Recent Advances in Vertically Aligned Nanocomposites with Tunable Optical Anisotropy: Fundamentals and Beyond

Developing reliable and tunable metamaterials is fundamental to next-generation optical-based nanodevices and computing schemes. In this review, an overview of recent progress made with a unique group of ceramic-based functional nanocomposites, i.e., vertically aligned nanocomposites (VANs), is presented, with the focus on the tunable anisotropic optical properties. Using a self-assembling bottom-up deposition method, the as-grown VANs present great promise in terms of structural flexibility and property tunability. Such broad tunability of functionalities is achieved through VAN designs, material selection, growth control, and strain coupling. The as-grown multi-phase VAN films also present enormous advantages, including wafer scale integration, epitaxial quality, sharp atomic interface, as well as designable materials and geometries. This review also covers the research directions with practical device potentials, such as multiplex sensing, high-temperature plasmonics, magneto-optical switching, as well as photonic circuits.

The Influence of Martensitic Intercalations in Magnetic Shape Memory NiCoMnAl Multilayered Films

Hysteresis and transformation behavior were studied in epitaxial NiCoMnAl magnetic shape memory alloy thin films with varying number martensitic intercalations (MIs) placed in between. MIs consists of a different NiCoMnAl composition with a martensitic transformation occurring at much higher temperature than the host composition. With increasing number of intercalations, we find a decrease in hysteresis width from 17 K to 10 K. For a large difference in the layers thicknesses this is accompanied by a larger amount of residual austenite. If the thicknesses become comparable, strain coupling between them dominates the transformation process, which manifests in a shift of the hysteresis to higher temperatures, splitting of the hysteresis in sub hysteresis and a decrease in residual austenite to almost 0%. A long-range ordering of martensite and austenite regions in the shape of a 3D checker board pattern is formed at almost equal thicknesses.

Salt thickness and heterogeneity control the degree of coupling between sub- and supra-salt structure during salt-detached translation: evidence from physical models

<p>Salt flows like a fluid over geological timescales and introduces significant structural complexity to the basins in which it is deposited. Salt typically flows seaward due to tilting of the basin margins, and is therefore influenced by the geometry of the surface that it flows across (e.g. fault scarps or folds on the base-salt surface). This can lead to coupling of sub- and supra-salt structures, with the orientation and distribution of base-salt structures reflected in the structure of the overburden. However, precisely what controls the degree of strain coupling during salt-detached translation is still poorly understood, in particular the role played by salt thickness and lithological heterogeneity. This partly reflects the fact that it can be difficult to deconvolve the relative contributions of natural variables such as the magnitude of relief, sediment supply, and regional tectonic regime. In addition, seismic data provide only the present structural configuration of salt basins, from which their formative kinematics must be inferred. If we can develop a better understanding of how sub-salt structure controls the types and patterns of supra-salt deformation, we can produce better kinematic (structural) restorations of salt basins and, therefore, have a better understanding of the related mechanics.</p><p>In order to isolate the influence of salt thickness and heterogeneity on sub- to supra-salt strain coupling during salt-detached horizontal translation, we present a series of physical analogue models with controlled boundary conditions. We use a simple base-salt geometry comprising three oblique base-salt steps, and vary the thickness and composition of the ductile salt analogue in each experiment. X-ray tomography allows us to image the internal structure during model evolution and therefore gain a 4D picture of its structural development.</p><p>Results show that thicker and more homogeneous salt units experience more vertical movement (i.e. minibasin subsidence and diapiric rise) and the overburden structure is less explicitly coupled with the underlying base-salt relief. Conversely, thinner and more heterogeneous salt units restrict vertical movement, and therefore the resulting overburden structure is dominated by lateral movement and more closely coupled to the geometry of the base-salt surface. These results highlight the important role of base-salt relief in the subsequent structural evolution of salt basins and why, despite broad similarities between different salt basins, there is significant variability in their structural styles.</p>

