Фотоиндуцированное состояние Флоке-изолятора в графеноподобном кристалле

Floquet spectrum of charge carriers in a 2D crystal with initially displaced Dirac points has been derived. The phase and amplitude dependences of the energy gap induced by elliptically polarized and bichromatic high-frequency fields has been investigated. In contrast to graphene the linearly polarized electric field has been shown to be able to transform the initially semi-metallic state of Dirac crystal into the Floquet-insulator state. The conditions for such a transition are indicated, one of which is the mismatch between the orientation of the field polarization line and the direction of the crystallographic axes.

Polyvinylidene Fluoride-Based Metasurface for High-Quality Active Switching and Spectrum Shaping in the Terahertz G-Band

We report theoretical investigations performed in the terahertz G-band, in the 228–232 GHz spectral window for a piezoelectrically-responsive ring-cone element metasurface composed of polyvinylidene fluoride (PVDF)/Silicon and PVDF/Silica glass. The choosing of this spectral window is motivated by a multitude of applications in terahertz detection and terahertz imaging, that commonly make use of this band. The uniqueness of the envisioned architecture resides in the combination between the readily-available polyvinylidene fluoride polymer and silicon/silica glass substrates, together with the introduction of an extra degree of freedom, in the form of a ring-cone architecture , and the active control of the geometric sizes through the longitudinal piezoelectric effect exhibited by the polymer. The spectral response of the metasurface is dependent on the combination between the polymer elements and the substrate, and ranges from near-zero absorption switching to a resonant behavior and significant absorption. The interaction between the electromagnetic field and the polymer-based metasurface also modifies the phase of the reflected and transmitted waves over a full 2π range, permitting complete control of the electric field polarization. Moreover, we take advantage of the longitudinal piezoelectric effect of PVDF and analyze the spectrum shaping capability of the polymer-based metasurface. Our analysis highlights the capability of the proposed architecture to achieve complete electric field polarization control, near-zero optical switching and resonant behavior, depending on the geometries and sizes of the architecture elements resulting from construction considerations and from the externally applied voltages through the piezoelectric effect.

Heteroatom coordination induces electric field polarization of single Pt sites to promote hydrogen evolution activity

Herein, we reported a kind of single Pt sites (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution...