Abstract. Biomass burning aerosol is a major source of PM2.5,
and significantly affects Earth's radiative budget. The magnitude of its
radiative effect is poorly quantified due to uncertainty in the optical
properties of aerosol formed from biomass burning. Using a broadband cavity-enhanced spectrometer with a recently increased spectral range (360–720 nm) coupled to a size-selecting aerosol inlet, we retrieve complex
refractive indices of aerosol throughout the near-ultraviolet and visible
spectral region. We demonstrate refractive index retrievals for two standard
aerosol samples: polystyrene latex spheres and ammonium sulfate. We then
retrieve refractive indices for biomass burning aerosol from 13 controlled
fires during the 2016 Missoula Fire Science Laboratory Study. We demonstrate
that the technique is highly sensitive to the accuracy of the aerosol size
distribution method and find that while we can constrain the optical
properties of brown carbon aerosol for many fires, fresh smoke dominated by
fractal-like black carbon aerosol presents unique challenges and is not
well-represented by Mie theory. For the 13 fires, we show that the accuracy
of Mie theory retrievals decreases as the fraction of black carbon mass
increases. At 475 nm, the average refractive index is 1.635 (±0.056)
+0.06 (±0.12)i, and at 365 nm, the average refractive index is 1.605
(±0.041) +0.038 (±0.074)i.