scholarly journals Possible changes of the isotopic composition of ice wedge as a result of self-diffusion

2021 ◽  
pp. 44-56
Author(s):  
Yurij Kirillovich Vasil'chuk
Keyword(s):  
Isotopic Composition ◽  
Differential Forms ◽  
Time Intervals ◽  
Simple Method ◽  
Chemical Systems ◽  
Self Diffusion ◽  
Probabilistic Values ◽  
Ice Wedge ◽  
Gaussian Integral ◽  
The Impact

  The subject of this research is the assessment of changes of the isotopic composition of ice wedge as a result of self-diffusion. The author offers a relatively simple method of considering the impact of the process of self-diffusion upon redistribution of paleo-isotopic composition that allows accurately and quickly estimating the changes in the values δ18О and δ2H values in ice wedges at different periods of the quaternary (1000 years, 10,000 years, 100,000 years, and 1,000,000 years). The patterns of diffusion process in physico-chemical systems are described by two differential forms of Fick's diffusion laws, which are transformed into Gaussian integral, using six-digit Chambers charts for calculation of the threshold values δ18О. The article applies the experimentally determined real values of self-diffusion coefficient in the ice – D=(2–10)×10-15 m2/s. The values of the Gaussian integral are calculated for time intervals, at different distances between samples with different concentration; for the period of 1,000 years its values in all cases exceed 0.99. For longer time intervals, these values change significantly. The calculated probabilistic values of changes in the concentration of heavy oxygen isotopes in ice wedge under the impact of self-diffusion at different distances and concentration gradients are noticeable only for the time period of over 100,000 years.  

scholarly journals Unraveling the hydrological budget of isolated and seasonally contrasted subtropical lakes

2019 ◽  
Vol 23 (3) ◽  
pp. 1705-1724 ◽  
Author(s):  
Chloé Poulin ◽  
Bruno Hamelin ◽  
Christine Vallet-Coulomb ◽  
Guinbe Amngar ◽  
Bichara Loukman ◽  
...  
Keyword(s):  
Surface Water ◽  
Isotopic Composition ◽  
Mass Balance ◽  
Water Budget ◽  
Large Scale ◽  
Satellite Mission ◽  
Simple Method ◽  
Lake Chad ◽  
Aquifer Systems ◽  
The Impact

Abstract. Complete understanding of the hydrological functioning of large-scale intertropical watersheds such as the Lake Chad basin is becoming a high priority in the context of climate change in the near future and increasing demographic pressure. This requires integrated studies of all surface water and groundwater bodies and of their quite-complex interconnections. We present here a simple method for estimating the annual mean water balance of sub-Sahelian lakes subject to high seasonal contrast and located in isolated regions with no road access during the rainy season, a situation which precludes continuous monitoring of in situ hydrological data. Our study focuses for the first time on two lakes, Iro and Fitri, located in the eastern basin of Lake Chad. We also test the approach on Lake Ihotry in Madagascar, used as a benchmark site that has previously been extensively studied by our group. We combine the δ18O and δ2H data that we measured during the dry season with altimetry data from the SARAL satellite mission in order to model the seasonal variation of lake volume and isotopic composition. The annual water budget is then estimated from mass balance equations using the Craig–Gordon model for evaporation. We first show that the closed-system behavior of Lake Ihotry (i.e., precipitation equal to evaporation) is well simulated by the model. For lakes Iro and Fitri, we calculate evaporation to influx ratios (E∕I) of 0.6±0.3 and 0.4±0.2, respectively. In the case of the endorheic Lake Fitri, the estimated output flux corresponds to the infiltration of surface water toward the surface aquifer that regulates the chemistry of the lake. These results constitute a first-order assessment of the water budget of these lakes, in regions where direct hydrological and meteorological observations are very scarce or altogether lacking. Finally, we discuss the implications of our data on the hydro-climatic budget at the scale of the catchment basins. We observe that the local evaporation lines (LELs) obtained on both lake and aquifer systems are slightly offset from the average rainfall isotopic composition monitored by IAEA at N'Djamena (Chad), and we show that this difference may reflect the impact of vegetation transpiration on the basin water budget. Based on the discussion of the mass balance budget we conclude that, while being broadly consistent with the idea that transpiration is on the same order of magnitude as evaporation in those basins, we cannot derive a more precise estimate of the partition between these two fluxes, owing to the large uncertainties of the different end-members in the budget equations.

scholarly journals Unraveling the hydrological budget of isolated and seasonally contrasted sub-tropical lakes

2018 ◽  
Author(s):  
Chloé Poulin ◽  
Bruno Hamelin ◽  
Christine Vallet-Coulomb ◽  
Guinbe Amngar ◽  
Bichara Loukman ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Water Budget ◽  
Tropical Lakes ◽  
Future Climate Change ◽  
Small Scale ◽  
Simple Method ◽  
Lake Chad ◽  
Aquifer Systems ◽  
Rain Season ◽  
The Impact

