Techniques for In Situ Monitoring the Performance of Organic Coatings and Their Applicability to the Pre-Finished Steel Industry: A Review

A review is carried out in this paper into techniques that currently exist for, of have the potential to be used for, monitoring the performance of organic coating. Specific attention is paid to the applicability of each method to pre-finished steel used in the construction industry as these are rarely monitored in situ and their expected performance is often only estimated from lab-based accelerated corrosion testing. Monitoring could allow more accurate estimates of building cladding lifespan and required maintenance schedules; provide customers with active performance data; additionally, with a better understanding of performance, more appropriate coatings or coating weights could be selected for a construction project, offering economic benefits as part of smart building developments. An introduction to coatings, their use for corrosion protection, failure mechanisms, and relevant monitoring techniques is given before current assessment techniques are described in terms of their working principles. Examples of recent work are presented for the techniques that have been investigated for monitoring or directly relatable purposes. The review concludes that there are several good reasons why an optimum corrosion monitoring technology does not currently exist, however, promising research is emerging in the field of wireless and embedded sensor design which is providing optimistic results.

Features of the ferrite-bainite structure low-alloy low-carbon steel after heat hardening and subsequent tempering

Problem statement. In recent decades, there has been a tendency to increase the mechanical properties of low-carbon, low-alloyed steel plate iron by using controlled rolling or hardening heat treatment of finished steel parts. At the same time, for welded parts, the most suitable is a metal having a ferrite-bainite (or bainite) structure. The work investigated the features of the ferrite-bainite structure of low-carbon and low-alloyed steel 15ХСНД for the production of connecting pipeline parts. Purpose of the article. To establish the laws of formation of a ferritic-bainitic structure in low-carbon low-alloy steels depending on the parameters of heat treatment. Determine the effect of heat treatment parameters on the properties of the connecting parts of pipelines made of these steels. Conclusion. The regularities of the influence of heat treatment parameters on the structure, mechanical properties and topography of fractures of impact samples of 15ХСНД steel with a ferrite-bainitic structure are established. Keywords: stamped-welded connecting parts of man pipelines; heat treatment; microstructure; bainite;mechanical properties; fractography

Investigation of the Microstructural Evolution during Hot Stamping of a Carburized Complex Phase Steel by Laser-Ultrasonics

Prior carburization of semi-finished steel sheets is a new process variant in hot stamping to manufacture parts with tailored properties. Compared to conventional hot stamping processes, a complex phase typed steel alloy is used instead of 22MnB5. Yet recent investigations focused on final mechanical properties rather than microstructural mechanisms cause an increase in strength. Thus, the influence of additional carburization on the microstructural evolution during hot stamping of a complex phase steel CP-W®800 is investigated within this work. The phase transformation behavior, as well as the grain growth during austenitization, is evaluated by in-situ measurements employing a laser-ultrasound sensor. The results are correlated with additional hardness measurements in as-quenched condition and supplementary micrographs. The experiments reveal that the carburization process significantly improves the hardenability of the CP-W®800. However, even at quenching rates of 70 K/s no fully martensitic microstructure was achievable. Still, the resulting hardness of the carburized samples might exceed the fully martensitic hardness of 22MnB5 derived from literature. Furthermore, the carburization process has no adverse effect on the fine grain stability of the complex phase steel. This makes it more robust in terms of grain size than the conventional hot stamping steel 22MnB5.

Tendencies of export and import of steel industry products of Russia within 9 months of 2019

Structure of the Russian export and import of steel industry products presented by results of 9 months of 2019 operation. It was shown, that the total share of pig iron, ferroalloys and semi-products (40.3%) in the ferrous metals export from Russia is practically the same as the share of rolled products and steel pipes (39.4%), whereas the shares in the import structure were 7.7 and 75% accordingly. The share the far abroad countries in the Russian export and import of finished steel products (in natural terms) accounted for 80.6 and 28.7% accordingly, while the share of CIS countries – 19.4 and 71.3% accordingly. For 9 months of 2019 the Russian export of semi-products declined by 10.9% comparing with the analogue period of 2018 and accounted for 10.9 m tons. 54.6% of the total export shipping of semi-products were directed to Mexico, Turkey, Egypt and Taiwan. Within the nearest years the Russian export of semi-products and billets, in particular, will be effected by the further development of the semi-products production in in the countries of Middle East, Turkey, Vietnam and India. The domestic market remained to be more attractive for many Russian companies. For the 9 months of 2019, export of long and flat products accounted for 3 and 5.7 m tons accordingly, declining comparing with the analogue period of the previous year by 11 and 15.6% accordingly. Import of long and flat products decreased by 12 and 0.5%, accounting for 1.0 and 2.9 m tons accordingly. By the results of 9 months of 2019, import declined and export shipping of coated sheet increased. Taking into account the expansion of steel grades assortment by Russian plants, increase of capacities for production of sheet with different coatings, this tendency is likely to remain.

