Trivalent ion overcharging on electrified graphene

The structure of the electrical double layer (EDL) formed near graphene in aqueous environments strongly impacts its performance for a plethora of applications, including capacitive deionization. In particular, adsorption and organization of multivalent counterions near the graphene interface can promote nonclassical behaviors of EDL including overcharging followed by co-ion adsorption. In this paper, we characterize the EDL formed near an electrified graphene interface in dilute aqueous YCl3 solution using in situ high resolution x-ray reflectivity (also known as crystal truncation rod (CTR)) and resonant anomalous x-ray reflectivity (RAXR). These interface-specific techniques reveal the electron density profiles with molecular-scale resolution. We find that yttrium ions (Y3+) readily adsorb to the negatively charged graphene surface to form an extended ion profile. This ion distribution resembles a classical diffuse layer but with a significantly high ion coverage, i.e., 1 Y3+ per 11.4 ± 1.6 Å2, compared to the value calculated from the capacitance measured by cyclic voltammetry (1 Y3+ per ~240 Å2). Such overcharging can be explained by co-adsorption of chloride that effectively screens the excess positive charge. The adsorbed Y3+ profile also shows a molecular-scale gap (≥5 Å) from the top graphene surfaces, which is attributed to the presence of intervening water molecules between the adsorbents and adsorbates as well as the lack of inner-sphere surface complexation on chemically inert graphene. We also demonstrate controlled adsorption by varying the applied potential and reveal consistent Y3+ ion position with respect to the surface and increasing cation coverage with increasing the magnitude of the negative potential. This is the first experimental description of a model graphene-aqueous system with controlled potential and provides important insights into the application of graphene-based systems for enhanced and selective ion separations.

Investigation of the role of defects on channel density profiles and their effect on the output characteristics of a nanowire FET

This work investigates the effect of defects on the electron density profiles of nanowire FETs with a rectangular cross-section. It also presents a framework for the discretization of the nanowire channels with defects. A self-consistent procedure using Schrodinger-Poisson solver with density matrix formalism calculates the local electron density profiles. The local electron density decreases due to defect-induced scattering potentials. The electron density profiles vary according to the nature of the intrinsic defects. The effect of defect-induced potentials on the output characteristics of the nanowire FET device is studied using the non-equilibrium Green's function (NEGF) methodology. An increase in scattering potential in the nanowire channel causes a considerable decrease in the saturation voltage and current. This results in a faster saturation which changes the overall device performance. Hence, defect-controlled channels can be utilized to fabricate FETs with desired characteristics.

Design of an edge TV Thomson scattering diagnostic system on EAST

The study of the edge plasma has significant effect for the performance improvement of magnetic confinement. However, the Thomson scattering system, which has been used to provide electron temperature and electron density on EAST, do not meet the requirements for the edge plasma measurements in measurement region, spatial and spectral resolution. Herein, a TV Thomson scattering diagnostic system has been constructed for the measurements of edge electron temperature and electron density profiles on EAST. A new laser system, optical collection system and data acquisition system are designed to enable the TV Thomson system operate at the measurement region of 0.65–1.1 ρ (“ρ” is the unitary radius in flux coordinate) with spectral resolution of 5 nm and spatial resolution as low as 2 mm. And the theoretical analysis proves that the system has the measurability at electron temperature of 20–1000 eV and density beyond 0.2 × 1019 m-3, which fulfills research of the pedestal microstructure on EAST. The establishment of the edge TV Thomson system can create the conditions for the edge physical study on EAST.

