels, for granular sea ice and for the full-thickness bulk permeability, other thresholds may apply.

scholarly journals An X-ray micro-tomographic study of the pore space, permeability and percolation threshold of young sea ice

2020 ◽  
Author(s):  
Sönke Maus ◽  
Martin Schneebeli ◽  
Andreas Wiegmann
Keyword(s):  
Sea Ice ◽  
Pore Space ◽  
Permeability Transition ◽  
Hydraulic Permeability ◽  
X Ray ◽  
Model Studies ◽  
Vertical Permeability ◽  
Porosity And Permeability ◽  
Brine Volume

Abstract. The hydraulic permeability of sea ice is an important property that influences the role of sea ice in the environment in many ways. As it is difficult to measure, so far not many observations exist and the quality of deduced empirical relationships between porosity and permeability is unknown. The present work presents a study of the permeability of young sea ice based on the combination of X-ray tomographic imaging and direct numerical simulations. The approach is new for sea ice. It allows to relate the permeability and percolation properties explicitly to characteristic properties of the sea ice pore space, in particular to pore size and connectivity metrics. For the young ice from the present field study we obtain a brine volume of 2.4 ± 0.3 % as threshold for the vertical permeability (transition to impermeable sea ice). We are able to relate this transition to the necking of brine pores at a critical pore throat diameter of ≈ 0.07 mm, being consistent with some limited pore analysis from earlier studies. The obtained critical brine porosity is considerably smaller than the value of 5 % proposed in earlier work and frequently adopted in sea ice model studies and applications. We revise the uncertainties associated with earlier estimates suggesting that the present result is more accurate. We then propose a consistent parametrisation for the permeability of young sea ice that will be useful for modelling. The study highlights the large potential of X-ray tomography, in combination with appropriate sampling, storage and processing, to derive physical properties of sea ice.

Permeability of growing sea ice - observations, modelling and some implications for thinning Arctic sea ice

2020 ◽  
Author(s):  
Sönke Maus
Keyword(s):  
Sea Ice ◽  
Pore Space ◽  
Arctic Sea Ice ◽  
Heat Fluxes ◽  
Onset Of Convection ◽  
Permeability Model ◽  
Electrically Conducting ◽  
Melt Pond ◽  
Starting Point

<p>The permeability of sea ice is an important property with regard to the role of sea ice in the earth system. It controls fluid flow within sea ice, and thus processes like melt pond drainage, desalination and to some degree heat fluxes between the ocean and the atmosphere. It also impacts the role of sea ice in hosting sea ice algae and organisms, and the uptake and release of nutrients and pollutants from Arctic surface waters. However, as it is difficult to measure in the field, observations of sea ice permeability are sparse and vary, even for similar porosity, over orders of magnitude. Here I present progress on this topic in three directions. First, I present results from numerical simulations of the permeability of young sea ice based on 3-d X-ray microtomographic images (XRT). These results provide a relationship between permeability and brine porosity of young columnar sea ice for the porosity range 2 to 25 %. The simulations also show that this ice type is permeable and electrically conducting down to a porosity of 2 %, considerably lower than what has been proposed in previous work. Second, the XRT-based simulations are compared to predictions based on a novel crystal growth modelling approach, finding good agreement. Third, the permeability model provides a relationship between sea ice growth velocity and permeability. Based on this relationshiop interesting aspects of the growth of permeable sea ice can be deduced: The predictions consistently explain observations of the onset of convection from growing sea ice. They also allow for an evaluation of expected permeability changes for a thinning sea ice cover in a warmer climate. As the model is strictly valid for growing and cooling sea ice, the results are mostly relevant for sea ice desalination processes during winter. Modelling permeability of summer ice (and melt pond drainage) will require more observations of the pore space evolution in warming sea ice, for which the present results can be considered as a resonable starting point.</p>

scholarly journals Imaging air volume fraction in sea ice using non-destructive X-ray tomography

2016 ◽  
Vol 10 (3) ◽  
pp. 1125-1145 ◽  
Author(s):  
Odile Crabeck ◽  
Ryan Galley ◽  
Bruno Delille ◽  
Brent Else ◽  
Nicolas-Xavier Geilfus ◽  
...  
Keyword(s):  
Sea Ice ◽  
Volume Fraction ◽  
Gas Bubbles ◽  
Internal Layers ◽  
X Ray ◽  
Air Volume ◽  
Air Interface ◽  
Saturation Factor ◽  
Brine Volume ◽  
Non Destructive

