scholarly journals Stabilized Organic Matter Quantities May Strongly Affect the Mobility of Glyphosate into Soil

2016 ◽  
Vol 8 (9) ◽  
pp. 135 ◽  
Author(s):  
Paulo Roberto Dores-Silva ◽  
Fernanda Benetti ◽  
Bruno Molero Silva ◽  
Maria Diva Landgraf ◽  
Maria Olímpia Oliveira Rezende
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Humic Substances ◽  
Acid Medium ◽  
Interaction Mechanism ◽  
Tropical Soils ◽  
Water Bodies ◽  
Adsorption Potential ◽  
The World

<p>Glyphosate [N-(phosphonomethyl) glycine] is an enzyme inhibiting herbicide, which is widely used in the world. Here, we investigate the glyphosate adsorption potential in tropical soils with pH close to 5. The herbicide was determined via HPLC with detection by UV-Vis. Our results suggest that glyphosate interacts especially with the stabilized organic matter. Thus, even with large amounts of soil organic matter, the soils may not be as effective in the adsorption of the herbicide if they do not also possess high percentage of humic substances. These data are worth far as it allows us to speculate on glyphosate interaction mechanism with the humic substances in slightly acid medium, in addition, also enable us to propose the use of that fraction of the organic matter to immobilize part of the herbicide in the soil and inhibiting its leaching into water bodies.</p>

scholarly journals Characterization of Soil Organic Matter Individual Fractions (Fulvic Acids, Humic Acids, and Humins) by Spectroscopic and Electrochemical Techniques in Agricultural Soils

Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1067
Author(s):  
Aleksandra Ukalska-Jaruga ◽  
Romualda Bejger ◽  
Guillaume Debaene ◽  
Bożena Smreczak
Keyword(s):  
Molecular Weight ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Humic Substances ◽  
Humic Acids ◽  
Agricultural Soils ◽  
Fulvic Acids ◽  
Sorption Properties ◽  
Aliphatic Chains

The objective of this paper was to investigate the molecular characterization of soil organic matter fractions (humic substances (HS): fulvic acids-FAs, humic acids-HAs, and humins-HNs), which are the most reactive soil components. A wide spectrum of spectroscopic (UV–VIS and VIS–nearIR), as well as electrochemical (zeta potential, particle size diameter, and polydispersity index), methods were applied to find the relevant differences in the behavior, formation, composition, and sorption properties of HS fractions derived from various soils. Soil material (n = 30) used for the study were sampled from the surface layer (0–30 cm) of agricultural soils. FAs and HAs were isolated by sequential extraction in alkaline and acidic solutions, according to the International Humic Substances Society method, while HNs was determined in the soil residue (after FAs and HAs extraction) by mineral fraction digestion using a 0.1M HCL/0.3M HF mixture and DMSO. Our study showed that significant differences in the molecular structures of FAs, Has, and HNs occurred. Optical analysis confirmed the lower molecular weight of FAs with high amount of lignin-like compounds and the higher weighted aliphatic–aromatic structure of HAs. The HNs were characterized by a very pronounced and strong condensed structure associated with the highest molecular weight. HAs and HNs molecules exhibited an abundance of acidic, phenolic, and amine functional groups at the aromatic ring and aliphatic chains, while FAs mainly showed the presence of methyl, methylene, ethenyl, and carboxyl reactive groups. HS was characterized by high polydispersity related with their structure. FAs were characterized by ellipsoidal shape as being associated to the long aliphatic chains, while HAs and HNs revealed a smaller particle diameter and a more spherical shape caused by the higher intermolecular forcing between the particles. The observed trends directly indicate that individual HS fractions differ in behavior, formation, composition, and sorption properties, which reflects their binding potential to other molecules depending on soil properties resulting from their type. The determined properties of individual HS fractions are presented as averaged characteristics over the examined soils with different physico-chemical properties.

scholarly journals ORGANIC CARBON DYNAMICS IN GRASSLAND SOILS. 1. BACKGROUND INFORMATION AND COMPUTER SIMULATION

1981 ◽  
Vol 61 (2) ◽  
pp. 185-201 ◽  
Author(s):  
J. A. VAN VEEN ◽  
E. A. PAUL
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Experimental Studies ◽  
Decay Rates ◽  
Background Information ◽  
Plant Residues ◽  
Decomposition Rates ◽  
Straw Decomposition ◽  
Soil Biomass ◽  
The World