Validation of SSUSI-derived auroral electron densities: comparisons to EISCAT data

The coupling of the atmosphere to the space environment has become recognized as an important driver of atmospheric chemistry and dynamics. In order to quantify the effects of particle precipitation on the atmosphere, reliable global energy inputs on spatial scales commensurate with particle precipitation variations are required. To that end, we have validated auroral electron densities derived from the Special Sensor Ultraviolet Spectrographic Imager (SSUSI) data products for average electron energy and electron energy flux by comparing them to EISCAT (European Incoherent Scatter Scientific Association) electron density profiles. This comparison shows that SSUSI far-ultraviolet (FUV) observations can be used to provide ionization rate and electron density profiles throughout the auroral region. The SSUSI on board the Defense Meteorological Satellite Program (DMSP) Block 5D3 satellites provide nearly hourly, 3000 km wide high-resolution (10 km×10 km) UV snapshots of auroral emissions. These UV data have been converted to average energies and energy fluxes of precipitating electrons. Here we use those SSUSI-derived energies and fluxes as input to standard parametrizations in order to obtain ionization-rate and electron-density profiles in the E region (90–150 km). These profiles are then compared to EISCAT ground-based electron density measurements. We compare the data from two satellites, DMSP F17 and F18, to the Tromsø UHF radar profiles. We find that differentiating between the magnetic local time (MLT) “morning” (03:00–11:00 MLT) and “evening” (15:00–23:00 MLT) provides the best fit to the ground-based data. The data agree well in the MLT morning sector using a Maxwellian electron spectrum, while in the evening sector using a Gaussian spectrum and accounting for backscattered electrons achieved optimum agreement with EISCAT. Depending on the satellite and MLT period, the median of the differences varies between 0 % and 20 % above 105 km (F17) and ±15 % above 100 km (F18). Because of the large density gradient below those altitudes, the relative differences get larger, albeit without a substantially increasing absolute difference, with virtually no statistically significant differences at the 1σ level.

A High Latitude Model for the E Layer Dominated Ionosphere

Under certain conditions, the ionization of the E layer can dominate over that of the F2 layer. This phenomenon is called the E layer dominated ionosphere (ELDI) and occurs mainly in the auroral regions. In the present work, we model the variation of the ELDI for the Northern and Southern Hemispheres. Our proposed Neustrelitz ELDI Event Model (NEEM) is an empirical, climatological model that describes ELDI characteristics by means of four submodels for selected model observables, considering the dependencies on appropriate model drivers. The observables include the occurrence probability of ELDI events and typical E layer parameters that are important to describe the propagation medium for High Frequency (HF) radio waves. The model drivers are the geomagnetic latitude, local time, day of year, solar activity and the convection electric field. During our investigation, we found clear trends for the model observables depending on the drivers, which can be well represented by parametric functions. In this regard, the submodel NEEM-N characterizes the peak electron density NmE of the E layer, while the submodels NEEM-H and NEEM-W describe the corresponding peak height hmE and the vertical width wvE of the E layer electron density profile, respectively. Furthermore, the submodel NEEM-P specifies the ELDI occurrence probability %ELDI. The dataset underlying our studies contains more than two million vertical electron density profiles covering a period of almost 13 years. These profiles were derived from ionospheric GPS radio occultation observations on board the six COSMIC/FORMOSAT-3 satellites (Constellation Observing System for Meteorology, Ionosphere and Climate/Formosa Satellite Mission 3). We divided the dataset into a modeling dataset for determining the model coefficients and a test dataset for subsequent model validation. The normalized root mean square deviation (NRMS) between the original and the predicted model observables yields similar values across both datasets and both hemispheres. For NEEM-N, we obtain an NRMS varying between 36.1% and 47.1% and for NEEM-H, between 6.1% and 6.3%. In the case of NEEM-W, the NRMS varies between 38.5% and 41.1%, while it varies between 56.5% and 60.3% for NEEM-P. In summary, the proposed NEEM utilizes primary relationships with geophysical and solar wind observables, which are useful for describing ELDI occurrences and the associated changes of the E layer properties. In this manner, the NEEM paves the way for future prediction of the ELDI and of its characteristics in technical applications, especially from the fields of telecommunications and navigation.

