Interfacial Concentrations of Hydroxytyrosol Derivatives in Fish Oil-in-Water Emulsions and Nanoemulsions and Its Influence on Their Lipid Oxidation: Droplet Size Effects

Reports on the effect of droplet size on the oxidative stability of emulsions and nanoemulsions are scarce in the literature and frequently contradictory. Here, we have employed a set of hydroxytyrosol (HT) esters of different hydrophobicity and fish oil-in-water emulsified systems containing droplets of different sizes to evaluate the effect of the droplet size, surfactant, (ΦI) and oil (ΦO) volume fractions on their oxidative stability. To quantitatively unravel the observed findings, we employed a well-established pseudophase kinetic model to determine the distribution and interfacial concentrations of the antioxidants (AOs) in the intact emulsions and nanoemulsions. Results show that there is a direct correlation between antioxidant efficiency and the concentration of the AOs in the interfacial region, which is much higher (20–200 fold) than the stoichiometric one. In both emulsified systems, the highest interfacial concentration and the highest antioxidant efficiency was found for hydroxytyrosol octanoate. Results clearly show that the principal parameter controlling the partitioning of antioxidants is the surfactant volume fraction, ΦI, followed by the O/W ratio; meanwhile, the droplet size has no influence on their interfacial concentrations and, therefore, on their antioxidant efficiency. Moreover, no correlation was seen between droplet size and oxidative stability of both emulsions and nanoemulsions.

Interfacial Engineering of Pickering Emulsion Co-Stabilized by Zein Nanoparticles and Tween 20: Effects of the Particle Size on the Interfacial Concentration of Gallic Acid and the Oxidative Stability

Lipid oxidation is still one of the major food-safety issues associated with the emulsion-based food systems. Engineering the interfacial region is an effective way to improve the oxidative stability of emulsion. Herein, a novel Pickering emulsion with strong oxidative stability was prepared by using zein nanoparticles and Tween 20 as stabilizers (ZPE). The modulation effects of the particle size on the distribution of gallic acid (GA) and the oxidative stability of ZPE were investigated. In the absence of GA, Pickering emulsions stabilized with different sizes of zein nanoparticles showed similar oxidative stability, and the physical barrier effect took the dominant role in retarding lipid oxidation. Moreover, in the presence of GA, ZPE stabilized by zein nanoparticles with the averaged particle size of 130 nm performed stronger oxidation than those stabilized by zein nanoparticles of 70 and 220 nm. Our study revealed that the interfacial concentration of GA (GAI) was tuned by zein nanoparticles due to the interaction between them, but the difference in the binding affinity between GA and zein nanoparticles was not the dominant factor regulating the (GAI). It was the interfacial content of zein nanoparticles (Γ), which was affected by the particle size, modulated the (GAI) and further dominated the oxidative stability of ZPEs. The present study suggested that the potential of thickening the interfacial layer to prevent lipid oxidation was limited, increasing the interfacial concentration of antioxidant by interfacial engineering offered a more efficient alternative.

Enhancement of the antioxidant efficiency of gallic acid derivatives in intact fish oil-in-water emulsions through optimization of their interfacial concentrations

Knowledge on the interfacial concentration of antioxidants is crucial to understand their efficiency.

Capillary liquid bridge and grain coarsening during liquid phase sintering

The finite element method is employed to simulate the microstructural evolution through grain coarsening within capillary liquid bridge. Liquid and solid phase domains will be represented with curved interfaces defined by the discrete set of points. Numerical method for simulation of grain coarsening will be based on the interfacial concentration as given by the Gibbs-Thomson equation and on modeling of intergrain diffusional interactions. It will be shown that the strong intergrain diffusional interactions can induce large shape distortion of multi grain model. Simulation of the grain coarsening for W-Ni alloy will be demonstrated as a first step.

The history effect in bubble growth and dissolution. Part 1. Theory

The term ‘history effect’ refers to the contribution of any past mass transfer events between a gas bubble and its liquid surroundings towards the current diffusion-driven growth or dissolution dynamics of that same bubble. The history effect arises from the (non-instantaneous) development of the dissolved gas concentration boundary layer in the liquid in response to changes in the concentration at the bubble interface caused, for instance, by variations of the ambient pressure in time. Essentially, the history effect amounts to the acknowledgement that at any given time the mass flux across the bubble is conditioned by the preceding time history of the concentration at the bubble boundary. Considering the canonical problem of an isolated spherical bubble at rest, we show that the contribution of the history effect in the current interfacial concentration gradient is fully contained within a memory integral of the interface concentration. Retaining this integral term, we formulate a governing differential equation for the bubble dynamics, analogous to the well-known Epstein–Plesset solution. Our equation does not make use of the quasi-static radius approximation. An analytical solution is presented for the case of multiple step-like jumps in pressure. The nature and relevance of the history effect is then assessed through illustrative examples. Finally, we investigate the role of the history effect in rectified diffusion for a bubble that pulsates under harmonic pressure forcing in the non-inertial, isothermal regime.

The role of surfactants on the mechanism of the long-wave instability in liquid film flows

The analysis for the physical mechanism of the long-wave instability in liquid film flow is extended to take into account the presence of a surfactant of arbitrary solubility. The Navier–Stokes equations are supplemented by mass balances for the concentrations at the interface and in the bulk, by a Langmuir model for adsorption kinetics at the interface, and are expanded in the limit of long-wave disturbances. The longitudinal flow perturbation, known to result from the perturbation shear stress which develops along the deformed interface, is shown to contribute a convective flux that triggers an interfacial concentration gradient. This gradient is, at leading order, in phase with the interfacial deformation, and as a result produces Marangoni stresses that stabilize the flow. The strength of the interfacial concentration gradient is shown to be maximum for an insoluble surfactant and to decrease with increasing surfactant solubility. The decrease is explained in terms of the spatial phase of mass transfer between interface and bulk, which mitigates the interfacial flux by the flow perturbation and leads to the attenuation of Marangoni stresses. Higher-order terms are derived, which provide corrections for disturbances of finite wavelength.