The decomposition rates of 14C-labelled plant residues in different parts of the world were characterized and mathematically simulated. The easily decomposable materials, cellulose and hemicellulose, were described as being decomposed directly by the soil biomass; the lignin fraction of aboveground residues and the resistant portion of the roots entered a decomposable native soil organic matter. Here it could be decomposed by the soil biomass or react with other soil constituents in the formation of more recalcitrant soil organic matter. The transformation rates were considered to be independent of biomass size (first–order). Data from 14C plant residue incorporation studies which yielded net decomposition rates of added materials and from carbon dating of the recalcitrant soil organic matter were transformed to gross decomposition rate constants for three soil depths. The model adequately described soil organic matter transformations under native grassland and the effect of cultivation on organic matter levels. Correction for microbial growth and moisture and temperature variations showed that the rate of wheat straw decomposition, based on a full year in the field in southern Saskatchewan, was 0.05 that under optimal laboratory conditions. The relative decay rates for plant residues during the summer months of the North American Great Plains was 0.1 times that of the laboratory. Comparison with data from other parts of the world showed an annual relative rate of 0.12 for straw decomposition in England, whereas gross decomposition rates in Nigeria were 0.5 those of laboratory rates. Both the decomposable and recalcitrant organic matter were found to be affected by the extent of physical protection within the soil. The extent of protection was simulated and compared to data from experimental studies on the persistence of 14C-labelled amino acids in soil. The extent of protection influenced the steady-state levels of soil carbon upon cultivation more than did the original decomposition rates of the plant residues.

scholarly journals Differences in soil organic matter and humus of sandy soil after application of biochar substrates and combination of biochar substrates with mineral fertilizers

2020 ◽  
Vol 23 (3) ◽  
pp. 117-124
Author(s):  
Dušan Šrank ◽  
Vladimír Šimanský
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Carbon Content ◽  
Humic Substances ◽  
Sandy Soil ◽  
The Other ◽  
Mineral Fertilizers ◽  
Other Hand ◽  
Sheep Manure ◽  
The Impact

The effort to achieve the sustainable farming system in arable soil led to the intensive search for a new solution but an inspiration can also be found in the application of traditional methods of soil fertility improvement as it is shown in numerous examples in history. Recently many scientific teams have focused their attention on the evaluation of biochar effects on soil properties and crop yields. Since there are a lot of knowledge gaps, especially in explanations how biochar can affect soil organic matter (SOM) and humus substances, we aimed this study at the solution of these questions. Therefore, the objective of the experiment was to evaluate the impact of two biochar substrates (B1 – biochar blended with sheep manure, and B2 – biochar blended with sheep manure and the residue from the biogas station) at two rates (10 and 20 t ha-1) applied alone or in combination with mineral fertilizers (Urea was applied in 2018, at rate 100 kg ha-1, and Urea at rate 100 kg ha-1 + AMOFOS NP 12-52 at 100 kg ha-1 were applied in 2019) on the quantity and quality of SOM and humus of sandy soil (Arenosol, Dolná Streda, Slovakia). The results showed that application of the biochar substrates together with mineral fertilizers (MF) had more pronounced effect on the organic matter mineralization in the sandy soil which resulted in low accumulation of soil organic carbon (Corg) and labile carbon compared to biochar substrates treatments without MF. The share of humic substances in Corg significantly decreased by 16, 50, 16 and 24% in B1 at 10 t ha-1, B1 at 20 t ha-1, B2 at 10 t ha-1 and B2 at 20 t ha-1 treatments, respectively, compared to the control. A similar tendency was observed for biochar substrates treatments + MF, compared to MF control. The carbon content of humic substances (CHS) was equal to 4.40 – 5.80 g kg-1 and the biochar substrates had statistically significant influence on CHS content. On average, there was a smaller decrease of CHS in B1 at rate 10 t ha-1 than at rate 20 t ha-1 and no effect of B2 compared to control. The carbon content of fulvic acid (CFA) was 9% higher in B1 at 10 t ha-1, and 20 t ha-1, 47% higher in B2 at 10 t ha-1 and 17% higher in B2 at 20 t ha-1 compared to control. As a result of biochar substrates + MF application, the reduction in CFA was observed. The results showed a decrease of CHA : CFA ratio with association to biochar substrates alone application compared to control on one hand, and a wider of CHA : CFA ratio in biochar substrates + MF treatments in comparison to MF control on the other hand. Humus stability was increased in biochar substrates alone treatments compared to control, on the other hand, compared to MF control, the application of biochar substrates + MF resulted in a lower humus stability.

