Correlation between diffusion coefficient values of chloride ions obtained through column and ion migration tests in cementitious matrices with varying contents of silica fume and mortar

Corrosion is one of the main phenomena that lead to pathological manifestations in reinforced concrete structures under aggressive environments. with the chloride ion being the most responsible for its occurrence. In this way, understanding the transport mechanisms of this ion through the microstructure of the concrete is of fundamental importance to prevent or delay the penetration of these aggressive agents to guarantee a durable structure. In the literature, there are extensive studies concerning the diffusion of chlorides in concrete and the influence of pozzolanic additions in this mechanism. However, only a few correlate the different methods of analysis. This work aims to determine the chloride ion diffusion coefficients in concrete containing various levels of silica fume (5%, 10%, and 15%) or varying the mortar content (54%, 80%, and 100%), and compares the results obtained through column tests and chloride migration tests. It was observed that, although the techniques used were quite distinct, the diffusion values obtained were similar, contributing to the validation of both techniques. Furthermore, the variation in the mortar ratio causes a reduction in the interfacial transition zone of coarse aggregate/mortars and an increase in the content of aluminates, which promotes a similar effect to the use of silica fume.

Chloride Migration in Graphene Oxide Concrete

This paper presents experimental work on the chloride penetration resistance of concrete, incorporating 0%, 2% and 3% Graphene Oxide (GO) by weight of cement. Nine 100mm diameter and 200mm high concrete cylinders were cast in the Materials Laboratory at the University of Plymouth. The cylinders were cut into 50mm thick disks and rapid chloride migration tests were carried out. After the tests, the penetration depth of the disks were measured and chloride migration coefficients were determined. It was found that compared with the control samples, the addition of 2% and 3% GO reduced the migration coefficient of concrete by about 11% and 17% respectively at 28 days after casting. This suggests that the inclusion of GO into a cementitious mix does have a noticeable effect on the increase of chloride resistance and hence the longevity of concrete.

Utilization of Granite powder and Glass Powder in Reactive Powder Concrete: Assessment of Strength and Long Term Durability Properties

This paper aims to assess the mechanical and long-term durability performance of Reactive Powder Concrete (RPC) containing Granite Powder (GrP) as cement replacement and waste Glass Powder (GP) as quartz sand replacement. The workability and mechanical behaviour of RPC containing various proportions of GrP and GP are assessed for different w/b ratios (0.3, 0.35, 0.4 and 0.45). The water resistance and tightness of RPC are measured by monitoring the electrical resistivity, water absorption, sorptivity and chloride migration over a one year period. Results reveal that substitution of GrP and GP at optimum levels of 15% and 30% respectively enhances the performance of RPC with the achievement of satisfiable workability at a 0.35 w/b ratio. A significant increase in the resistance towards chloride penetration and electrical resistivity was also observed with increasing ages. Thus, glass powder and granite powder can be considered as alternative construction materials providing economical and ecological efficiency.

Autogenous Healing of Cracked Mortar Using Modified Steady-State Migration Test against Chloride Penetration

Concrete is a popular building material all over the world, but because of different physiochemical processes, it is susceptible to crack development. One of the primary deterioration processes of reinforced concrete buildings is corrosion of steel bars within the concrete through these cracks. In this regard, a self-healing technique for crack repair would be the best solution to reduce the penetration of chloride ions inside concrete mass. In this study, a rapid chloride migration (RCM) test was conducted to determine the self-healing capacity of cracked mortar. With the help of the RCM test, the steady-state migration coefficient of cracked and uncracked specimens incorporating expansive and crystalline admixtures was calculated. Based on the rate of change of the chloride ion concentrations in the steady-state condition, the migration coefficient was calculated. Furthermore, bulk electrical conductivity tests were also conducted before and after the migration test to understand the self-healing behavior. It was evident from the test results that the self-healing of cracks was helpful to reduce the penetration of chloride ions and that it enhanced the ability of cracked mortar to restrict the chloride ingress. Using this test method, the self-healing capacity of the new self-healing technologies can be evaluated. The RCM test can be an acceptable technique to assess the self-healing ability of cement-based materials in a very short period, and the self-healing capacity can be characterized in terms of the decrease of chloride migration coefficients.

The Rapid Chloride Migration Test in Assessing the Chloride Penetration Resistance of Normal and Lightweight Concrete

Chloride-induced corrosion has been one of the main causes of reinforced concrete deterioration. One of the most used methods in assessing the chloride penetration resistance of concrete is the rapid chloride migration test (RCMT). This is an expeditious and simple method but may not be representative of the chloride transport behaviour of concrete in real environment. Other methods, like immersion (IT) and wetting–drying tests (WDT), allow for a more accurate approach to reality, but are laborious and very time-consuming. This paper aims to analyse the capacity of RCMT in assessing the chloride penetration resistance of common concrete produced with different types of aggregate (normal and lightweight) and paste composition (variable type of binder and water/binder ratio). To this end, the RCMT results were compared with those obtained from the same concretes under long-term IT and WDT. A reasonable correlation between the RCMT and diffusion tests was found, when slow-reactive supplementary materials or porous lightweight aggregates surrounded by weak pastes were not considered. A poorer correlation was found when concrete was exposed under wetting–drying conditions. Nevertheless, the RCMT was able to sort concretes in different classes of chloride penetration resistance under distinct exposure conditions, regardless of the type of aggregate and water/binder ratio.

The Durability of Mortar Containing Alkali Activated Fly Ash-Based Lightweight Aggregate

Beneficiating fly ash as valuable construction material such as artificial lightweight aggregate (LWA) could be an alternative solution to increase the utilization of the industrial by-product. However, generally, LWA is characterized by high porosity and a related high water absorption, which on the one hand allows production of lightweight mortar, but on the other hand can affect its performance. Thus, in this research, the durability performance of mortar composed with alkali-activated fly ash-based LWA, and commercial expanded clay (EC) LWA was investigated. The fly ash LWA was prepared in a pan granulator, with a 6-molar solution of NaOH mixed with Na2SiO3 in a Na2SiO3/NaOH weight ratio of 1.5 being used as activator (FA 6M LWA). The results revealed that mortar containing FA 6M LWA had equivalent mechanical strength with mortar containing EC LWA. The mortar containing FA 6M LWA had comparable capillary water uptake and chloride migration resistance with the reference and EC LWA mortar. Furthermore, the addition of FA 6M LWA was proven to enhance the carbonation resistance in the resulting mortar, due to the denser interfacial transition zone (ITZ) of mortar with LWA.

Investigation on Electrical Resistance of Chloride Penetration of Alkali Activated Slag Concrete

Alternating-current method for measuring chloride penetration resistance of concrete, test method for coulomb electric flux and rapid chloride migration coefficient (RCM) were applied to evaluate the resistance of chloride penetration in alkali-activated slag concrete in this paper. At the same time, the applicability of the above three electrical parameters test methods to the alkali slag concrete was discussed. The results show that NaOH activated slag concrete behaves higher resistance to chloride penetration than water glass activated slag concrete. Blend of fly ash increases the porosity of alkali-activated slag concrete and weakens the resistance of chloride penetration. Correlation coefficient between chloride migration coefficient and AC electrical resistivity is 0.99. There are good correlations among the evaluation results of three electrical parameters test methods, and all of them behave sound applicability to alkali-activated slag concrete.