Abstract. Although the presence of a gas phase in sea ice creates the potential for gas exchange with the atmosphere, the distribution of gas bubbles and transport of gases within the sea ice are still poorly understood. Currently no straightforward technique exists to measure the vertical distribution of air volume fraction in sea ice. Here, we present a new fast and non-destructive X-ray computed tomography technique to quantify the air volume fraction and produce separate images of air volume inclusions in sea ice. The technique was performed on relatively thin (4–22 cm) sea ice collected from an experimental ice tank. While most of the internal layers showed air volume fractions  <  2 %, the ice–air interface (top 2 cm) systematically showed values up to 5 %. We suggest that the air volume fraction is a function of both the bulk ice gas saturation factor and the brine volume fraction. We differentiate micro bubbles (Ø  <  1 mm), large bubbles (1 mm  <  Ø  <  5 mm) and macro bubbles (Ø  >  5 mm). While micro bubbles were the most abundant type of gas bubbles, most of the air porosity observed resulted from the presence of large and macro bubbles. The ice texture (granular and columnar) as well as the permeability state of ice are important factors controlling the air volume fraction. The technique developed is suited for studies related to gas transport and bubble migration.

scholarly journals Reliable estimation of hydraulic permeability from 3D X-ray CT images of porous rock

2020 ◽  
Vol 205 ◽  
pp. 08004
Author(s):  
Eomzi Yang ◽  
Dong Hun Kang ◽  
Tae Sup Yun
Keyword(s):  
Pore Structure ◽  
Structural Information ◽  
Pore Space ◽  
Finite Size ◽  
Image Resolution ◽  
Accurate Estimation ◽  
Hydraulic Permeability ◽  
Related Phenomenon ◽  
X Ray ◽  
Segmentation Methods

The hydraulic permeability is a key parameter for simulating the flow-related phenomenon so that its accurate estimation is crucial in both experimental and numerical simulation studies. 3D pore structure can be readily taken by X-ray computed tomography (CT) and it often serves as a flow domain for pore-scale simulation. However, one encounters the challenges in segmenting the authentic pore structure owing to the finite size of image resolution and segmentation methods. Therefore, the loss of structural information in pore space seems unavoidable to result in the unreliable estimation of permeability. In this study, we propose a novel framework to overcome these limitations by using a flexible ternary segmentation scheme. Given the pore size distribution curve and porosity, three phases of pore, solid, and gray regions are segmented by considering the partial volume effect which holds the composition information of unresolved objects. The resolved objects such as solid and pore phases are taken to equivalently solve Stokes equation while the fluid flow through unresolved objects is simultaneously solved by Stokes-Brinkmann equation. The proposed numerical scheme to obtain the permeability is applied to Indiana limestone and Navajo sandstone. The results show that the computed hydraulic permeability is similar to the experimentally obtained value without being affected by image resolution. This approach has advantages of achieving consistent permeability values, less influenced by segmentation methods.

A directed percolation model for the permeability of young sea ice

2021 ◽  
Author(s):  
Sönke Maus
Keyword(s):  
Sea Ice ◽  
Pore Space ◽  
Thermal Fluctuations ◽  
Percolation Model ◽  
First Year ◽  
Directed Percolation ◽  
Pore Networks ◽  
Melt Pond ◽  
Starting Point