Abstract. Complete understanding of the hydrological functioning of large scale intertropical watersheds like the Lake Chad basin, which become a high priority in the prospect of near future climate change and increasing demographic pressure, require integrated studies of all surface and groundwater reservoirs and their quite complex interconnections. In this respect, detailed hydrological studies of secondary peripheral lakes of these large basins may provide us with interesting small scale analogs of the major waterbodies, which can help disentangling the multiple influences of various forcing factors of the water cycle and its evolution. We present here a simple method for estimating the annual mean water balance of sub-sahelian lakes subject to high seasonal contrast, and located in isolated regions with no road access during the rain season, precluding continuous monitoring of in-situ hydrological data. The approach is illustrated by the study of the two lakes Iro and Fitri in the eastern basin of lake Chad, so far unstudied, and also tested on lake Ihotry (Madagascar), extensively studied previously by our group. We combine the isotopic data (δ18O; δ2H) that we measured during the dry season with altimetry data from the SARAL satellite mission, in order to model the seasonal variation of lake volume and isotopic composition. The annual water budget is then estimated from mass balance equations using the Craig and Gordon's model for evaporation. We show that the closed-system behavior (precipitation equal to evaporation) can be confirmed for lake Ihotry, whereas we calculate E / I ratios of 0.6 ± 0.3 and 0.4 ± 0.2 for Iro and Fitri, respectively, in both cases compatible with water fluxes estimated from nearby gauging stations. In the case of Fitri the estimated output flux is contributing to the groundwater recharge, since the lake has no identified surface outlet. Finally, we use our data to discuss possible inferences about the hydro-climatic budget of the catchment basins of those two lakes. We show that the average rainfall isotopic composition monitored by IAEA at NDjamena is slightly offset from the two distinct Local Evaporation Lines that we obtain on the two lake-aquifer systems, and that this slight difference may reflect the impact of vegetation transpiration on the basin water budget. We conclude that, while being broadly consistent with transpiration being on the same order of magnitude as evaporation in those basins, we cannot derive a more precise estimate of the partition between these two fluxes, owing to the large uncertainties of the different end-members in the budget equations.

scholarly journals Assessing an Atmospheric Correction Algorithm for Time Series of Satellite-Based Water-Leaving Reflectance Using Match-Up Sites in Australian Coastal Waters

2021 ◽  
Vol 13 (10) ◽  
pp. 1927
Author(s):  
Fuqin Li ◽  
David Jupp ◽  
Thomas Schroeder ◽  
Stephen Sagar ◽  
Joshua Sixsmith ◽  
...  
Keyword(s):  
Coastal Waters ◽  
Atmospheric Correction ◽  
Correction Method ◽  
In Situ Measurements ◽  
Landsat 8 ◽  
Correction Algorithm ◽  
Simple Method ◽  
North East ◽  
The Impact

An atmospheric correction algorithm for medium-resolution satellite data over general water surfaces (open/coastal, estuarine and inland waters) has been assessed in Australian coastal waters. In situ measurements at four match-up sites were used with 21 Landsat 8 images acquired between 2014 and 2017. Three aerosol sources (AERONET, MODIS ocean aerosol and climatology) were used to test the impact of the selection of aerosol optical depth (AOD) and Ångström coefficient on the retrieved accuracy. The initial results showed that the satellite-derived water-leaving reflectance can have good agreement with the in situ measurements, provided that the sun glint is handled effectively. Although the AERONET aerosol data performed best, the contemporary satellite-derived aerosol information from MODIS or an aerosol climatology could also be as effective, and should be assessed with further in situ measurements. Two sun glint correction strategies were assessed for their ability to remove the glint bias. The most successful one used the average of two shortwave infrared (SWIR) bands to represent sun glint and subtracted it from each band. Using this sun glint correction method, the mean all-band error of the retrieved water-leaving reflectance at the Lucinda Jetty Coastal Observatory (LJCO) in north east Australia was close to 4% and unbiased over 14 acquisitions. A persistent bias in the other strategy was likely due to the sky radiance being non-uniform for the selected images. In regard to future options for an operational sun glint correction, the simple method may be sufficient for clear skies until a physically based method has been established.

scholarly journals Impact of the Coronavirus Pandemic Lockdown on Atmospheric Nanoparticle Concentrations in Two Sites of Southern Italy

