Quantum interference between spin-orbit split partial waves in the F + HD → HF + D reaction

The effect of electron spin-orbit interactions on chemical reaction dynamics has been a topic of much research interest. Here we report a combined experimental and theoretical study on the effect of electron spin and orbital angular momentum in the F + HD → HF + D reaction. Using a high-resolution imaging technique, we observed a peculiar horseshoe-shaped pattern in the product rotational-state–resolved differential cross sections around the forward-scattering direction. The unusual dynamics pattern could only be explained properly by highly accurate quantum dynamics theory when full spin-orbit characteristics were considered. Theoretical analysis revealed that the horseshoe pattern was largely the result of quantum interference between spin-orbit split–partial-wave resonances with positive and negative parities, providing a distinctive example of how spin-orbit interaction can effectively influence reaction dynamics.

Evolution of orbit and clock quality for real-time multi-GNSS solutions

High-quality satellite orbits and clocks are necessary for multi-GNSS precise point positioning and timing. In undifferenced GNSS solutions, the quality of orbit and clock products significantly influences the resulting position accuracy; therefore, for precise positioning in real time, the corrections for orbits and clocks are generated and distributed to users. In this research, we assess the quality and the availability of real-time CNES orbits and clocks for GPS, GLONASS, Galileo, and BeiDou-2 separated by satellite blocks and types, as well as the product quality changes over time. We calculate the signal-in-space ranging error (SISRE) as the main orbit and clock quality indicator. Moreover, we employ independent orbit validation based on satellite laser ranging. We found that the most accurate orbits are currently available for GPS. However, Galileo utmost stable atomic clocks compensate for systematic errors in Galileo orbits. As a result, the SISRE for Galileo is lower than that for GPS, equaling 1.6 and 2.3 cm for Galileo and GPS, respectively. The GLONASS satellites, despite the high quality of their orbits, are characterized by poor quality of clocks, and together with BeiDou-2 in medium and geosynchronous inclined orbits, are characterized by SISRE of 4–6 cm. BeiDou-2 in geostationary orbits is characterized by large orbital errors and the lowest availability of real-time orbit and clock corrections due to a large number of satellite maneuvers. The quality of GNSS orbit and clock corrections changes over time and depends on satellite type, block, orbit characteristics, onboard atomic clock, and the sun elevation above the orbital plane.

Rotordynamic Energy Expressions for General Anisotropic Finite Element Systems

It is often desirable to identify the critical components that are active in a particular mode shape or an operational deflected shape (ODS) in a complex rotordynamic system with multiple rotating groups and bearings. The energy distributions can help identify the critical components of a rotor bearing system that may be modified to match the design requirements. Although the energy expressions have been studied by researchers in the past under specific limited conditions, these expressions require computing the displacements and velocities of all degrees-of-freedom (DOFs) over one full cycle. They do not address the overall time dependency of the energies and energy distributions, and their effect on the interpretation of a mode shape or an ODS. Moreover, a detailed finite element formulation of these energy expressions including the effects of anisotropy, skew-symmetric stiffness, viscous and structural damping have not been identified by the authors in the open literature. In this article, a detailed account of orbit characteristics and planarity for isotropic and anisotropic systems is presented. The effect of orbit characteristics on the energy expressions is then discussed. An elegant approach to obtaining time-dependent kinetic and strain energies of a mode shape or an ODS directly from the structural matrices and complex eigenvectors/displacement vectors is presented. The expressions for energy contributed per cycle by various types of damping and the destabilizing skew-symmetric stiffness that can be obtained in a similar way are also shown. The conditions under which the energies and energy distributions are time-invariant are discussed. An alternative set of energy expressions for isotropic systems with the DOFs reduced by half is also presented.

Rotordynamic Energy Expressions for General Anisotropic Finite Element Systems

It is often desirable to identify the critical components that are active in a particular mode shape or an operational deflected shape (ODS) in a complex rotordynamic system with multiple rotating groups and bearings. The energy distributions can help identify the critical components of a rotor bearing system that may be modified to match the design requirements. Although the energy expressions have been studied by researchers in the past under specific limited conditions, these expressions require computing the displacements and velocities of all degrees of freedom over one full cycle. They do not address the overall time-dependency of the energies and energy distributions, and their effect on the interpretation of a mode shape or an ODS. Moreover, a detailed finite element formulation of these energy expressions including the effects of anisotropy, skew-symmetric stiffness, viscous and structural damping have not been identified by the authors in the open literature. In this article, a detailed account of orbit characteristics and planarity for isotropic and anisotropic systems is presented. The effect of orbit characteristics on the energy expressions is then discussed. An elegant approach to obtaining time-dependent kinetic and strain energies of a mode shape or an ODS directly from the structural matrices and complex eigenvectors/displacement vectors is presented. The expressions for energy contributed per cycle by various types of damping and the destabilizing skew-symmetric stiffness that can be obtained in a similar way are also shown. The conditions under which the energies and energy distributions are time-invariant are discussed. An alternative set of energy expressions for isotropic systems with the degrees of freedom reduced by half is also presented.

The Number continuity service, Part I GSM Satellite phone

Mobile Number Portability is now a widely used service allowing users to keep their number if they change their subscribed operator. It was first deployed in Hong-Kong (1999). « Number Continuity » corresponds to the same service but with the switch to another technology, because the subscribed main terminal does not have coverage. The new terminal may be a PC, a smartphone / WiFi, a “satphone”, a GSM phone if the main one is CDMA, with (almost) the same service transparently. Making calls or SMS with its normal CLI shown, receiving calls, SMS, MMS to his normal GSM number (unlike « Skype »). This article explains the GSM <-> satphone number continuity implementation. The Geostationnary and Low Earth Orbit characteristics are presented as well the consequences of orbit drifts for which the exact computation is given based on the formal integration of Kepler's area law. The handover implementation and cases for the satellite service are explained. The constellation and services of the main satellite operators are compared. The telecom core network implementation of the service is detailed in the cases of a GSM type core network and an IS-41 (CDMA) core network.

Level 1 algorithms for TANSO on GOSAT: processing and on-orbit calibrations

The Thermal And Near infrared Sensor for carbon Observation Fourier-Transform Spectrometer (TANSO-FTS) onboard the Greenhouse gases Observing SATellite (GOSAT) (nicknamed "Ibuki") has been providing global space-borne observations of carbon dioxide (CO2) and methane (CH4) since 2009. In this paper, we first describe the version V150.151 operational Level 1 algorithms that produce radiance spectra from the acquired interferograms. Second, we will describe the on-orbit characteristics and calibration of TANSO-FTS. Overall function and performance such as signal to noise ratio and spectral resolution are within design objectives. Correction methods of small on-orbit degradations and anomalies, which have been found since launch, are described. Lastly, calibration of TANSO Cloud and Aerosol Imager (TANSO-CAI) are summarized.