Late Eocene–early Miocene evolution of the southern Australian subtropical front: a marine palynological approach

Improvements in our capability to reconstruct ancient surface-ocean conditions based on organic-walled dinoflagellate cyst (dinocyst) assemblages from the Southern Ocean provide an opportunity to better establish past position, strength and oceanography of the subtropical front (STF). Here, we aim to reconstruct the late Eocene to early Miocene (37–20 Ma) depositional and palaeoceanographic history of the STF in the context of the evolving Tasmanian Gateway as well as the potential influence of Antarctic circumpolar flow and intense waxing and waning of ice. We approach this by combining information from seismic lines (revisiting existing data and generating new marine palynological data from Ocean Drilling Program (ODP) Hole 1168A) in the western Tasmanian continental slope. We apply improved taxonomic insights and palaeoecological models to reconstruct the sea surface palaeoenvironmental evolution. Late Eocene–early Oligocene (37–30.5 Ma) assemblages show a progressive transition from dominant terrestrial palynomorphs and inner-neritic dinocyst taxa as well as cysts produced by heterotrophic dinoflagellates to predominantly outer-neritic/oceanic autotrophic taxa. This transition reflects the progressive deepening of the western Tasmanian continental margin, an interpretation supported by our new seismic investigations. The dominance of autotrophic species like Spiniferites spp. and Operculodinium spp. reflects relatively oligotrophic conditions, like those of regions north of the modern-day STF. The increased abundance in the earliest Miocene of Nematosphaeropsis labyrinthus, typical for modern subantarctic zone (frontal) conditions, indicates a cooling and/or closer proximity of the STF to the site . The absence of major shifts in dinocyst assemblages contrasts with other records in the region and suggests that small changes in surface oceanographic conditions occurred during the Oligocene. Despite the relatively southerly (63–55∘ S) location of Site 1168, the rather stable oceanographic conditions reflect the continued influence of the proto-Leeuwin Current along the southern Australian coast as Australia continued to drift northward. The relatively “warm” dinocyst assemblages at ODP Site 1168, compared with the cold assemblages at Antarctic Integrated Ocean Drilling Program (IODP) Site U1356, testify to the establishment of a pronounced latitudinal temperature gradient in the Oligocene Southern Ocean.

Mineral Geochemistry of Basaltic Rocks from IODP Expeditions 334 and 344: Implications for Magmatic Processes of Cocos Ridge Segment Being Subducted Beneath the Middle America Trench

The Cocos Ridge, which is subducted beneath the Central American Volcanic Arc, has a complex tectonic evolution history due to plume-ridge interaction between the Galápagos plume and the Cocos—Nazca spreading center. This study presents major and trace element analyses of plagioclase and clinopyroxenes hosted by Cocos Ridge basaltic rocks that were drilled in three holes (U1381A, U1381C and U1414A) of Sites U1381 and U1414 on the Cocos Ridge close to the Middle America Trench during the Integrated Ocean Drilling Program (IODP) Expeditions 334 and 344. The results show that (1) plagioclases are mainly bytownite and labradorite with subordinate andesine, which are enriched in light rare earth elements (LREE) and some large-ion lithophile elements (LILE) and exhibit marked positive Eu anomalies; and (2) that clinopyroxenes are augites, which are depleted in highly incompatible elements such as LREE and LILE, have nearly flat heavy rare earth elements patterns (HREE) and lack Eu anomalies in chondrite-normalized rare earth element (REE) diagrams. During the ascent to the surface, the primary magmas experienced fractional crystallization of plagioclase, clinopyroxene, Ti-Fe oxides and possibly olivine (complete replacement of olivine by secondary minerals). The crystallization temperatures of plagioclase phenocrysts and microlites are 1050 to 1269 °C, and 866 to 1038 °C, respectively, and the pressures of plagioclase phenocrysts are 0.3–0.7 GPa. The crystallization temperatures of clinopyroxene phenocrysts/micro-phenocrysts is 1174–1268 °C, similar to those of plagioclase phenocrysts, suggesting some of clinopyroxene and plagioclase phenocrysts cotectic crystallized during early stage of magmatic evolution. In addition, the equilibrium pressures of clinopyroxene phenocrysts/micro phenocrysts are 0.02–0.97 GPa, implying that the clinopyroxene started to crystallize within the mantle, and magma evolution has undergone an early crystallization stage with clinopyroxene and no plagioclase.

