Influence of Device Geometry on Transport Properties of Topological Insulator Microflakes

In the transport studies of topological insulators, microflakes exfoliated from bulk single crystals are often used because of the convenience in sample preparation and the accessibility to high carrier mobilities. Here, based on finite element analysis, we show that for the non-Hall-bar shaped topological insulator samples, the measured four-point resistances can be substantially modified by the sample geometry, bulk and surface resistivities, and magnetic field. Geometry correction factors must be introduced for accurately converting the four-point resistances to the longitudinal resistivity and Hall resistivity. The magnetic field dependence of inhomogeneous current density distribution can lead to pronounced positive magnetoresistance and nonlinear Hall effect that would not exist in the samples of ideal Hall bar geometry.

Berry curvature generation detected by Nernst responses in ferroelectric Weyl semimetal

The quest for nonmagnetic Weyl semimetals with high tunability of phase has remained a demanding challenge. As the symmetry-breaking control parameter, the ferroelectric order can be steered to turn on/off the Weyl semimetals phase, adjust the band structures around the Fermi level, and enlarge/shrink the momentum separation of Weyl nodes which generate the Berry curvature as the emergent magnetic field. Here, we report the realization of a ferroelectric nonmagnetic Weyl semimetal based on indium-doped Pb1−xSnxTe alloy in which the underlying inversion symmetry as well as mirror symmetry are broken with the strength of ferroelectricity adjustable via tuning the indium doping level and Sn/Pb ratio. The transverse thermoelectric effect (i.e., Nernst effect), both for out-of-plane and in-plane magnetic field geometry, is exploited as a Berry curvature–sensitive experimental probe to manifest the generation of Berry curvature via the redistribution of Weyl nodes under magnetic fields. The results demonstrate a clean, nonmagnetic Weyl semimetal coupled with highly tunable ferroelectric order, providing an ideal platform for manipulating the Weyl fermions in nonmagnetic systems.

Modeling of the Response of Hydrogen Bond Properties on an External Electric Field: Geometry, NMR Chemical Shift, Spin-Spin Scalar Coupling

The response of the geometric and NMR properties of molecular systems to an external electric field has been studied theoretically in a wide field range. It has been shown that this adduct under field approach can be used to model the geometric and spectral changes experienced by molecular systems in polar media if the system in question has one and only one bond, the polarizability of which significantly exceeds the polarizability of other bonds. If this requirement is met, then it becomes possible to model even extreme cases, for example, proton dissociation in hydrogen halides. This requirement is fulfilled for many complexes with one hydrogen bond. For such complexes, this approach can be used to facilitate a detailed analysis of spectral changes associated with geometric changes in the hydrogen bond. For example, in hydrogen-bonded complexes of isocyanide C≡15N-1H⋯X, 1J(15N1H) depends exclusively on the N-H distance, while δ(15N) is also slightly influenced by the nature of X.

Demonstration of reduced neoclassical energy transport in Wendelstein 7-X

Research on magnetic confinement of high-temperature plasmas has the ultimate goal of harnessing nuclear fusion for the production of electricity. Although the tokamak1 is the leading toroidal magnetic-confinement concept, it is not without shortcomings and the fusion community has therefore also pursued alternative concepts such as the stellarator. Unlike axisymmetric tokamaks, stellarators possess a three-dimensional (3D) magnetic field geometry. The availability of this additional dimension opens up an extensive configuration space for computational optimization of both the field geometry itself and the current-carrying coils that produce it. Such an optimization was undertaken in designing Wendelstein 7-X (W7-X)2, a large helical-axis advanced stellarator (HELIAS), which began operation in 2015 at Greifswald, Germany. A major drawback of 3D magnetic field geometry, however, is that it introduces a strong temperature dependence into the stellarator’s non-turbulent ‘neoclassical’ energy transport. Indeed, such energy losses will become prohibitive in high-temperature reactor plasmas unless a strong reduction of the geometrical factor associated with this transport can be achieved; such a reduction was therefore a principal goal of the design of W7-X. In spite of the modest heating power currently available, W7-X has already been able to achieve high-temperature plasma conditions during its 2017 and 2018 experimental campaigns, producing record values of the fusion triple product for such stellarator plasmas3,4. The triple product of plasma density, ion temperature and energy confinement time is used in fusion research as a figure of merit, as it must attain a certain threshold value before net-energy-producing operation of a reactor becomes possible1,5. Here we demonstrate that such record values provide evidence for reduced neoclassical energy transport in W7-X, as the plasma profiles that produced these results could not have been obtained in stellarators lacking a comparably high level of neoclassical optimization.