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 352
Author(s):  
Adelaide Dinoi ◽  
Daniel Gulli ◽  
Ivano Ammoscato ◽  
Claudia R. Calidonna ◽  
Daniele Contini
Keyword(s):  
Particle Number ◽  
Southern Italy ◽  
Time Intervals ◽  
Atmospheric Particle ◽  
Total Particle Number ◽  
Total Particle ◽  
Consequent Reduction ◽  
Containment Measures ◽  
Coronavirus Infection ◽  
The Impact

During the new coronavirus infection outbreak, the application of strict containment measures entailed a decrease in most human activities, with the consequent reduction of anthropogenic emissions into the atmosphere. In this study, the impact of lockdown on atmospheric particle number concentrations and size distributions is investigated in two different sites of Southern Italy: Lecce and Lamezia Terme, regional stations of the GAW/ACTRIS networks. The effects of restrictions are quantified by comparing submicron particle concentrations, in the size range from 10 nm to 800 nm, measured during the lockdown period and in the same period of previous years, from 2015 to 2019, considering three time intervals: prelockdown, lockdown and postlockdown. Different percentage reductions in total particle number concentrations are observed, −19% and −23% in Lecce and −7% and −4% in Lamezia Terme during lockdown and postlockdown, respectively, with several variations in each subclass of particles. From the comparison, no significant variations of meteorological factors are observed except a reduction of rainfall in 2020, which might explain the higher levels of particle concentrations measured during prelockdown at both stations. In general, the results demonstrate an improvement of air quality, more conspicuous in Lecce than in Lamezia Terme, during the lockdown, with a differed reduction in the concentration of submicronic particles that depends on the different types of sources, their distance from observational sites and local meteorology.

Nitrification preservation in activated sludge during curative bulking chlorination

2003 ◽  
Vol 47 (11) ◽  
pp. 85-92 ◽  
Author(s):  
E. Cotteux ◽  
P. Duchene
Keyword(s):  
Activated Sludge ◽  
Pilot Plant ◽  
Wastewater Treatment Plants ◽  
Oxygen Uptake Rate ◽  
Ammonia Concentration ◽  
Synthetic Wastewater ◽  
Biological Wastewater Treatment ◽  
Simple Method ◽  
Method Of Measurement ◽  
The Impact

The bulking that occurs in biological wastewater treatment plants using activated sludge is very often controlled by the injection of sodium hypochlorite into the return activated sludge (RAS) stream. In the present study undertaken at two pilot plants fed with synthetic wastewater, the impact of the pass frequency of the sludge at the chlorine dosing point on the nitrifying flora is analysed. The pass frequency is one for the pilot plant 1 and two for the pilot plant 2. A dose of chlorine of 4.85 ± 0.05 g/kg/MLVSS per day was applied at both pilots. The preservative effect on nitrifying activity of the lowest concentration of chlorine at the dosing point and therefore of the highest pass frequency was evidenced. Among other tools, a simple method of measurement of the oxygen uptake rate enabled us to monitor the effect of chlorination on nitrification before recording an increase in the ammonia concentration in the bulking.

scholarly journals Pb isotopes in the impact melt breccia 66095: Association with the Imbrium basin and the isotopic composition of lithologies at the Apollo 16 landing site

2017 ◽  
Vol 466 ◽  
pp. 608-616 ◽  
Author(s):  
Joshua F. Snape ◽  
Alexander A. Nemchin ◽  
Jeremy J. Bellucci ◽  
Martin J. Whitehouse
Keyword(s):  
Isotopic Composition ◽  
Landing Site ◽  
Pb Isotopes ◽  
Impact Melt ◽  
The Impact

Abstract P99: Impact of the Covid-19 Pandemic on Stroke Thrombolysis Rate and Delay to Thrombolysis Treatment in a Regional Stroke Centre in London, UK

Stroke ◽  
2021 ◽  
Vol 52 (Suppl_1) ◽  
Author(s):  
Brian Drumm ◽  
Paul Bentley ◽  
Zoe Brown ◽  
Lucio D’Anna ◽  
Tsering Dolkar ◽  
...  
Keyword(s):  
Arrival Time ◽  
Negative Impact ◽  
Public Awareness ◽  
Stroke Severity ◽  
Time Intervals ◽  
Neurological Outcomes ◽  
Stroke Thrombolysis ◽  
Prehospital Delays ◽  
The Impact ◽  
Stroke Centre

