scholarly journals Evaluation of the effects of fires and explosions in the transport of hazardous materials

2015 ◽  
Vol 34 (2) ◽  
pp. 7-18 ◽  
Author(s):  
Marc J. Assael ◽  
Leandros Ch. Paschalidis ◽  
George P. Sakellaropoulos

Transportation of liquid and gaseous fuels and chemicals, albeit not frequent, can lead to serious dangers for humans, the environment and property due to fires and explosions. The two most common transportation modes on land are tanker trucks and pipelines. The effects of fires and explosions in such transportations can be modelled successfully to describe observed damages, as discussed here for three different types of accidents, namely tanker trucks carrying liquefied natural gas (LNG) or liquefied petroleum gas (LPG), and a gas pipeline, resulting in ignition and explosion. The effects of overpressure due to explosion and of radiated heat by fires are effectively modelled. The methodology and the developed e-platform are valuable teaching tools for engineers and civic personnel in order to foresee and assess risk and accident consequences near inhabited areas, and/or to predict alternate routes.

2021 ◽  
Author(s):  
Guido Zichittella ◽  
Javier Pérez-Ramírez

We critically review the recent advances in process, reactor, and catalyst design that enable process miniaturisation for decentralised natural gas upgrading into electricity, liquefied natural gas, fuels and chemicals.


2017 ◽  
Vol 2 (5) ◽  
pp. 20
Author(s):  
Jafaar A. Kadhem ◽  
Khalid Sadiq Reza ◽  
Wahab K. Ahmed

The Iraq air is polluted highly by pollutants emitted from automobiles and trucks as well as power stations. This pollution resource is well known it is the burning of oil and natural gas. Iraq has been subjected to a series of wars and economic blockade for more than 40 continuing years. The war and blockade conditions have affected all the country's infrastructure causing huge deterioration in the services provided to Iraqi citizens. The Iraqi refineries as well have been subjected to major destruction and reconstruction several times. Unfortunately, the reconstruction in Iraq conditions was not in appropriate level, and for that reason we find the Iraqi gasoline and diesel are one of the worst fuels in the world. All reports demonstrated that the Iraqi gasoline contains high levels of sulfur (500ppm), as well as high levels of lead compounds to increase octane. The Iraqi diesel contains sulfur up to 1 to 2.5% of its weight which makes it the worst globally.In Iraq there are many alternative fuels that generate better engine performance and emit lower exhaust pollutants while improving fuel consumption. This paper reviews some of the Iraqi experimental work during the past ten years and the available results about using gaseous fuels such as natural gas, liquefied petroleum gas and hydrogen. In addition, the study focus on the use of some additives to gasoline and diesel, such as alcohols and biofuels to reduce the effects of sulfur associated with these types of fuel. The Iraqi research works have found many solutions and alternative methods of operation to eliminate the various engines emitted pollutants. The role has now come to the decision makers to legislate the laws and decisions necessary to switch to new types of alternative fuels.


Author(s):  
Par Neiburger

Liberator Engine Company, LLC designs, develops and produces alternative fuel engines for vehicles around the globe. The Company’s 6.0 Liter Liberator™ gaseous fuels engine will have the ability to operate on Compressed Natural Gas, Liquefied Natural Gas or Liquid Propane Gas: clean, domestic, economical fuels. The Liberator engine will target OEM on road vehicles, as well as off road applications. The Liberator engine is also an excellent choice for the repower of existing diesel vehicles. The 6.0L Liberator™ engine will serve as a replacement engine for vehicle currently operating on a Cummins 5.9L diesel engine or Mercedes diesel 6.0L engine. Paper published with permission.


2021 ◽  
Author(s):  
Celestine A. Udie ◽  
Agnes A. Anuka ◽  
Ekpenyong A. Ana

Abstract: Global energy crisis has been on the increase due to increase on energy demand driven by population growth. In attempting to address the global energy crisis, this work uses the alternative resources to diversify the conventional energy sources in order to supplement the available energy generating sources. Energy resources are being evaluated to supplement the conventional energy sources thereby boosting the total energy generation in a nation. Technical and economic models are developed and used to evaluate the energy values in natural gas fractionation. Natural gas fractions evaluated include liquefied natural gas (LNG), liquefied petroleum gas (LPG) and condensate (liquid fuel). Collated field data are inputted into the developed economic models to estimate feasible technical and economic values in each of the gas fractions. The technical and economic analysis revealed that bulk natural gas contains 85.76% liquefied natural gas, 11.61% liquefied petroleum gas and 2.28% condensate (liquid). The result also revealed that natural gas fractionation improves its economic and energy values. With this, it is clear that the improvement in natural gas energy sources has the potency to supplement, hydro-electric power source, coal power source, oil and/or diesel fuel power sources.


Author(s):  
Olivier Benyessaad ◽  
Diane Ruf

The development of the Liquefied Natural Gas (LNG) offshore industry is viewed as a major improvement in the exploitation of the world’s energy resources. Most energy analysts agree that significant increases in Natural Gas (NG) demand is expected in the next decades due to relatively low prices and an important gas quantity worldwide. In order to develop the use of this resource, many innovative offshore floating installations have been developed and are currently deployed all over the world. However, hazards linked to LNG and due to hydrocarbon releases are not always so well understood or controlled. Thus, in order to quantify and understand these risks associated to LNG treatment or containment as well as their consequences, a number of different types of risk and reliability engineering techniques can be used at different stages of the project. The following will present specific analyses that have been performed on innovative LNG Offshore floating units to provide a qualitative and quantitative hazard assessment by predicting the consequences and the frequencies of these hazards, while improving the reliability of the installation and its availability. The paper will first introduce the LNG offshore industry outlining the different installations possibilities and the associated hazards. Then, based on recent projects, it will detail the risk-based methodology applied to ensure the safety and the profitability of such innovative installations when no rules are able to frame fully the development of these projects. Finally, after having pointed out the ins and outs of risk studies, a case study using most of the methods presented previously will be developed.


2021 ◽  
pp. 152-170
Author(s):  
Danilo de Almeida Barbosa ◽  
Fabio Pavan Piccoli ◽  
Daniel dos Santos Moreira

The sloshing problem has been studied in recent decades, as it causes damage to the container structure, caused by hydrodynamic loads. In our work, we show that it is possible to mitigate the action of the fluid on the structure. First, we applied Smoothed Particle Hydrodynamics (SPH) to perform numerical simulations involving the sloshing effect in tanks used to transport Liquefied Petroleum Gas similar to the physical experiments found in the literature. Then, we added (on the container floor) to our numerical model attenuation devices to reduce the sloshing effect. Two types of sloshing suppressors were used, where two different heights are assigned and tested. In addition, we changed the deflector's morphology, leaving it in the shape of an arrow pointing upwards. The results have shown that the baffles can be efficient mechanisms for the suppression of sloshing and that there is a strong relationship between the height of the baffles and the level of fluid concerning the tank.


Author(s):  
Tomohiro Asai ◽  
Keisuke Miura ◽  
Kazuki Abe ◽  
Yoshinori Matsubara ◽  
Tomomi Koganezawa ◽  
...  

Liquefied petroleum gas (LPG) will be suitable for satisfying part of the growing global energy demands. The widespread utilization of LPG as a gas turbine fuel for power generation requires an advanced combustor that achieves dry low nitrogen oxides (NOx) combustion and flashback-resistant combustion. This paper describes the development of a “multi-cluster combustor” as an advanced dry low NOx and flashback-resistant combustion technology for dual gaseous fuels of natural gas and petroleum gas. The dual gaseous fuel capability will contribute to expanding fuel flexibility. The purpose of this paper is to evaluate the feasibility of the dual gaseous fueled combustion with the multi-cluster combustor with the same configuration. The combustor was tested in a single-can combustor test stand at medium pressure with both fuels. In the tests, natural gas consisted mainly of methane with a content of over 90 vol.%, and petroleum gas consisted almost entirely of propane. The test results showed that the combustor achieves dry low NOx combustion of both fuels within their stable ranges without flashback. This paper concluded from the test results that the multi-cluster combustor possesses the potential capability to achieve dry low NOx and flashback-resistant combustion of dual gaseous fuels of natural gas and petroleum gas. As the next step, further tests will be required with petroleum gas including butane and for high pressure conditions.


Author(s):  
Erwan Auburtin ◽  
Eric Morilhat ◽  
Stéphane Paquet ◽  
Abdeslam Raissi ◽  
Ewoud van Haaften ◽  
...  

Abstract Prelude Floating Liquefied Natural Gas (FLNG) facility reached a significant milestone in June 2018 when gas was introduced onboard for the first time as part of the facility startup process, loaded from an LNG carrier moored in side-by-side (SBS) configuration. This first offshore LNG SBS operation allowed Prelude’s utilities to switch from running on diesel to running on gas. SBS mooring is the base case configuration for of floading both LNG and Liquefied Petroleum Gas (LPG) into product carriers using Marine Loading Arms (MLA) once the Prelude FLNG facility is fully operational. These complex and weather sensitive operations are expected to take place on a weekly basis. This means critical decisions about weather-window and timing should be supported as much as possible by predictive analysis and modelling of environment forecasts to reduce the risks. Prelude Floating Liquefied Natural Gas (FLNG) is designed to offload Liquefied Natural Gas (LNG) and Liquefied Petroleum Gas (LPG) to carrier vessels moored in a side-by-side (SBS) configuration, using Marine Loading Arms (MLA) technology. For onshore terminals or small/medium FLNG, the traditional design of MLA (Double Counterweight Marine Arm – DCMA), featuring a vertical riser, can be used. However due to the exceptional freeboard of Prelude a new type of MLA was designed, namely the Offshore Loading Arm Footless (OLAF), without vertical riser in order to reach the LNG or LPG manifolds located as far as about 16 meters below the MLA base. Thanks to the OLAF design, the length and weight of the articulated MLA sections is reduced in comparison with conventional DCMA, and so are the dynamic loads applied by the MLA on the vessel manifold, which was mandatory to remain below the acceptable stress limit of standard LNG/LPG carrier manifolds. OLAF employs the field proven targeting system (TS) allowing the connection and disconnection of the MLA to the vessel manifold in dynamic conditions. This paper describes the assumptions and process to design and validate this new system — in terms of overall geometry and structural design, while verifying project feasibility, aiming at a reliable design of all components and minimizing the risks during operations. The key challenges and lessons learnt are also discussed. This innovative type of MLA had to be thoroughly designed and tested before being manufactured and assembled on the FLNG. The innovation management was also coupled with the additional challenge imposed by the expected highly dynamic conditions of relative motion between vessels that were never encountered for such systems in the past. MLA were designed with the objective to cover the operable envelope induced by berthing, mooring and relative motion criteria, so that it should not become an additional criterion in general. Since such an envelope is larger for this offshore application compared to sheltered terminals, this objective was particularly challenging but could be met thanks to the OLAF design. The SBS hydrodynamic numerical model is based on potential theory and includes multi-body coupling, non-linear mooring characteristics and coupling with sloshing. This model was calibrated using wave basin tests with a good agreement, and was used to determine the maximum operable environments and associated MLA envelope, using a 39-year hindcast for various LNG carriers and considering a scenario with different criteria and loading conditions. More than 100,000 time-domain simulations were required to evaluate non-linear quantities on a reduced set of environment ‘bins’. The new OLAF-type MLA was developed using these hydrodynamic simulations. Specific processes — based on spectral screening and selection using relevant criteria — were used to identify and select, in a systematic way, the designing load cases for connecting, connected, and emergency disconnection cases, while complying with the maximum allowable loads of conventional LNG and LPG carrier manifolds. An instrumented 1:4 OLAF scale model was built and tested with 6 degrees of freedom hexapods reproducing the motions on both sides of the OLAF which enabled us to confirm a 10% accuracy of the numerical studies results. The actual OLAF were dynamically tested with a full scale motion simulator before shipment to the yard for installation. The successful first operations were performed safely and confirmed the validity of the design. Measurements are now collected onboard Prelude to verify the design and when possible improve the accuracy of numerical modelling.


Author(s):  
Emiliano Pipitone ◽  
Stefano Beccari

Gaseous fuels, such as Liquefied Petroleum Gas (LPG) and Natural Gas (NG), thank to their good mixing capabilities, allow complete and cleaner combustion than normal gasoline, resulting in lower pollutant emissions and particulate matter. Moreover natural gas, which is mainly constituted by methane, whose molecule has the highest hydrogen/carbon ratio, leads also to lower ozone depleting emissions. The authors in a previous work (1) experienced the simultaneous combustion of gasoline and natural gas in a bi-fuel S.I. engine, exploiting so the high knock resistance of methane to run the engine with an ‘overall stoichiometric’ mixture (thus lowering fuel consumption and emissions) and better spark advance (which increases engine efficiency) even at full load: the results showed high improvements in engine efficiency without noticeable power losses with respect to the pure gasoline operation. With the aim to provide a knock prevision submodel to be used in engine thermodynamic simulations for a knock-safe performance optimization of engines fuelled by NG/gasoline mixtures, the authors recorded the in-cylinder pressure cycles under light knocking condition for different engine speed, loads and natural gas fraction (i.e. the ratio between the injected natural gas mass and the total fuel mass), and used the gas pressure data to calibrate a classical knock-prediction model: as shown, the results obtained allow to predict the onset of knocking in a S.I. engine fuelled with a gasoline-natural gas mixture with any proportion between the two fuels, with a maximum error of 5 CAD.


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