Quasi-continuous melting of model polymer monolayers prompts reinterpretation of polymer melting

Condensed matter textbooks teach us that melting cannot be continuous and indeed experience, including with polymers and other long-chain compounds, tells us that it is a strongly first-order transition. However, here we report nearly continuous melting of monolayers of ultralong n-alkane C390H782 on graphite, observed by AFM and reproduced by mean-field theory and MD simulation. On heating, the crystal-melt interface moves steadily and reversibly from chain ends inward. Remarkably, the final melting point is 80 K above that of the bulk, and equilibrium crystallinity decreases continuously from ~100% to <50% prior to final melting. We show that the similarity in melting behavior of polymers and non-polymers is coincidental. In the bulk, the intermediate melting stages of long-chain crystals are forbidden by steric overcrowding at the crystal-liquid interface. However, there is no crowding in a monolayer as chain segments can escape to the third dimension.

Mechanism of Continuous Melting and Secondary Contact Melting in Resistance Heating Metal Wire Additive Manufacturing

Resistance heating metal wire materials additive manufacturing technology is of great significance for space environment maintenance and manufacturing. However, the continuous deposition process has a problem in which the metal melt is disconnected from the base metal. In order to study the difference between the second contact melting of the disconnected metal melt and the continuous melting of the metal wire as well as eliminate the problem of the uneven heat dissipation of the base metal deposition on the melting process of the metal wire, the physical test of melting the metal wire clamped by the equal diameter conductive nozzle was carried out from the aspects of temperature distribution, temperature change, melting time, dynamic resistance change, and the microstructure. The current, wire length, and diameter of the metal wire are used as variables. It was found that the dynamic resistance change of the wire can be matched with the melting state. During the solid-state temperature rise, due to the presence of the contact interface, the continuous melting and secondary contact melting of metal wires differ in dynamic resistance and the melting process. The continuous melting of the metal wire was caused by the overall resistance of the wire to generate heat and melt, and the temperature distribution is “bow-shaped”. In the second contact melting, the heat generated by the contact interface resistance was transferred to both ends of the metal wire to melt, and the temperature distribution is “inverted V”. The microstructure of the metal wire continuous melting and secondary contact melting solidification is similar. The continuous melting length of the metal wire is greater than the melting length of the secondary contact.