&lt;p&gt;The permeability of sea ice is an important property with regard to the role of sea ice in the earth system. It controls fluid flow within sea ice, and thus affects processes like desalination and melt pond drainage. It also impacts the role of sea ice in hosting sea ice algae and organisms, and the uptake and release of nutrients and pollutants from Arctic surface waters. However, as sea ice permeability is difficult to measure in the field, observations are sparse and vary, even for similar porosity, over orders of magnitude. This range is related to the evolution of the sea ice pore space during aging from young ice to thick first year ice. In young ice, the pore network is dominated by primary pores constrained by brine layers and the near-interface microstructure. In older sea ice, the ongoing desalination and thermal fluctuations have created wider secondary brine channels, implying a several orders of magnitude higher permeability. It is a challenge to understand and model these changes in pore space and permeability. Here a directed percolation model for the permeability of young sea ice is proposed. The model describes the dependence of sea ice permeability and electrical conductivity on brine porosity, and its critical behaviour and percolation transition due to necking of pores, and related disconnection of pore networks. Its parameters are based on 3D X-ray micro-tomographic imaging of young sea ice and direct numerical simulation of its transport properties, that strongly support the application of directed percolation theory to young sea ice, with a threshold porosity (impermeable ice) of 2 to 3 percent. Combined to an approach to predict the crystal structure at the ice-ocean interface, the model also the growth-velocity dependence and evolution of permeability near the ice-ocean interface. As the model is strictly valid for growing and cooling sea ice, without present of wider secondary brine channels, it is mostly relevant for sea ice desalination processes during winter. Modelling permeability of older and summer ice (and melt pond drainage) will require more observations of the pore space evolution in warming sea ice, for which the present results can be considered as a starting point.&lt;/p&gt;

Digital x-ray mapping of nanometer-size supported bimetallic catalysts

1988 ◽  
Vol 46 ◽  
pp. 530-531
Author(s):  
L. T. Germinario
Keyword(s):  
Background Radiation ◽  
Metal Cluster ◽  
Single Element ◽  
Beam Diameter ◽  
X Rays ◽  
X Ray ◽  
Major Interest ◽  
Induced Changes

Understanding the role of metal cluster composition in determining catalytic selectivity and activity is of major interest in heterogeneous catalysis. The electron microscope is well established as a powerful tool for ultrastructural and compositional characterization of support and catalyst. Because the spatial resolution of x-ray microanalysis is defined by the smallest beam diameter into which the required number of electrons can be focused, the dedicated STEM with FEG is the instrument of choice. The main sources of errors in energy dispersive x-ray analysis (EDS) are: (1) beam-induced changes in specimen composition, (2) specimen drift, (3) instrumental factors which produce background radiation, and (4) basic statistical limitations which result in the detection of a finite number of x-ray photons. Digital beam techniques have been described for supported single-element metal clusters with spatial resolutions of about 10 nm. However, the detection of spurious characteristic x-rays away from catalyst particles produced images requiring several image processing steps.

The role of silicon in forages: A quantitative X-Ray study

1987 ◽  
Vol 45 ◽  
pp. 416-417
Author(s):  
Janet H. Woodward ◽  
D. E. Akin
Keyword(s):  
Sodium Acetate ◽  
Dry Matter ◽  
Acetate Buffer ◽  
Plant Tissues ◽  
Sodium Acetate Buffer ◽  
X Ray ◽  
Dry Matter Digestibility ◽  
Percent Composition

Silicon (Si) is distributed throughout plant tissues, but its role in forages has not been clarified. Although Si has been suggested as an antiquality factor which limits the digestibility of structural carbohydrates, other research indicates that its presence in plants does not affect digestibility. We employed x-ray microanalysis to evaluate Si as an antiquality factor at specific sites of two cultivars of bermuda grass (Cynodon dactvlon (L.) Pers.). “Coastal” and “Tifton-78” were chosen for this study because previous work in our lab has shown that, although these two grasses are similar ultrastructurally, they differ in in vitro dry matter digestibility and in percent composition of Si.Two millimeter leaf sections of Tifton-7 8 (Tift-7 8) and Coastal (CBG) were incubated for 72 hr in 2.5% (w/v) cellulase in 0.05 M sodium acetate buffer, pH 5.0. For controls, sections were incubated in the sodium acetate buffer or were not treated.

Pathophysiological function of the mitochondria as a calcium reservoir: Quantitative x-ray microanalysis

1990 ◽  
Vol 48 (2) ◽  
pp. 164-165
Author(s):  
K. Teraoka ◽  
N. Kaneko ◽  
Y. Horikawa ◽  
T. Uchida ◽  
R. Matsuda ◽  
...  
Keyword(s):  
Bolus Injection ◽  
Contact Method ◽  
X Ray