scholarly journals CO2-C losses and carbon quality of selected Maritime Antarctic soils

2012 ◽  
Vol 25 (1) ◽  
pp. 11-18 ◽  
Author(s):  
Juliana Vanir De Souza Carvalho ◽  
Eduardo De Sá Mendonça ◽  
Newton La Scala ◽  
César Reis ◽  
Efrain Lázaro Reis ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Temperature ◽  
Soil Carbon ◽  
Humic Substances ◽  
Microbial Activity ◽  
Chemical Characteristics ◽  
Maritime Antarctic ◽  
Antarctic Soils ◽  
Humification Degree

AbstractPolar Regions are the most important soil carbon reservoirs on Earth. Monitoring soil carbon storage in a changing global climate context may indicate possible effects of climate change on terrestrial environments. In this regard, we need to understand the dynamics of soil organic matter in relation to its chemical characteristics. We evaluated the influence of chemical characteristics of humic substances on the process of soil organic matter mineralization in selected Maritime Antarctic soils. A laboratory assay was carried out with soils from five locations from King George Island. We determined the contents of total organic carbon, oxidizable carbon fractions of soil organic matter, and humic substances. Two in situ field experiments were carried out during two summers, in order to evaluate the CO2-C emissions in relation to soil temperature variations. The overall low amounts of soil organic matter in Maritime Antarctic soils have a low humification degree and reduced microbial activity. CO2-C emissions showed significant exponential relationship with temperature, suggesting a sharp increase in CO2-C emissions with a warming scenario, and Q10 values (the percentage increase in emission for a 10°C increase in soil temperature) were higher than values reported from elsewhere. The sensitivity of the CO2-C emission in relation to temperature was significantly correlated with the humification degree of soil organic matter and microbial activity for Antarctic soils.

A molecular dynamic study of Soil Organic Matter stabilization mechanisms

2021 ◽  
Author(s):  
Edgar Galicia-Andrés ◽  
Yerko Escalona ◽  
Peter Grančič ◽  
Chris Oostenbrink ◽  
Daniel Tunega ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Humic Substances ◽  
Clay Mineralogy ◽  
Metal Cations ◽  
Dense Matter ◽  
Chemical Degradation ◽  
Molecular Graphics ◽  
Organic Matter Stabilization ◽  
Reactive Surfaces

&lt;p&gt;It is well known that some fractions of soil organic matter (SOM) can resist to physical and (bio)chemical degradation which can be attributed to factors ranging from molecular properties to the preference for digesting other molecular species by microorganisms. Some mechanisms, by which organic matter is protected, are often referred to as: physical stabilization through microaggregation, chemical stabilization by formation of SOM-mineral aggregates, and biochemical stabilization through the formation of recalcitrant SOM.&lt;/p&gt;&lt;p&gt;Protection mechanisms are responsible for the accumulation process of organic carbon, reducing the exposure of organic matter and making it less vulnerable to microbial, enzymatic or chemical attacks. In these mechanisms, water molecular bridges and metal cation bridges play a key role. Cation bridges serve as aggregation sites on humic substances, forming dense matter, in comparison to systems where bridges are missing. This effect is enhanced in systems with cations at higher oxidation states.&lt;/p&gt;&lt;p&gt;By using the modeler tool developed in our group (Vienna Soil&amp;#8211;Organic&amp;#8211;Matter Modeler, VSOMM2) (Escalona et al., 2021), we generated aggregate models of humic substances at atomistic scale reflecting the diversity in composition, size and conformations of the constituting molecules. Further, we built models of organo-clay aggregates using kaolinite and montmorillonite as typical soil minerals. This allowed a systematic study to understand the effect of the surrounding environment at microscopic scale, not fully accessible experimentally.&lt;/p&gt;&lt;p&gt;Molecular simulations of the adsorption process of SOM aggregates on the reactive surfaces of led to two observations: 1) the humic substances aggregates were able to interact with the reactive surfaces mainly via hydrogen bonds forming stable organic matter-clay complexes and 2) the aggregates subsequently lost rigidity and stability after metal cations removing, consequently leading to a gradual loss of humic substance molecules, evidencing the role of metal cations in the protection mechanism of soil organic matter aggregates and possibly explaining its recalcitrance (Galicia-Andr&amp;#233;s et al., 2021).&lt;/p&gt;&lt;p&gt;References&lt;/p&gt;&lt;ul&gt;&lt;li&gt;Escalona, Y., Petrov, D., &amp; Oostenbrink, C. (2021). Vienna soil organic matter modeler 2 (VSOMM2). Journal of Molecular Graphics and Modelling, 103, 107817. https://doi.org/10.1016/j.jmgm.2020.107817&lt;/li&gt; &lt;li&gt;Galicia-Andr&amp;#233;s, E., Gran&amp;#269;i&amp;#269;, P., Gerzabek, M. H., Oostenbrink, C., &amp; Tunega, D. (2021). Modeling of interactions in natural and synthetic organoclays. In I. C. Sainz Diaz (Ed.), Computational modeling in clay mineralogy.&lt;/li&gt; &lt;/ul&gt;

