The socialization of technology and the technicalization of society have accelerated the speed, scope and scale of human liberation from nature. In our past technological society, “liberation” mainly referred to people's physical strength. An intelligent society, characterized by the wide application of the internet, big data, and artificial intelligence (AI), will further liberate not only people's physical strength, but also their mental power, greatly changing social forms and social operation modes, as well as people themselves. In the application of technologies and the design and manufacture of equipment on which the intelligent society depends, a new tension is formed between instrumental rationality and value rationality. While promoting the liberation of human beings, intelligent society will also cause humans to be dominated and enslaved by AI, which will lead to human alienation. Intelligent society is more in pursuit of how the invested capital and technology can multiply in the process of accumulation and circulation; meanwhile, it will ignore the moral responsibilities of relevant parties, such as researchers, manufacturers, and users. In the process of developing an intelligent society, instrumental rationality should be regulated by value rationality, thus promoting the liberation of human beings and eliminating their alienation. As capital appreciation occurs, the moral responsibilities of relevant parties should be clarified.