The aim of this study was to elucidate the role of the mitochondria as a store of calcium(Ca) under the condition of pathophysiological Ca overload induced by a rise in extracellular Ca concentration and the administration of isoproterenol.Eight rats were employed, and hearts were perfused as in the Langendorff method with Krebs-Henseleit solution gassed with 95% O2 and 5% CO2. Tow specimens were perfused with 2mM Ca for 30 min, and 2 were perfused with 5.5 mM Ca for 20 min. 4 specimens were perfused with 2 mM Ca for 5 min, and of these 4, 2 were infused with 10-7 mM/kg/min. isoproterenol for 5 min, and 2 were given a bolus injection of 3 x 10-7 mM isoproterenol. After rapid-cryofixation by the metal-mirror contact method with a Reichert-Jung KF80/MM80, and cryosectioning at -160 to -180° C with a Reichert-Jung Ultracut Fc-4E, ultrathin specimens (100nm) were free-ze-dreid for several hours at 10-5 Torr in the JEOL FD 7000, and mitochondrial Ca was determined by quantitative x-ray micranalysis (JEOL 1200EX, LINK AN 10000S).

Ionic homeostasis and subcellular element compartmentation

1990 ◽  
Vol 48 (2) ◽  
pp. 150-151
Author(s):  
Ann LeFurgey ◽  
Peter Ingram ◽  
J.J. Blum ◽  
M.C. Carney ◽  
L.A. Hawkey ◽  
...  
Keyword(s):  
Leishmania Major ◽  
Ionic Homeostasis ◽  
X Ray ◽  
Functional Studies ◽  
Cell Compartments ◽  
X Ray Imaging ◽  
Resolution Electron ◽  
Multiple Cell ◽  
Role Of Zn

Subcellular compartments commonly identified and analyzed by high resolution electron probe x-ray microanalysis (EPXMA) include mitochondria, cytoplasm and endoplasmic or sarcoplasmic reticulum. These organelles and cell regions are of primary importance in regulation of cell ionic homeostasis. Correlative structural-functional studies, based on the static probe method of EPXMA combined with biochemical and electrophysiological techniques, have focused on the role of these organelles, for example, in maintaining cell calcium homeostasis or in control of excitation-contraction coupling. New methods of real time quantitative x-ray imaging permit simultaneous examination of multiple cell compartments, especially those areas for which both membrane transport properties and element content are less well defined, e.g. nuclei including euchromatin and heterochromatin, lysosomes, mucous granules, storage vacuoles, microvilli. Investigations currently in progress have examined the role of Zn-containing polyphosphate vacuoles in the metabolism of Leishmania major, the distribution of Na, K, S and other elements during anoxia in kidney cell nuclel and lysosomes; the content and distribution of S and Ca in mucous granules of cystic fibrosis (CF) nasal epithelia; the uptake of cationic probes by mltochondria in cultured heart ceils; and the junctional sarcoplasmic retlculum (JSR) in frog skeletal muscle.

Silicon Substitution for Calcium in the Shell of the Fingernail Clam, Musculium Transversum Studied By X-Ray Analysis

1980 ◽  
Vol 38 ◽  
pp. 560-561
Author(s):  
Judith A. Murphy ◽  
Anthony Paparo ◽  
Richard Sparks
Keyword(s):  
Carbonic Anhydrase ◽  
River Water ◽  
Food Chains ◽  
Well Water ◽  
Shell Formation ◽  
X Ray ◽  
Molluscan Shell ◽  
Fingernail Clams

Fingernail clams (Muscu1ium transversum) are dominant bottom-dwelling animals in some waters of the midwest U.S. These organisms are key links in food chains leading from nutrients in water and mud to fish and ducks which are utilized by man. In the mid-1950’s, fingernail clams disappeared from a 100-mile section of the Illinois R., a tributary of the Mississippi R. Some factor(s) in the river and/or sediment currently prevent clams from recolonizing areas where they were formerly abundant. Recently, clams developed shell deformities and died without reproducing. The greatest mortality and highest incidence of shell deformities appeared in test chambers containing the highest proportion of river water to well water. The molluscan shell consists of CaCO3, and the tissue concerned in its secretion is the mantle. The source of the carbonate is probably from metabolic CO2 and the maintenance of ionized Ca concentration in the mantle is controlled by carbonic anhydrase. The Ca is stored in extracellular concentric spherical granules(0.6-5.5μm) which represent a large amount of inertCa in the mantle. The purpose of this investigation was to examine the role of raw river water and well water on shell formation in the fingernail clam.

Sign in / Sign up

Export Citation Format

Share Document