Clay minerals modulate early carbonate diagenesis

Early diagenetic precipitation of authigenic carbonate has been a globally significant carbon sink throughout Earth history. In particular, SO4 2– and Fe3+ reduction and CH4 production create conditions in pore fluids that promote carbonate mineral precipitation; however, these conditions may be modified by the presence of acid-base buffers such as clay minerals. We integrated the acid-base properties of clay minerals into a biogeochemical model that predicts the evolution of pore-water pH and carbonate mineral saturation during O2, Fe3+, and SO42– reduction and CH4 production. Key model inputs were obtained using two natural clay mineral–rich sediments from the Integrated Ocean Drilling Program as well as from literature. We found that clay minerals can enhance carbonate mineral saturation during O2 and SO42– reduction and moderate saturation during Fe3+ reduction and CH4 production if the pore-fluid pH and clay mineral pKa values are within ~2 log units of one another. We therefore suggest that clay minerals could significantly modify the environmental conditions and settings in which early diagenetic carbonate precipitation occurs. In Phanerozoic marine sediments—where O2 and SO42– have been the main oxidants of marine sedimentary organic carbon—clay minerals have likely inhibited carbonate dissolution and promoted precipitation of authigenic carbonate.

Sedimentological characterization of coarse sediments within the deglaciation sequence in the east Antarctic Wilkes Land margin

<p>During the Holocene, 180 m of diatom ooze sediments were deposited in the Antarctic Wilkes Land margin continental shelf at site U1357A (Integrated Ocean Drilling Program Expedition 318, Escutia et al., 2011). Holocene sediments are dominated by rhythmic laminated deposits above a poorly sorted gravelly siltstone diamicton from the Last Glacial Maximum (LGM). CT-scans reveal three events of gravel/sand/silt sediments interbedded within the laminated sediments and interpreted as ice rafted debris (IRD).  Two of these events (from 185,1 to 185,45 and 174, 8 to 175,37 meters below seafloor, mbsf) are characterized by dispersed large clasts (1-5cm) within a muddy matrix at the base, transitioning to the top to millimetre-size clasts that are either aligned with the dark and light laminae or dispersed. A third event (176,2 to 177,2 mbsf) is characterized by a structureless sediment sequence with high concentrations of dispersed clasts that are up to 1-2 cm size. We used ImageJ/Fiji software, to conduct a quantitative analysis of grains bigger than 1mm in CT Scan 3D images. Measured parameters include grain size (Feret length), grain orientation (Feret angle), circularity and roundness, among other. In addition, grey scale profiles have been created from the sediment CT-scan images as a density proxy. Quantitative data and density profiles have been used to aid the sedimentological characterization of the Holocene deglaciation section and to infer depositional environment and patterns of deglaciation.</p><p>Escutia, C., Brinkhuis, H., Klaus, A., and the Expedition 318 Scientists, Proc. IODP, 318: Site 1357. Tokyo (Integrated Ocean Drilling Program Management International, Inc.). doi:10.2204/​iodp.proc.318.105.2011</p><p> </p>

A Long-Term Geothermal Observatory Across Subseafloor Gas Hydrates, IODP Hole U1364A, Cascadia Accretionary Prism

