scholarly journals Hydrogeochemistry Evidence for Impacts of Chemical Acidic Wastewater on Karst Aquifer in Dawu Water Source Area, Northern China

Author(s):  
Henghua Zhu ◽  
Jianwei Zhou ◽  
Zhizheng Liu ◽  
Lizhi Yang ◽  
Yunde Liu

The study of the hydrochemical characteristics and the water–rock interaction of karst groundwater is very important for the rational exploitation of karst groundwater and its pollution control. In this paper, the systematic clustering method was used to analyze the hydrochemical characteristics of different types of groundwater, combined with hydrochemical graphic analysis and correlation analysis to explore the impact of chemical acidic wastewater on the evolution of karst aquifer in the Dawu water source area, northern China. The results show that the chemical acid wastewater, sourcing from discharges/spillages from the local chemical industries, has different degrees of pollution impact on karst groundwater, causing the total hardness of all karst groundwater and the total dissolved solids, Cl− and SO42− in nearly half of the karst groundwater to exceed the quality indexes of class III water in China’s standard for groundwater quality (GB/T 14848-2017). Hydrochloric acid and sulfuric acid in the wastewater can be buffered by the dissolution of carbonate rocks, resulting in a nearly neutral pH (pH-buffering effect) and an increase in Ca2+, Mg2+, Sr, Cl− and SO42− concentrations in karst groundwater.

Water ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1643 ◽  
Author(s):  
Zongjun Gao ◽  
Jiutan Liu ◽  
Fuquan Li ◽  
Min Wang ◽  
Jianguo Feng ◽  
...  

Geothermal water resources are a kind of clean energy, which is a renewable resource to a certain extent and has a high value of development and utilization. To understand the hydrochemical characteristics, origins, and temporal variations of geothermal water quality in Tangtou, 13 geothermal water samples from 2007 to 2019 and geothermal geological conditions were collected. Cl− and Na+ are the major ions, which make the geothermal water belong Cl-Na type. The total dissolved solids values of geothermal waters were 1560–2512 mg/L and pH were in the range of 6.7–8.8. The development of faulted structures provides conditions for the formation of geothermal water. In addition, geothermal water is recharged by shallow underground cold water. Water-rock interaction, as well as mixing processes, in the process of long runoff path and the slower deep-water cycle is the main factor controlling the chemical composition of geothermal water. Calculated saturation index values indicated that the geothermal water was saturated with respect to silicate and carbonate minerals. Cation and silica chemical geothermometers indicated that reservoir temperatures ranged from 94.63 to 196.10 °C and from 69.13 to 123.75 °C, respectively. Based on the grey relational analysis, the main physicochemical components of geothermal water are obviously correlated with the geothermal water exploitation and precipitation. Overall, affected by exploitation and precipitation, main physicochemical components (such as the total dissolved solids, total hardness, temperature, Na+, Ca2+, Cl−, K+, and Mg2+) showed a certain stage.


Water ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 755 ◽  
Author(s):  
Wu ◽  
Shu ◽  
Li ◽  
Chen ◽  
Xu ◽  
...  

Karst aquifers produce the world’s largest springs and supply the water resources to about a quarter of the global population while being influenced by high-intensity human activities. Knowledge about spring discharge hydrographs driven by the effects of artificial regulation is essential to develop practical strategies for the management of karst groundwater. Based on hydrogeological conditions of the karst aquifer in Jinan, a two-dimensional laboratory tank was constructed, and a corresponding numerical simulation model was developed to explore how artificial regulation drives spring hydrographs in northern China. The results showed that the spring hydrographs were significantly changed under the effects of artificial regulation. The recession coefficient increased with pumping and decreased with increasing injection rates. The late sub-recession of spring discharge did not obey the exponential recession under the influence of injection. Pumping and injection in conduit zones showed more obvious effects on the recession coefficient in the late sub-recession curves. Groundwater exchange between conduits and fissure zones differed totally for different artificial regulation modes. With continuing rainfall, the flow fields were gradually controlled by rainfall. There was a time lag in the flow fields caused by rainfall. Under the stress of exploitation at different positions, stagnation points appeared at different locations in fissure zones, and locations of stagnation points were highly dependent on the positions of pumping wells. These findings are essential for better management of karst groundwater and karst spring protection.


2018 ◽  
Vol 14 (4) ◽  
pp. 58
Author(s):  
Zelin Wang ◽  
Ruliang Zhang

The South-to-North Water Transfer Project (SNWTP) in China which is the world’s largest water transfer project completed in 2014 is promoted as a strategy to mitigate water stresses in the northern China by the Chinese government and engineers. However, the ecological compensation of SNWTP in China has been slow and less for the people living in the water source area which was lost their opportunities to earn money; some had even lost their farmland. A key issue for SNWTP is to establish an eco-compensation system, define the compensation scheme, and make an effective economic compensation to the people living in the water source area. In this paper, we take the water source area of the Middle-Route project of SNWTP located in Southern Shaanxi including three cities called Hanzhong, Ankang and Shangluo as the research regions. Six factors are taken into consideration: (1) ecological losses, (2) economic losses and (3) ecological bonus in our eco-compensation strategy, as well as join two dynamic factors accounting in the calculation of ecological damage, (4) water quantity and (5) water quality. Besides, the total amount of compensation is changing over time. (6) Time scale factor is also used to simulate. In the article, we set three-time periods to calculate the different amount of compensation for the water source area. Finally, the Southern Shaanxi, supplied 70% water to Danjiangkou Reservoir, were analyzed by this model. We make full use of the reasonable eco-compensation strategy and try to solve actual problems of water source area and even provide a basis conception for the watershed protection and management.


