Epithermal Zeolite Alteration Associated with Siliceous Sinters, Hydrothermal Eruption Breccias, and Gold-Silver Mineralization, Central Taupo Volcanic Zone, New Zealand

In the central Taupo Volcanic Zone, extensive zeolite (mordenite ± clinoptilolite) alteration occurs in late Quaternary rhyolitic vitric tuffs that were deposited in a lake formed by caldera collapse following the ~290 Ka Ohakuri ignimbrite eruptions. Glass shards in lacustrine vitric tuffs of the Ngakuru Formation and in the underlying Ohakuri Formation ignimbrite are replaced by mordenite ± clinoptilolite, along with hydrothermal adularia, opal-A, opal-CT, and cristobalite. This mineral assemblage is also found in the outer alteration zones of the nearby Ohakuri and Tahunaatara epithermal gold prospects. Evaluation of whole-rock chemical analyses indicates that the zeolitized vitric tuffs show a slight gain in K, and Na, Ca loss relative to unaltered Ohakuri Formation pumice, which is reflected in the presence of hydrothermal adularia in the alteration assemblage. The mordenite ± clinoptilolite alteration is associated with siliceous sinters and hydrothermal eruption breccias that were formed in recently active (39–1.5 Ka) geothermal systems. By analogy with geothermal systems elsewhere in the Taupo Volcanic Zone at Wairakei and Ohaaki, the mordenite ± clinoptilolite alteration was formed from dilute alkali-chloride aqueous liquid at 60° to 150°C. Based on the close association of the mordenite ± clinoptilolite alteration with siliceous sinters and hydrothermal eruption breccias in the central Taupo Volcanic Zone, it is classified as shallow, low-temperature, epithermal alteration. Mordenite ± clinoptilolite alteration has also been identified in Quaternary rhyolitic caldera settings in Japan and the United States, where it is termed “caldera-type zeolitization.” In exploration for epithermal Au-Ag deposits in rifted arc settings, such alteration may be overlooked, given its subtle appearance and distal location relative to veins that mark upflow areas.

Hydrothermal eruption dynamics reflecting vertical variations in host rock geology and geothermal alteration, Champagne Pool, Wai-o-tapu, New Zealand

Hydrothermal eruptions are characterised by violent explosions ejecting steam, water, mud, and rock. They pose a risk to tourism and the operation of power plants in geothermal areas around the world. Large events with a severe destructive threat are often intensified by the injection of magmatic fluids along faults and fractures within volcano-tectonic rifting environments, such as the Taupo Volcanic Zone. How these hydrothermal eruptions progress, how craters form and the scale of ejecta impacts, are all influenced by the local geology and reservoir hydrology. By analysing breccia lithology, undisturbed strata proximal to the explosion sites, and conducting tailored decompression experiments, we elucidate the eruption sequence that formed Champagne Pool, Wai-o-tapu, New Zealand. This iconic touristic site was formed by a violent hydrothermal eruption at ~ 700 years B.P. Samples from undisturbed drill cores and blocks ejected in the eruption were fragmented in shock-tube experiments under the moderate pressure/temperature conditions estimated for this system (3–4 MPa, 210–220 °C). Our results show that this was a two-phase eruption. It started with an initial narrow jetting of deep-sourced lithologies, ejecting fragments from at least a 110-m depth. This event was overtaken by a larger, broader, and dominantly shallower eruption driven by decompression of much more geothermal fluid within a soft and porous ignimbrite horizon. The second phase was triggered once the initial, deeper-sourced eruption broke through a strong silicified aquitard cap. The soft ignimbrite collapsed during the second-phase eruption into the crater, to repeatedly choke the explosions causing short-term pressure rises that triggered ongoing deeper-sourced eruptions. The eruption spread laterally also by exploiting a local fault. These results are relevant for hydrothermal eruption hazard scenarios in environments where strong vertical variations in rock strength and porosity occur.