We report 4 years of temperature profiles collected from May 2014 to May 2018 in Integrated Ocean Drilling Program Hole U1364A in the frontal accretionary prism of the Cascadia subduction zone. The temperature data extend to depths of nearly 300 m below seafloor (mbsf), spanning the gas hydrate stability zone at the location and a clear bottom-simulating reflector (BSR) at ∼230 mbsf. When the hole was drilled in 2010, a pressure-monitoring Advanced CORK (ACORK) observatory was installed, sealed at the bottom by a bridge plug and cement below 302 mbsf. In May 2014, a temperature profile was collected by lowering a probe down the hole from the ROV ROPOS. From July 2016 through May 2018, temperature data were collected during a nearly two-year deployment of a 24-thermistor cable installed to 268 m below seafloor (mbsf). The cable and a seismic-tilt instrument package also deployed in 2016 were connected to the Ocean Networks Canada (ONC) NEPTUNE cabled observatory in June of 2017, after which the thermistor temperatures were logged by Ocean Networks Canada at one-minute intervals until failure of the main ethernet switch in the integrated seafloor control unit in May 2018. The thermistor array had been designed with concentrated vertical spacing around the bottom-simulating reflector and two pressure-monitoring screens at 203 and 244 mbsf, with wider thermistor spacing elsewhere to document the geothermal state up to seafloor. The 4 years of data show a generally linear temperature gradient of 0.055°C/m consistent with a heat flux of 61–64 mW/m2. The data show no indications of thermal transients. A slight departure from a linear gradient provides an approximate limit of ∼10−10 m/s for any possible slow upward advection of pore fluids. In-situ temperatures are ∼15.8°C at the BSR position, consistent with methane hydrate stability at that depth and pressure.

Integrated Pliocene-Pleistocene magnetostratigraphy and tephrostratigraphy of deep-sea sediments at IODP Site U1424 (Yamato Basin, Japan Sea)

Sediments from the semi-enclosed Japan Sea are sensitive to paleoclimatic perturbations and they offer great opportunities for many regional and global paleoceanographic and paleoclimatic studies. These studies often require a robust chronology. However, due to rare preservation of calcareous microfossils and drastic changes in surface water salinity during glacial lowstands, the construction of a traditional oxygen isotope stratigraphy for Japan Sea sediments is often difficult. Here, we use sediments recovered at Integrated Ocean Drilling Program (IODP) Expedition 346 Site U1424 to build an integrated Pliocene-Pleistocene reference magnetostratigraphy and tephrostratigraphy for sedimentary sequences from the region. Rock magnetic experiments indicate that magnetic remanence of Site U1424 sediments are carried primarily by (titano)magnetite with small contributions from high coercivity minerals (e.g., hematite) and possibly iron sulphides (pyrrhotite and/or greigite). Dark-colored sediments appear to contain less (titano)magnetite probably due to reductive diagenesis under euxinic conditions. Natural remanent magnetization (NRM) of u-channel samples covering a continuous ~ 167.6 m sediment sequence at Site U1424 was repeatedly measured at 1 cm intervals before and after stepwise demagnetization. Despite lower NRM intensity in dark-colored sediments, NRM directional data from both dark- and light-colored sediments are considered suitable for the construction of magnetostratigraphy. Site U1424 sediments clearly recorded the majority of the polarity chrons and subchrons within the last ~ 4.89 Myr, with the Cobb Mountain subchron, the end of Kaena subchron, and the onset of Nunivak subchron less well preserved. Sixteen tephra layers from the site were sampled for chemical composition analyses and the results were correlated to reference tephrostratigraphy of the region. Ages of the identified tephras are consistent with and can be well integrated with the magnetostratigraphy. The resulting age model suggests that sedimentation rates at Site U1424 range between ~ 1.7 and 7.6 cm/kyr with an average of ~ 3.3 cm/kyr. The acquired magnetostratigraphy and tephrostratigraphy at Site U1424 provide a reference chronology that can be correlated with and transferred to other sediment sequences in the region to study paleoceanographic and paleoclimatic changes of the region as well as their links to other regional and global changes. Graphical abstract

VOLCORE, a global database of visible tephra layers sampled by ocean drilling

The VOLCORE (Volcanic Core Records) database is a collection of 34,696 visible tephra (volcanic ash and lithological or grain size variations) occurrences reported in the initial reports volumes of all of the Deep Sea Drilling Project (DSDP; 1966–1983), the Ocean Drilling Program (ODP; 1983–2003), the Integrated Ocean Drilling Program (IODP; 2003–2013) and the International Ocean Discovery Program (IODP; 2013-present) up to and including IODP Expedition 381. The combined international ocean drilling programmes (OD) have locations with global coverage. Cored tephra layers and tephra-bearing sediments span timescales from recent to ~150 million years in age. This database is a collection of information about reported visible tephra layers entirely or predominantly composed of volcanic ash. Data include the depth below sea floor, tephra thickness, location, and any reported comments. An approximate age was estimated for most (29,493) of the tephra layers using published age-depth models. The database can be used as a starting point for studies of tephrochronology, volcanology, geochemistry, studies of sediment transport and palaeoclimatology.