Introduction: There are reports of changes in the numbers of stroke admissions and time intervals to receiving emergency treatments during the COVID-19 pandemic. We examined the impact of the COVID-19 pandemic on the stroke thrombolysis rate and delay to thrombolysis treatment in a regional stroke centre in London, UK. Methods: COVID-19 testing began at our hospital on 3 March 2020. Clinical data for all acute stroke admissions were routinely collected as part of a national Sentinel Stroke National Audit Programme (SSNAP) and all thrombolysis data were entered into our local thrombolysis database. We retrospectively extracted the relevant patient data for the period of March to May 2020 (COVID group) and compared to the same period in 2019 (pre-COVID group). Results: Compared with pre-COVID, there was a 17.5% fall in total stroke admissions (from 315 to 260) during COVID; but there were no significant differences in the demographics, stroke severity, proportions with known time of onset, or median onset-to-arrival time. The thrombolysis rates amongst ischemic strokes were not significantly different between the two groups (59/260=23% pre-COVID vs. 41/228=18% COVID, p=.19). For thrombolysis patients, their stroke severity and demographics were similar between the two both groups. Median onset-to-needle time was significantly longer by 22 minutes during COVID [127 (IQR 94-160) vs. 149 (IQR 110-124) minutes, p=.045]; this delay to treatment was almost entirely due to a longer median onset-to-arrival time by 16 minutes during COVID (p=.029). Favorable early neurological outcomes post-thrombolysis (defined as an improvement in NIHSS by ≥4 points at 24 hours) were similar (45% vs. 46%, p=.86). Conclusion: COVID-19 pandemic had a negative impact on prehospital delays which in turn significantly increased onset-to-needle time, but without affecting the chance of a favorable early neurological outcome. Our data highlight the need to maintain public awareness of taking immediate action when stroke symptoms occur during the COVID-19 pandemic.

Abstract 13248: The Impact of Instructions for Covering the Mouth and the Nose on Dispatch-Assisted Cardiopulmonary Resuscitation

Circulation ◽  
2021 ◽  
Vol 144 (Suppl_2) ◽  
Author(s):  
Hidetada Fukushima ◽  
Hideki Asai ◽  
Koji Yamamoto ◽  
Yasuyuki Kawai
Keyword(s):  
Cardiopulmonary Resuscitation ◽  
Median Time ◽  
Chest Compression ◽  
Fire Department ◽  
Emergency Call ◽  
Time Interval ◽  
Time Intervals ◽  
Median Time Interval ◽  
Study Results ◽  
The Impact

Introduction: Under the SARS-CoV-2 pandemic, rescuers are recommended to cover their mouth and nose with a facemask or a cloth as well as victim’s mouth and nose when performing cardiopulmonary resuscitation (CPR). However, its impact on dispatch-assisted CPR (DACPR) has not been investigated well. Hypothesis: DACPR including the instruction for covering the rescuer’s and the victim’s mouth and nose can significantly delay the start of the first chest compression. Methods: We retrospectively analyzed DACPR records of the Nara Wide Area Fire Department, covering population of 853,000/3361km 2 , in Japan. We investigated the key time intervals of 505 DACPR records between May 2020 and March 2021. We also compared the results to that of the same period in 2019 (535 records). Results: Dispatchers failed to provide mask instruction in 322 cases (63.8%). The median time interval from the emergency call and the start of CPR instruction was longer in 2020 (197 seconds vs 190 seconds, p=0.641). The time to the first chest compression was also delayed in 2020 (264 seconds vs 246 seconds, p=0.015). Among the cases that dispatchers successfully provided mask instruction (183 cases, 36.2%), median time intervals to the start of instruction and the first chest compression were relatively faster than cases without mask instruction (177 seconds vs 211 seconds and 254 seconds vs 269.5 seconds, respectively). Conclusions: Dispatchers failed to provide mask instruction in the majority of CA cases. However, our study results indicate that the impact of mask instruction on DACPR can be minor in terms of immediate CPR provision.

Departure Time Choice in Schedule-Based Transit Assignment

2021 ◽  
pp. 036119812110338
Author(s):  
Markus Friedrich ◽  
Matthias Schmaus ◽  
Jonas Sauer ◽  
Tobias Zündorf
Keyword(s):  
Travel Demand ◽  
Time Intervals ◽  
Transit Assignment ◽  
Common Assumption ◽  
Adaptation Time ◽  
Highly Sensitive ◽  
Departure Time ◽  
Departure Time Choice ◽  
Passenger Behavior ◽  
The Impact

This paper investigates existing departure time models for a schedule-based transit assignment and their parametrization. It analyzes the impact of the temporal resolution of travel demand and suggests functions for evaluating the adaptation time as part of the utility of a path. The adaptation time quantifies the time between the preferred and the scheduled departure times. The findings of the analysis suggested that travel demand should be discretized into intervals of 1 min, with interval borders right between the full minute, that is, ±0.5 min. It was shown that longer time intervals led to arbitrary run volumes, even for origin–destination pairs with just one transit line and a fixed headway. Although a linear relationship between adaptation time and adaptation disutility is a common assumption in several publications, it cannot represent certain types of passenger behavior. For some trip purposes, passengers may be insensitive to small adaptation times, but highly sensitive to large adaptations. This requires a nonlinear evaluation function.

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