Inductive Tracking Methodology for Wireless Sensors in Photoreactors

In this paper, we present a methodology for locating wireless sensors for the use in photoreactors. Photoreactors are, e.g., used to cultivate photosynthetic active microorganisms. For measuring important parameters like, e.g., the temperature inside the reactor, sensors are needed. Wireless locatable floating sensors would enable it to measure the data anywhere inside the reactor and to get a spatial resolution of the registered data. Due to the well defined propagation properties of magnetic fields and the fact that they are not significantly influenced in underwater environments when using low frequencies, a magnetic induction (MI) system is chosen for the data transmission as well as for the localization task. We designed an inductive transmitter and a receiver capable of measuring the magnetic field in every three spatial directions. The transmitting frequency is set at approx. 300kHz. This results in a wavelength of approx. 1km which clearly exceeds the dimensions of our measurement setup where the transmitter–receiver distances in general are lower than one meter. Due to this fact, only the quasi-static field component has to be considered and the location of the transmitter is calculated by measuring its magnetic field at defined positions and in using the magnetic dipole field equation in order to model its magnetic field geometry. The used measurement setup consists of a transmitter and two receivers. The first measurements were performed without a water filled photoreactor since no differences in the propagation criteria of magnetic fields are expected due to the negligibly low differences in the relative magnetic permeability of water and air. The system is calibrated and validated by using a LIDAR depth camera that is also used to locate the transmitter. The transmitter positions measured with the camera are therefore compared with the inductively measured ones.

Visualizing Water Desaturation in Frozen Gas Diffusion Layers With Flow Field Segmentation via Synchrotron X-Ray Radiography

Synchrotron X-ray tomography images were used to study dynamic, regional water transfer behavior in the gas diffusion layer (GDL) during thawing and desaturation processes. Initially saturated, frozen GDLs were thawed and desaturated with air in a serpentine gas flow channel. On-the-fly (OTF) high speed CT scans via synchrotron X-ray allowed the capture of consecutive water transfer inside the GDL under the cold start-up gas purging condition. Desaturation data of Sigracet 35AA GDLs with three superficial gas velocities (2.88–5.98 m/s) were selected for analysis. Multiple spatial segmentation levels based on the flow field geometry, including channel vs. rib, individual channels and ribs, and smaller sections in each channel and rib, were applied to the in-plane direction to study the GDL regional thawing and desaturation behaviors. Each segmentation volume had a similar desaturation pattern in general; however, water distribution and desaturation show heterogeneity over the GDL domain, as well as relation with factors including the flow field geometry, air traveling distance, and initial saturation level. These data from the segmentation analysis expand the knowledge of localized water transfer behavior during the cold start thawing process. These data can also provide valuable information for future cold start modeling and help in optimizing the PEM fuel cell flow field design.

The paleoinclination of the ancient lunar magnetic field from an Apollo 17 basalt

Paleomagnetic studies of Apollo samples indicate that the Moon generated a core dynamo lasting for at least 2 billion years. However, the geometry of the lunar magnetic field is still largely unknown because the original orientations of essentially all Apollo samples have not been well-constrained. Determining the direction of the lunar magnetic field over time could elucidate the mechanism by which the lunar dynamo was powered and whether the Moon experienced true polar wander. Here we present measurements of the lunar magnetic field 3.7 billion years (Ga) ago as recorded by Apollo 17 mare basalts 75035 and 75055. These samples formed as part of basalt flows in the Taurus-Littrow valley that make up wall-rock within Camelot crater, now exposed at the rim of the crater. Using apparent layering in the parent boulder for 75055, we inferred its original paleohorizontal orientation on the lunar surface at the time of magnetization. We find that 75035 and 75055 record a mean paleointensity of ~50 µT. Furthermore, 75055 records a paleoinclination of 34 ± 11°. This inclination is consistent with, but does not require, a selenocentric axial dipole field geometry (i.e., a dipole in the center of the Moon and aligned along the spin axis). Additionally, although true polar wander is also not required by our data, true polar wander paths inferred from some independent studies of lunar hydrogen deposits and crustal magnetic anomalies are consistent with our measured paleoinclination.