Sulfur forms in bulk soils and alkaline soil extracts of tropical mountain ecosystems in northern Thailand

Soil Research ◽  
2002 ◽  
Vol 40 (1) ◽  
pp. 161 ◽  
Author(s):  
A. Möller ◽  
K. Kaiser ◽  
N. Kanchanakool ◽  
C. Anecksamphant ◽  
W. Jirasuktaveekul ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Tropical Soils ◽  
Forest Site ◽  
Alkaline Soil ◽  
Northern Thailand ◽  
Total N ◽  
Soil Extracts ◽  
Organic C ◽  
Organic S

Sulfur, besides phosphorus, is crucial for the nutrition of plants on tropical soils. Its availability is closely related to the turnover of soil organic matter. To get a better insight into transformation of soil S forms during the decomposition of organic matter, we studied inorganic and organic S pools in bulk samples and alkaline extracts of soils under different land uses representative of the tropical highlands of northern Thailand. Samples were taken from a cabbage cultivation, a Pinus reforestation, a secondary forest, and a primary forest. Total S ranged from 483 549 mg&sol;kg in the subsoil to 1909 376 mg&sol;kg in the organic layers, which is relatively high for tropical soils. The major S component in soil was organic S, comprising 75–99&percnt; of total S. Organic S was significantly correlated with total S, organic C, and total N, indicating that there is a close relationship between C, N, and S cycling in soil. C-bonded S was the predominant form in the topsoils (35–99&percnt; of total S) but its presence decreased with soil depth. The maximum concentrations of ester SO4-S were found in the A horizons (128 49 mg&sol;kg), whereas the concentrations of inorganic SO4-S were small in all horizons. Compared with the forest site, the cabbage cultivation site was strongly depleted in S. C-bonded S was more depleted than ester SO4-S. A comparison of the S forms in NaOH extracts with S forms in bulk soil and C forms as indicated by 13C-NMR spectroscopy showed (i) that the extracts were very representative of soil organic S fractions and (ii) that ester SO4-S was mainly associated with O-substituted aliphatic C. In contrast, C-bonded S seemed to be connected to more-or-less all C binding types. transformation of soil organic matter, sulfate.

Changes in soil organic matter and soil humic substances following the afforestation of former agricultural lands in the boreal-nemoral ecotone (Latvia)

2019 ◽  
Vol 16 ◽  
pp. e00213 ◽  
Author(s):  
Imants Kukuļs ◽  
Māris Kļaviņš ◽  
Oļģerts Nikodemus ◽  
Raimonds Kasparinskis ◽  
Guntis Brūmelis
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Humic Substances ◽  
Agricultural Lands

No isotopic evidence for a differential mineralization of old soil organic matter in sandy, nutrient-poor, tropical soils under eucalypts and acacias

2016 ◽  
Vol 76 ◽  
pp. 92-94
Author(s):  
Daniel Epron ◽  
Sogni Viviane Tchichelle ◽  
Yann Nouvellon ◽  
Louis Mareschal ◽  
Lydie-Stella Koutika
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Tropical Soils ◽  
Isotopic Evidence
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