Propagation of Nano Sized CDG Deep into Porous Media

Enhanced Oil Recovery (EOR) technologies become more critical as number of mature oilfields grows continually. Among the variety of chemical EOR methods, conventional application of the polymer-based solutions occupies the largest space. One of the most perspective technologies is application of polymeric fluids that do not contain a 3D polymer structure. Among such compositions, colloid dispersion systems are especially worth mentioning as they could be simultaneously used for water-oil mobility ratio control as well as permeability profile modification. Presented study considers the propagation of colloidal dispersed gels in porous media under different mineralization of formation water. For this purpose were conducted rheological measurements, Particle size distribution and Propagation experiments. The results show that divalent ions cause higher viscosity reduction due to the formation a more severe electrolyte and average particle size decreased with ionic strength increment. The presence of divalent ions improves the propagation probably by cause of repulsion forces increase.

Universal and Programmable Thinning and Thickening of Topologically-Active DNA Fluids

Understanding and controlling the rheology of polymeric fluids that are out-of-equilibrium is a fundamental problem in biology and industry. For example, to package, repair, and replicate DNA, cells use enzymes to constantly manipulate DNA topology, length, and structure. Inspired by this impressive feat, we combine experiments with theory and simulations to show that complex fluids of entangled DNA display a rich range of non-equilibrium material properties when undergoing enzymatic reactions that alter their topology and size. We reveal that while enzymatically-active fluids of linear DNA display universal viscous thinning, circular DNA fluids - undergoing the same non-equilibrium process - display thickening with a rate and degree that can be tuned by the DNA and enzyme concentrations. Our results open the way for the topological functionalization of DNA-based materials via naturally occurring enzymes to create a new class of "topologically-active" materials that can autonomously alter their rheological properties in a programmable manner.

DNA topology dictates strength and flocculation in DNA-microtubule composites

Polymer composites are ubiquitous in biology and industry alike, owing to their emergent desirable mechanical properties not attainable in single-species systems. At the same time, polymer topology has been shown to play a key role in tuning the rheology of polymeric fluids. However, how topology impacts the rheology of composites remains poorly understood. Here, we create composites of rigid rods (microtubules) polymerized within entangled solutions of flexible linear and ring polymers (DNA). We couple linear and nonlinear optical tweezers microrheology with confocal microscopy and scaled particle theory to show that composites of linear DNA and microtubules exhibit a strongly non-monotonic dependence of elasticity and stiffness on microtubule concentration due to depletion-driven polymerization and flocculation of microtubules. In contrast, composites of ring DNA and microtubules show a much more modest monotonic increase in elastic strength with microtubule concentration, which we demonstrate arises from the increased ability of rings to mix with microtubules.

Electrokinetics of polymeric fluids in narrow rectangular confinements

Flow of polymeric liquids in narrow confinements of rectangular cross section, in the presence of electrical double layers is analyzed here. Our analysis is motivated by the fact that many...

A multi-scale method for complex flows of non-Newtonian fluids

<abstract><p>We introduce a new heterogeneous multi-scale method for the simulation of flows of non-Newtonian fluids in general geometries and present its application to paradigmatic two-dimensional flows of polymeric fluids. Our method combines micro-scale data from non-equilibrium molecular dynamics (NEMD) with macro-scale continuum equations to achieve a data-driven prediction of complex flows. At the continuum level, the method is model-free, since the Cauchy stress tensor is determined locally in space and time from NEMD data. The modelling effort is thus limited to the identification of suitable interaction potentials at the micro-scale. Compared to previous proposals, our approach takes into account the fact that the material response can depend strongly on the local flow type and we show that this is a necessary feature to correctly capture the macroscopic dynamics. In particular, we highlight the importance of extensional rheology in simulating generic flows of polymeric fluids.</p></abstract>

Polymer viscosifier systems with potential application for enhanced oil recovery: a review

Due to the growing demand for oil and the large number of mature oil fields, Enhanced Oil Recovery (EOR) techniques are increasingly used to increase the oil recovery factor. Among the chemical methods, the use of polymers stands out to increase the viscosity of the injection fluid and harmonize the advance of this fluid in the reservoir to provide greater sweep efficiency. Synthetic polymers based on acrylamide are widely used for EOR, with Partially Hydrolyzed Polyacrylamide (PHPA) being used the most. However, this polymer has low stability under harsh reservoir conditions (High Temperature and Salinity – HTHS). In order to improve the sweep efficiency of polymeric fluids under these conditions, Hydrophobically Modified Associative Polymers (HMAPs) and Thermo-Viscosifying Polymers (TVPs) are being developed. HMAPs contain small amounts of hydrophobic groups in their water-soluble polymeric chains, and above the Critical Association Concentration (CAC), form hydrophobic microdomains that increase the viscosity of the polymer solution. TVPs contain blocks or thermosensitive grafts that self-assemble and form microdomains, substantially increasing the solution’s viscosity. The performance of these systems is strongly influenced by the chemical group inserted in their structures, polymer concentration, salinity and temperature, among other factors. Furthermore, the application of nanoparticles is being investigated to improve the performance of injection polymers applied in EOR. In general, these systems have excellent thermal stability and salinity tolerance along with high viscosity, and therefore increase the oil recovery factor. Thus, these systems can be considered promising agents for enhanced oil recovery applications under harsh conditions, such as high salinity and temperature. Moreover, stands out the use of genetic programming and artificial intelligence to estimate important parameters for reservoir engineering, process improvement, and optimize polymer flooding in enhanced oil recovery.

A Simple Construction of a Thermodynamically Consistent Mathematical Model for Non-Isothermal Flows of Dilute Compressible Polymeric Fluids

We revisit some classical models for dilute polymeric fluids, and we show that thermodynamically consistent models for non-isothermal flows of these fluids can be derived in a very elementary manner. Our approach is based on the identification of energy storage mechanisms and entropy production mechanisms in the fluid of interest, which, in turn, leads to explicit formulae for the Cauchy stress tensor and for all of the fluxes involved. Having identified these mechanisms and derived the governing equations, we document the potential use of the thermodynamic basis of the model in a rudimentary stability analysis. In particular, we focus on finite amplitude (nonlinear) stability of a stationary spatially homogeneous state in a thermodynamically isolated system.