Flat Metal Rolling Simulation by Finite Volume Method

In Thailand, the sheet metal products that were produced by rolling process have high demand and the consumption trend to grow in the future. Many new products, which made from rolling steel sheet, had been developed with various design. Thus the manufacturers have to improve the productivity through the investigation and analysis of different process parameters, which affect to the quality during the production. In this paper, finite volume method FVM had been applied to analyze different effects of processes parameters such as temperature, roller speed, friction, size and capacity of rolling machine. The commercial software MSC.SuperForge was used in the modeling and simulation of metal deformation under the flat rolling process. Considering the predicted results compared with the experimental data, the different in dimension error data were within an acceptable range of quality specification. The error in width of finished steel sheet was 1.17%, the length was error of 1.50%, and the thickness was error of 2.32%. By using this technique, different factors affected during rolling process can be investigated and controlled such as the metal flow, the distribution of stress and strain, and the deformation zone.

Tracing Microalloy Precipitation in Nb-Ti HSLA Steel during Austenite Conditioning

The microalloying with niobium (Nb) and titanium (Ti) is standardly applied in low carbon steel high-strength low-alloy (HSLA) steels and enables austenite conditioning during thermo-mechanical controlled processing (TMCP), which results in pronounced grain refinement in the finished steel. In that respect, it is important to better understand the precipitation kinetics as well as the precipitation sequence in a typical Nb-Ti-microalloyed steel. Various characterization methods were utilized in this study for tracing microalloy precipitation after simulating different austenite TMCP conditions in a Gleeble thermo-mechanical simulator. Atom probe tomography (APT), scanning transmission electron microscopy in a focused ion beam equipped scanning electron microscope (STEM-on-FIB), and electrical resistivity measurements provided complementary information on the precipitation status and were correlated with each other. It was demonstrated that accurate electrical resistivity measurements of the bulk steel could monitor the general consumption of solute microalloys (Nb) during hot working and were further complemented by APT measurements of the steel matrix. Precipitates that had formed during cooling or isothermal holding could be distinguished from strain-induced precipitates by corroborating STEM measurements with APT results, because APT specifically allowed obtaining detailed information about the chemical composition of precipitates as well as the elemental distribution. The current paper highlights the complementarity of these methods and shows first results within the framework of a larger study on strain-induced precipitation.

Tracing Microalloy Precipitation in Nb-Ti HSLA Steel During Austenite Conditioning

Microalloying of low carbon steel with niobium (Nb) and titanium (Ti) is standardly applied in high-strength low-alloy (HSLA) steels enabling austenite conditioning during thermo-mechanical controlled processing (TMCP), which results in pronounced grain refinement in the finished steel. The metallurgical effects of microalloying elements are related solute drag and precipitate particle pinning, both acting on the austenite grain boundary thereby delaying or suppressing recrystallization of the deformed grain. In that respect it is important to better understand the precipitation kinetics as well as the precipitation sequence in a typical Nb-Ti-microalloyed steel. Various characterization methods have been utilized in this study for tracing microalloy precipitation after simulating different austenite TMCP conditions in a Gleeble apparatus. Atom probe tomography (APT), scanning transmission electron microscopy in a focused ion beam equipped scanning electron microscope (STEM-on-FIB) and electrical resistivity measurements provide complementary information on the precipitation status and are correlated with each other. It will be demonstrated that accurate electrical resistivity measurements can monitor the general consumption of solute microalloys (Nb) during hot working which was complemented by APT measurements of the steel matrix. On the other hand, STEM revealed that a large part of Nb-containing particles during hot working are co-precipitated with titanium during cooling from the austenitizing temperature. Precipitates that form during cooling or isothermal holding can be distinguished from strain-induced precipitates by corroborating STEM measurements with APT results. APT specifically allows obtaining detailed information about the chemical composition of precipitates as well as the distribution of elements inside the particle. Electrical resistivity measurement, on the contrary, provides macroscopic information on the progress of precipitation and can be calibrated by APT. The current paper highlights the complementarity of these methods and shows first results within the framework of a larger study on strain-induced precipitation.

Export and Import Performance of Steel in India

Steel is crucial to the event of any fashionable economy and is taken into account the backbone of human civilization. At present, developing countries lead the expansion in world steel demand. India is presently the world's third largest producer of crude steel and is anticipated to become the largest producer of crude steel within the world before long. The country is additionally the third largest client of finished steel (83.5 Million Tonnes in 2016) within the world preceded by China (681 Million Tonnes in 2016) and also the USA (91.6 million tonnes in 2016. Steel occupies this position due to its skillfulness, strength and recyclability. The steel sector contributes to over two of the country's gross domestic product and employs around 25 lakhs utilized in steel/allied sectors. Between 2008 and 2011 India has recorded a growth of 29.2% in Steel production. Indian industry has been preponderantly serving domestic market. Consumption of steel in India is a smaller amount compared to alternative Asian steel majors specifically China, Japan, and Republic of Korea. Thus, the business has scope for growth in future. In recent times, India is that the contributor of four p.c to the world’s crude production and is anticipated to carry and retain its position in coming back years. The rapid climb of population, increase in urbanization still as increase in agricultural and industrial product together with sweetening of ordinary of living, give an honest scope for the event of Indian industry. Iron and Steel Exports stood at 7.606 million tonnes, a growth of 52.9% compared to 2016 and also the Imports stood at half dozen 0.097 million tonnes, a growth of 10.9% compared to the year 2016. This paper examines the export and import performance of Steel Industry from 2014-2015 to 2017-2018. The industry is mainly dominated by Tata Steel Ltd on the basis of overall competitiveness and financial and non - financial aspe cts of competitiveness.