On the determination of ionospheric electron density profiles using multi-frequency riometry

Radio wave absorption in the ionosphere is a function of electron density, collision frequency, radio wave polarisation, magnetic field and radio wave frequency. Several studies have used multi-frequency measurements of cosmic radio noise absorption to determine electron density profiles. Using the framework of statistical inverse problems, we investigated if an electron density altitude profile can be determined by using multi-frequency, dual-polarisation measurements. It was found that the altitude profile cannot be uniquely determined from a complete measurement of radio wave absorption for all frequencies and two polarisation modes. This implies that accurate electron density profile measurements cannot be ascertained using multi-frequency riometer data alone, but that the reconstruction requires a strong additional a priori assumption of the electron density profile, such as a parameterised model for the ionisation source. Nevertheless, the spectral index of the absorption could be used to determine if there is a significant component of hard precipitation that ionises the lower part of the D region, but it is not possible to infer the altitude distribution uniquely with this technique alone.

Mutual radio occultation experiment between ExoMars Trace Gas Orbiter and Mars Express: algorithms testing

<p>Radio Occultation (RO) is a very powerful technique to probe a planetary atmosphere, in providing vertical density profiles of the neutral atmosphere and ionosphere. The standard method uses a radio link between a spacecraft and an Earth ground station. Nevertheless, the possibility to obtain information about the Martian atmosphere with mutual RO events, using data from NASA Mars Odyssey and Mars Reconnaissance Orbiters (MRO), has been demonstrated by Ao et al. (2015).<br />Taking advantage of two European spacecraft in orbit around Mars, the European Space Agency is currently preparing experiments of mutual RO between Mars Express (MEX) and the ExoMars Trace Gas Orbiter (TGO). In preparation of MEX and TGO data inversion and analysis, a simulation-based strategy has been adopted and an algorithm able to retrieve vertical electron density profiles from Doppler shift measurements has been implemented and validated. Subsequently, in order to test the mentioned algorithm with experimental data, the same three RO events considered in the paper by Ao et al. (2015) have been processed. In particular, for each RO event, having the information about the satellites’ orbit, the (excess) Doppler shift values corresponding to the Mars Odyssey-MRO ray-paths have been converted to bending angles as a function of impact parameter. Then, assuming a spherical symmetry (Fjeldbo et al., 1971) for the ionosphere electron density, the bending angles have been transformed (through Abel integral) to a vertical refractivity profile, which, in turn, has been converted to an ionospheric electron density profile.<br />In this work, the results obtained by the application of the mentioned inversion algorithm to experimental data will be presented, with particular focus on the retrieval of the ionospheric electron density profiles.</p> <p><strong>References</strong></p> <p>Ao, C. O., C. D. Edwards Jr., D. S. Kahan, X. Pi, S. W. Asmar, and A. J. Mannucci (2015), A first demonstration of Mars crosslink occultation measurements, Radio Sci., 50, 997–1007, doi:10.1002/2015RS005750.</p> <p>Fjeldbo, G., A. J. Kliore, and V. R. Eshleman (1971), The neutral atmosphere of Venus as studied with the Mariner V radio occultation<br />experiments, Astron. J., 76, 123–140.</p>

Surface-response functions obtained from equilibrium electron-density profiles

Surface-response functions are one of the most promising routes for bridging the gap between fully quantum-mechanical calculations and phenomenological models in quantum nanoplasmonics. Among all currently available recipes for obtaining such response functions, the use of ab initio methods remains one of the most conspicuous trends, wherein the surface-response functions are retrieved via the metal’s non-equilibrium response to an external time-dependent perturbation. Here, we present a complementary approach to approximate one of the most appealing surface-response functions, namely the Feibelman d-parameters, yield a finite contribution even when they are calculated solely with the equilibrium properties of the metal, described under the local-response approximation (LRA) but with a spatially varying equilibrium electron density, as input. Using model calculations that mimic both spill-in and spill-out of the equilibrium electron density, we show that the obtained d-parameters are in qualitative agreement with more elaborate, but also more computationally demanding, ab initio methods. The analytical work presented here illustrates how microscopic surface-response functions can emerge out of entirely local electrodynamic considerations.