The future of coal as a transportation fuel

Due to environmental concerns and cost issues, coal is currently being phased out from usage in electricity production. Regardless, there remains a massive stockpile of coal reserves along with a large industrial complex and a robust distribution/processing infrastructure. As such, coal should be considered for usage in other energy areas. Since coal is simply a solid hydrocarbon, it can be converted over for usage as a transportation fuel. The Fischer-Tropsch process that underlies this conversion is well established with some countries like South Africa currently using it at large scales. Unfortunately, this conversion process has a large carbon footprint, even when using carbon capture technology. However, the blending of coal-based fuels with biodiesel has been found to be more carbon neutral than standard diesel or biodiesel alone. Additionally, coal can be used as an alternate to methane for hydrogen production. Given carbon capture technologies and the existing coal infrastructure, these two uses of coal provide opportunities for a sustainable and economical use of coal as a transportation fuel.

Review on toxic effect of naphthalene

Naphthalene is a toxic substance. Naphthalene, also known as naphthalin, is a crystalline, aromatic, white, solid hydrocarbon (PAH: Polycyclic Aromatic Hydrocarbon) with formula C10H8 and the structure of two fused benzene rings. It is best known as the traditional, primary ingredient of moth balls. Repeated naphthalene exposure has also been found to potentially cause airway epithelial damage, aberrant repair, and inflammation. Greater numbers of peribronchial Mac-3-positive macrophages and CD3-positive T-cells were observed throughout the airways which displays acute inflammation within the airways. The effects of naphthalene poisoning are particularly severe in infants and young children. Toxic effects vary from individual to individual. This article gives a brief review about the toxic effect of naphthalene.

Grain composition and diagenesis of organic-rich lacustrine tarls, Triassic Yanchang Formation, Ordos Basin, China

The role of the primary detrital grain assemblage as a control on diagenetic pathways is reasonably well-understood in sandstones and limestones, but less so in mudrocks. We have documented diagenesis in mudstones from the Triassic Yanchang Formation that are dominated ([Formula: see text] by volume) by grains derived from outside the basin of deposition (terrigenous-argillaceous mudstones or tarls). Major extrabasinal grains are K-rich clay, quartz, plagioclase, K-feldspar, lithic fragments, and micas. In terms of the quartz-feldspar-lithic grain compositions, the silt fraction in these samples is classified as arkose. Grains of intrabasinal derivation include particulate organic matter, phosphatic debris, and rare carbonate allochems. The principal chemical diagenetic components in these mudrocks have strongly localized spatial distributions at micrometer to centimeter scales. Chemical diagenetic components include cone-in-cone structures, replacements of detrital feldspar, pore-filling precipitates within anomalously large pores, pore-filling solid hydrocarbon, and very minor quartz overgrowths associated with local packing flaws around silt-size detrital quartz grains. Matrix-dispersed intergranular cementation, as observed in well-known organic-rich marine mudstones, such as the Barnett Shale and the Eagle Ford Formation, is not observed in Yanchang Formation lacustrine mudstones. The authigenic features present are consistent with the thermal maturity of the units ([Formula: see text]) and are broadly similar to features observed in other mudstones that contain grain assemblages dominated by particles of extrabasinal derivation. The low porosity and the absence of significant amounts of intergranular cement indicate that compactional porosity loss and in-filling by migrated solid hydrocarbon were the major causes of porosity decline during diagenesis of Yanchang Formation mudrocks. Although the mudstones of the Yanchang Formation have a relatively high content of organic carbon and serve as source rocks in the Ordos Basin, the depositional grain assemblage is not conducive to creation of porosity, permeability, and mechanical properties that would make these mudrocks effective unconventional reservoirs.