Simultaneous Determination of Fluorine and Chlorine in Marine and Stream Sediment by Ion Chromatography Combined with Alkaline Digestion in a Bomb

Fluorine and chlorine are important tracers for geochemical and environmental studies. In this study, a rapid alkaline digestion (NaOH) method for the simultaneous determination of fluorine and chlorine in marine and stream sediment reference samples using ion chromatography is developed. The proposed method suppresses the volatilization loss of fluorine and chlorine and decreases the matrix effects. The results are in good agreement with fluorine ~100%, chlorine ranging from 90 to 95% of the expected concentrations. The detection limits of this method were 0.05 μg/g for fluorine and 0.10 μg/g for chlorine. This method is simple, economical, precise and accurate, which shows great potential for the rapid simultaneous determination of fluorine and chlorine in large batches of geological and environmental samples commonly analyzed for environmental geochemistry studies.

Overview of surficial geochemistry and indicator mineral surveys and case studies from the Geological Survey of Canada's GEM Program

The Geological Survey of Canada carried out reconnaissance-scale to deposit-scale geochemical and indicator-mineral surveys and case studies across northern Canada between 2008 and 2020 as part of its Geo-mapping for Energy and Minerals (GEM) program. In these studies, surficial geochemistry was used to determine the concentrations of up to 65 elements in various sample media including lake sediment, lake water, stream sediment, stream water, or till samples across approximately 1 000 000 km2 of northern Canada. As part of these surficial geochemistry surveys, indicator mineral methods were also used in regional-scale and deposit-scale stream sediment and till surveys. Through this program, areas with anomalous concentrations of elements and/or indicator minerals that are indicative of bedrock mineralization were identified, new mineral exploration models and protocols were developed, a new generation of geoscientists was trained, and geoscience knowledge was transferred to northern communities. Regional- and deposit-scale studies demonstrated how transport data (till geochemistry, indicator mineral abundance) and ice-flow indicator data can be used together to identify and understand complex ice flow and glacial transport. Detailed studies at the Izok Lake Zn-Cu-Pb-Ag VMS, Nunavut, the Pine Point carbonate-hosted Pb-Zn in the Northwest Territories, the Strange Lake REE deposit in Quebec and Labrador as well as U-Cu-Fe-F and Cu-Ag-Au-Au IOCG deposits in the Great Bear magmatic zone, Northwest Territories demonstrate new suites of indicator minerals that can now be used in future reconnaissance- and regional-scale stream sediment and till surveys across Canada.

Analysis Of Carrying Capacity of The Porong River Caused by Sidoarjo Mud Disposal

This study aims to examine the sediment distribution models and the stream sediment distribution due to mud disposal of Porong River. It examines how the sediment distribution models and deposition, the distribution of stream sediment due to mud disposal along with its impacts on the river's capacity, and whether the mud disposal has a harmful impact on the water quality. The data used were based on topographic and Bathymetric data of Porong River, cross-sections of the river, and terrain sediment distribution patterns. The study conducted field and secondary data analysis, hydrological analysis, oceanographic analysis of Mura River and river hydraulic analysis. The study concludes that to maintain its capacity and prevent negative impacts, it is necessary to protect the cliffs and embankments along the segment of the river. To protect the community pond area, overburden and/or river dredging activities along with the segments from the branch to the estuary of the river are needed. Furthermore, it is also necessary to add artificial inputs such as submersible Kribs that are arranged on piles to deal with problems of river sediments in the mouth of Porong River

ASSAY AND GRAPHITE FURNACE- ATOMIC ABSORBANCE SPECTROMETRY ACCURACY FOR PALLADIUM CONTENT ANALYSIS

Palladium is a member of the expensive Platinum Group Metals as it is indispensable for various applications of modern technology. Due to the very small number of these elements in nature, high-sensitivity analytical methods and devices are required for accurate PGM measurement. The current study aims to determine the accuracy level of the Graphite Furnace-Atomic Absorbance Spectrometry device for palladium analysis after pre-concentration through the assaying process. The studied samples were two in-house standard reference samples with stream sediment and ultramafic rock matrices. Due to the lack of certified reference material containing certain palladium compositions, the degree of accuracy was tested by the spiking method. The detection limit for Pd in this study was 11.79 ppb. Pd content in the stream sediment (17 ppb) is much lower than of the ultramafic sample (290 ppb), implying PGM association to ultramafic rock naturally. Almost all measurements have good accuracy according to spike recovery between 80-120%. Inaccurate addition process and inappropriate calibration range most probably lead to inaccuracy.