Transformation of the groundwater composition in coastal zone of the Ivankovo reservoir during 20 years
The Ivankovo reservoir is an important source of drinking water for the city of Moscow. The water quality status of aquifers around the reservoir is important for its safety, as groundwater inflow into the reservoir is considerable. The chemical composition of the shallow groundwater around the Ivankovo reservoir is studied. The study is based on long-term monitoring (1999–2019) of both surface and groundwater quality. The aim of the paper is to identify changes in groundwater quality over this period and to determine their causes. The results show that over this 20 year-period, the groundwater quality in the study area shifted from HCO3–Ca to HCO3–Ca-Mg type, proven by statistical methods. The median values of the total dissolved solids (TDS) decreased by 13% in summer and by 17% in winter. It is shown that the ongoing processes of transformation of the groundwater chemical composition are mainly due to climate change, and atmospheric precipitation in the spring-winter period is a possible source of the Mg2+ ion entering the groundwater table. Among other components, concentrations of chlorides and sulfates underwent the largest change, the median values of which have decreased by two or more times, which is caused by both the dilution of the groundwater by melt water and a decrease in the anthropogenic load.