2018 ◽  
Vol 10 (12) ◽  
pp. 4507 ◽  
Author(s):  
Yanna Yang ◽  
Wenlai Xu ◽  
Jinyao Chen ◽  
Qiang Chen ◽  
Zhicheng Pan

Methods for groundwater quality and pollution assessment are applied extensively, but it is difficult to determine a unified evaluation model. On the basis of hydrogeochemical characteristics analysis in 2016 compared with that in 1995, the five-element connection number SPA (set pair analysis) method was applied to evaluate the groundwater quality of the Gaoqiao diluvial fan under the influence of hydrogeological conditions and human activities along the flow path in our work. Descriptive statistics methods, Piper diagram, and a Schoeller diagram were also used to analyze the hydrochemical characteristics of groundwater such as chemical components, total dissolved solid, and total hardness. The change of the typical pollutant of fluorine was analyzed to evaluate the groundwater quality under the influence of human activities. The results showed that the groundwater quality in the study area was more in rank П. The basic hydrochemical types of shallow groundwater were HCO3-Ca·Mg and HCO3·SO4-Ca·Mg. The influencing factors of the hydrochemical component of groundwater were identified in the Gaoqiao diluvial fan. The quality of groundwater changed slightly from the top to the edge of the fan due to the water–rock interaction except for in Yucun and Hucun influenced by human activities. The assessment result can provide a scientific basis for the pollution prevention and changing process control of the groundwater in the hydrogeological unit of the Gaoqiao diluvial fan.


2021 ◽  
Vol 13 (11) ◽  
pp. 2103
Author(s):  
Yuchen Liu ◽  
Jia Liu ◽  
Chuanzhe Li ◽  
Fuliang Yu ◽  
Wei Wang

An attempt was made to evaluate the impact of assimilating Doppler Weather Radar (DWR) reflectivity together with Global Telecommunication System (GTS) data in the three-dimensional variational data assimilation (3DVAR) system of the Weather Research Forecast (WRF) model on rain storm prediction in Daqinghe basin of northern China. The aim of this study was to explore the potential effects of data assimilation frequency and to evaluate the outputs from different domain resolutions in improving the meso-scale NWP rainfall products. In this study, four numerical experiments (no assimilation, 1 and 6 h assimilation time interval with DWR and GTS at 1 km horizontal resolution, 6 h assimilation time interval with radar reflectivity, and GTS data at 3 km horizontal resolution) are carried out to evaluate the impact of data assimilation on prediction of convective rain storms. The results show that the assimilation of radar reflectivity and GTS data collectively enhanced the performance of the WRF-3DVAR system over the Beijing-Tianjin-Hebei region of northern China. It is indicated by the experimental results that the rapid update assimilation has a positive impact on the prediction of the location, tendency, and development of rain storms associated with the study area. In order to explore the influence of data assimilation in the outer domain on the output of the inner domain, the rainfall outputs of 3 and 1 km resolution are compared. The results show that the data assimilation in the outer domain has a positive effect on the output of the inner domain. Since the 3DVAR system is able to analyze certain small-scale and convective-scale features through the incorporation of radar observations, hourly assimilation time interval does not always significantly improve precipitation forecasts because of the inaccurate radar reflectivity observations. Therefore, before data assimilation, the validity of assimilation data should be judged as far as possible in advance, which can not only improve the prediction accuracy, but also improve the assimilation efficiency.


2021 ◽  
Vol 11 (8) ◽  
pp. 3580
Author(s):  
Cristina Val-Peón ◽  
Juan I. Santisteban ◽  
José A. López-Sáez ◽  
Gerd-Christian Weniger ◽  
Klaus Reicherter

The SW coast of the Iberian Peninsula experiences a lack of palaeoenvironmental and archaeological data. With the aim to fill this gap, we contribute with a new palynological and geochemical dataset obtained from a sediment core drilled in the continental shelf of the Algarve coast. Archaeological data have been correlated with our multi-proxy dataset to understand how human groups adapted to environmental changes during the Early-Mid Holocene, with special focus on the Mesolithic to Neolithic transition. Vegetation trends indicate warm conditions at the onset of the Holocene followed by increased moisture and forest development ca. 10–7 ka BP, after which woodlands are progressively replaced by heaths. Peaks of aridity were identified at 8.2 and 7. 5 ka BP. Compositional, textural, redox state, and weathering of source area geochemical proxies indicates abrupt palaeoceanographic modifications and gradual terrestrial changes at 8.2 ka BP, while the 7.5 ka BP event mirrors a decrease in land moisture availability. Mesolithic sites are mainly composed of seasonal camps with direct access to the coast for the exploitation of local resources. This pattern extends into the Early Neolithic, when these sites coexist with seasonal and permanent occupations located in inland areas near rivers. Changes in settlement patterns and dietary habits may be influenced by changes in coastal environments caused by the sea-level rise and the impact of the 8.2 and 7.5 ka BP climate events.


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