Shallow Magmatic Hydrothermal Eruption in April 2018 on Ebinokogen Ioyama Volcano in Kirishima Volcano Group, Kyushu, Japan

The Kirishima Volcano Group is a volcanic field ideal for studying the mechanism of steam-driven eruptions because many eruptions of this type occurred in the historical era and geophysical observation networks have been installed in this volcano. We made regular geothermal observations to understand the hydrothermal activity in Ebinokogen Ioyama Volcano. Geothermal activity resumed around the Ioyama from December 2015. A steam blowout occurred in April 2017, and a hydrothermal eruption occurred in April 2018. Geothermal activity had gradually increased before these events, suggesting intrusion of the magmatic component fluids in the hydrothermal system under the volcano. The April 2018 eruption was a magmatic hydrothermal eruption caused by the injection of magmatic fluids into a very-shallow hydrothermal system as a bottom–up fluid pressurization, although juvenile materials were not identifiable. Additionally, the upwelling of mixed magma–meteoric fluids to the surface as a kick was observed just before the eruption to cause the top–down flashing of April 2018. A series of events was generated in the shallower hydrothermal regime consisting of multiple systems divided by conductive caprock layers.

Hydrothermal Aluminum-Phosphate-Sulfates in Ash from the 2014 Hydrothermal Eruption at Ontake Volcano, Central Honshu, Japan

Aluminum-phosphate-sulfates (APS) of the alunite supergroup occur in igneous rocks within zones of advanced argillic and silicic alteration in porphyry and epithermal ore environments. In this study we report on the presence of woodhouseite-rich APS in ash from the 27 September 2014 hydrothermal eruption of Ontake volcano. Scanning electron microscope coupled with energy dispersive X-ray spectrometer (SEM-EDS) and field emission (FE)-SEM-EDS observations show two types of occurrence of woodhouseite: (a) as cores within chemically zoned alunite-APS crystals (Zoned-alunite-woodhouseite-APS), and (b) as a coherent single-phase mineral in micro-veinlets intergrown with similar micro-veinlets of silica minerals (Micro-wormy-vein woodhouseite-APS). The genetic environment of APS minerals at Ontake volcano is that of a highly acidic hydrothermal system existing beneath the volcano summit, formed by condensation in magmatic steam and/or ground waters of sulfur-rich magmatic volatiles exsolved from the magma chamber beneath Mt. Ontake. Under these conditions, an advanced argillic alteration assemblage forms, which is composed of silica, pyrophyllite, alunite and kaolinite/dickite, plus APS, among other minerals. The discovery of woodhouseite in the volcanic ash of the Ontake 2014 hydrothermal eruption represents the first reported presence of APS within an active volcano. Other volcanoes in Japan and elsewhere with similar phreatic eruptions ejecting altered ash fragments will likely contain APS minerals derived from magmatic-hydrothermal systems within the subvolcanic environment. The presence of APS minerals within the advanced argillic zone below the summit vent of Ontake volcano, together with the prior documentation of phyllic and potassically altered ash fragments, provides evidence for the existence within an active volcano in Japan of an alteration column comparable to that of porphyry copper systems globally.

Jurassic hot-spring activity in a fluvial setting at La Marciana, Patagonia, Argentina

Silicified rocks at La Marciana farm, Deseado Massif, Argentinean Patagonia, represent an ancient hot-spring discharging into an active fluvial setting. Their fortuitous burial–erosion history and minimal post-depositional structural modification provide an unparalleled view of a complete, exhumed, late Jurassic geothermal landscape, and thus an opportunity to illuminate hot-spring geological context and palaeoenvironmental gradients. Geological mapping, stratigraphy and petrography revealed hydrothermal eruption events, the spring vent source, structural relationships, dimensions of the discharge apron, and hot-spring facies distributions. Remarkable similarities to Quaternary analogues from the Taupo Volcanic Zone, New Zealand, and Yellowstone National Park, USA, are apparent with respect to scale, spatial distribution of facies, and types of microbial and other palaeoenvironmentally significant fabrics.