High resolution CO2 record of the great Plio-Pleistocene glaciations using boron isotopes

<p>The intensification of Northern Hemisphere glaciation (iNHG) at 3.4-2.5 million years ago (Ma) represents the last great transition in Cenozoic climate state with the development of large scale ice sheets in the Northern Hemisphere that waxed and waned with changes in insolation. Declining atmospheric CO<sub>2</sub> levels are widely suggested to have been the main cause of iNHG but the CO<sub>2</sub> proxy record is too poorly resolved to provide an adequate test of this hypothesis. The boron isotope-pH proxy, in particular, has shown promise when it comes to accurately estimating past CO<sub>2</sub> concentrations and is very good at reconstructing relative changes in CO<sub>2</sub> on orbital timescales. Here we present a new orbitally resolved record of atmospheric CO<sub>2 </sub>(1 sample per 3 kyr) change from Integrated Ocean Drilling Program Site 999 (12.74˚N, -78.74 ˚E) spanning ~2.6–2.4 Ma based on the boron isotope (δ<sup>11</sup>B) composition of planktic foraminiferal calcite, <em>Globingerinoides ruber</em> (senso stricto, white).  We find that δ<sup>11</sup>B values of <em>G. ruber</em> show clear glacial-interglacial cycles with a magnitude that is similar to those of the Mid-Pleistocene at the same site and elsewhere.  This new high-resolution view of CO<sub>2</sub> during the first large glacial events of the Pleistocene confirms the importance of CO<sub>2</sub> in amplifying orbital forcing of climate and offers new insights into the mechanistic drivers of natural CO<sub>2</sub> change. </p>

Slip-dependent weakening revealed for a shallow megasplay fault in the Nankai subduction zone

<p>The Nankai Trough megasplay fault likely hosts different modes of fault slip, from slow to megathrust earthquakes, and is responsible for related phenomena such as tsunamis and submarine landslides. All types of slip events require some kind of frictional weakening process (e.g. slip and/or velocity weakening) in order to nucleate and propagate. Most frictional earthquake studies analyze the velocity dependence of friction but disregard the slip dependence of friction observed in experimental friction studies.</p><p>We tested fluid-saturated powdered megasplay fault samples from Integrated Ocean Drilling Program Site C0004 in a direct shear apparatus under effective normal stresses from 2 – 18 MPa to investigate the velocity- and slip-dependence of friction of the megasplay fault. For every tested effective normal stress, we performed one velocity-step experiment and two constant velocity experiments (no velocity step). In the velocity-step experiments the samples were sheared to a total displacement of 10 mm, with an initial sliding velocity V<sub>0</sub> = 0.1 µm/s for the first ~5 mm (run-in) followed by a velocity step increase to V = 1.0 µm/s over the last 5 mm. During the constant velocity experiments, the shearing velocity (0.1 and 1.0 µm/s respectively) was held constant for 10 mm of displacement.</p><p>The velocity-stepping tests showed an evolution from velocity weakening at low effective normal stresses to velocity strengthening at high effective normal stresses. All experiments revealed strong slip-weakening behavior, with the slip dependence having a much larger effect on friction than the velocity dependence. The friction slip dependence is also controlled by the effective normal stress, showing large weakening rate at low effective normal stresses and smaller weakening rate at higher effective normal stresses. Therefore, both frictional weakening mechanisms on the megasplay fault become more effective at shallow depths. This may amplify seafloor deformation by shallow coseismic slip and could increase the tsunamigenic potential of the fault zone.</p>