Absolute Nodal Coordinate Formulation-Based Decoupled-Stranded Model for Flexible Cables With Large Deformation

The existing flexible cable dynamics model, established using the absolute nodal coordinate formulation (ANCF), suffers from the issue of strain coupling. It also does not consider the nonlinear mechanical properties inside the flexible cable and consequently provides an inaccurate description of the strain and the constitutive properties. In this study, the axial strain of the flexible cable was redescribed by constructing an equivalent rod element in order to decouple the axial strain and bending strain. Subsequently, a strain-decoupled ANCF cable element was derived. Then, by analyzing the geometry of the stranded flexible cable as well as the relative sliding and friction between the wires in the cable, the axial stiffness and bending stiffness calculation formulae were obtained and the decoupled-stranded model was established. This study, therefore, achieved an improvement upon the traditional model in describing the strain and constitutive properties. The simulation results show that the decoupled model eliminates the strain coupling effect compared with the traditional model and has the advantages of fast convergence and high accuracy. The stiffness characteristics analysis shows that the bending stiffness of the cable changes during the bending process due to the relative motion and friction between the wires. Finally, the comparative analysis shows that the accuracy of the decoupled-stranded model is very close to that of the detailed model and performs much better than the other ANCF models, and the complexity of the decoupled-stranded model is far lower than that of the detailed model.

Mechanisms for collective inversion-symmetry breaking in dabconium perovskite ferroelectrics

We show that the combination of molecular shape and strain coupling drives the emergence of polarisation in methyldabconium perovskite ferroelectrics.

Expanded Byrne model for evaluating seismic compression

Seismic compression is the accrual of contractive volumetric strain in unsaturated or partially saturated sandy soils during earthquake shaking and has caused significant distress to overlying and nearby structures. The phenomenon can be well characterized by load-dependent, interaction macro-level fatigue theories. Toward this end, the Byrne cyclic shear-volumetric strain coupling model is expanded and calibrated for evaluating seismic compression for several soil types. In addition, the model was transformed to allow it to be implemented in a “simplified” manner, in addition to the original “non-simplified” formulation. Both implementation approaches are used to analyze a site in Japan impacted by the 2007, Mw6.6 Niigata-ken Chuetsu-oki earthquake. The results from the analyses are in general accord with the post-earthquake field observations and highlight the sensitivity of predicted magnitude of the seismic compression to the input variables used and modeling assumptions (e.g. relative density of the soil, magnitude of the volumetric threshold strain, orientation of the ground motions, settlement of soils below the ground water table, and accounting for multidirectional shaking). Although additional studies are needed to further validate the findings presented herein, estimation of relative density and threshold shear strain of the soil and ground motion orientation individually have moderate-to-significant influence on the computed magnitude of seismic compression, but they have a significant influence when taken in combination. Also, the seismic compression models can seemingly be used to predict the settlement in fully saturated sand when the excess pore water pressures are limited. Finally, accounting for multidirectional shaking has a significant influence on the computed magnitude of seismic compression.

Giant electrochemical actuation in a nanoporous silicon-polypyrrole hybrid material

The absence of piezoelectricity in silicon makes direct electromechanical applications of this mainstream semiconductor impossible. Integrated electrical control of the silicon mechanics, however, would open up new perspectives for on-chip actuorics. Here, we combine wafer-scale nanoporosity in single-crystalline silicon with polymerization of an artificial muscle material inside pore space to synthesize a composite that shows macroscopic electrostrain in aqueous electrolyte. The voltage-strain coupling is three orders of magnitude larger than the best-performing ceramics in terms of piezoelectric actuation. We trace this huge electroactuation to the concerted action of 100 billions of nanopores per square centimeter cross section and to potential-dependent pressures of up to 150 atmospheres at the single-pore scale. The exceptionally small operation voltages (0.4 to 0.9 volts), along with the sustainable and biocompatible base materials, make this hybrid promising for bioactuator applications.