Broadband wavelength tuning of electrically stretchable chiral photonic gel

Chiral photonic-band structure provides technical benefits in the form of a self-assembled helical structure and further functional wavelength tunability that exploits helical deformation according to pitch changes. The stopband wavelength control of the chiral photonic-band structure can be obtained by individual electrical methods or mechanical stretching deformation approaches. However, research on combined electric control of stretchable chiral photonic-band wavelength control while ensuring optical stability during the tuning process has remained limited till now. In this study, using the hybrid structure of elastomeric mesogenic chiral photonic gels (CPGs) with an electrically controlled dielectric soft actuator, we report the first observation of electrically stretchable CPGs and their electro-mechano-optical behaviors. The reliable wavelength tuning of a CPG to a broadband wavelength of ∼171 nm changed with high optical stability and repeated wavelength transitions of up to 100 times. Accordingly, for the first time, electrical wavelength tuning method of stretchable chiral liquid crystal photonicband structure was investigated.

Strain-Induced Form Transition and Crystallization Behavior of the Transparent Polyamide

A transparent polyamide, poly(4,4′-aminocyclohexyl methylene dodecanedicarboxylamide) (PAPACM12), was studied and characterized by in situ wide-angle X-ray diffraction (WAXD) to establish the relationship between its crystallization behavior, crystalline form transition under external fields, and macroscopic properties. During the heating process, cold crystallization occurred and increased, and there was no form transition below the melting point. During the isothermal process, PAPACM12 exhibited the same crystalline structure as that during the heating process. The crystalline structure of PAPACM12 was attributed to α-form crystal, which is the stable form, according to the WAXD diffraction peaks of the conventional AABB-type polyamides. During stretching deformation, the crystal transition from α-form to γ-form and strain-induced crystallization were observed to contribute to the PAPACM12 with higher breaking strength and elongation. This study firstly determine the crystalline structure of transparent polyamides, and then the controlled strain-induced crystallization and transformation are demonstrated to be effective preparation methods for polyamides with high properties.

Deformation-Induced Crystallization Behavior of Isotactic Polypropylene Sheets Containing a β-Nucleating Agent under Solid-State Stretching

The deformation-induced crystallization of an isotactic polypropylene (iPP) sheet containing a β-nucleating agent was evaluated. The phase transformation of the β-modifications was investigated and the crystal morphology was observed at room temperature after stretching at different temperatures. The results showed that the crystallinity increased after solid-state stretching. When the stretching temperature was below the initial crystallization temperature, stretching deformation promoted the orientation of amorphous molecular chains. When the deformation temperature exceeded the crystallization temperature, part of the β-modifications underwent a phase transformation process and was stretched into a shish-kebab structure. However, once the stretching temperature was close to the melting point, the β-modifications melted and recrystallized, and the shish-kebab structure underwent stress relaxation due to poor thermal stability, transforming into α-modifications. It was revealed that the crystal phase transformation mechanism of the β-modifications was based on the orientation of the molecular chains between the adjacent lamellae. In addition, the shish-kebab cylindrite structure played an important role in modifying the tensile and impact properties of the iPP sheet. The tensile and impact strengths increased by as much as 34% and 126%, respectively.

Folding deformation modeling and simulation of 4D printed bilayer structures considering the thickness ratio

This paper addresses the problem of deformation modeling and simulation of 4D printed polymeric bilayer structures considering the thickness ratio. Through an equivalent transformation, the folding deformation model is transformed into two simpler deformation models, stretching and bending, which greatly reduces the complexity of the modeling problem. The stretching deformation model is developed by Hooke’s law, and based on the final strain of the stretching deformation, which is determined by the thickness ratio, a new hyperelastic energy density function considering the thickness ratio is defined to calculate the energy of the bilayer structure during the bending deformation. According to the new energy density function, the bending deformation model considering the thickness ratio is developed by minimizing the energy of the bilayer structure during the bending deformation. Numerical simulations show encouraging results obtained by the proposed model.

Numerical Studies of Shape Recovery of a Red Blood Cell Using Dissipative Particle Dynamics

A biological cell exhibits viscoelastic behavior mainly because its components (membrane and cytoplasm) are viscoelastic, and this is clearly seen when it is stretched and released. The present work numerically studied the shape recovery of a red blood cell (RBC) based on a viscoelastic model at the meso-scale using Dissipative Particle Dynamics (DPD) method. In this model, the RBC membrane is represented by a triangular network of worm-like chains, while the cytoplasm is replaced by a system of DPD particles. This viscoelastic model is validated by examining the stretching deformation of an RBC and comparing with the existing experimental data. Viscoelastic properties of the RBC are then analyzed by stretching an RBC under a 20 pN stretching force, and allowing it to relax. The time to recover its shape upon removal of the stretching force is measured to be 111 and 92.6[Formula: see text]ms for an RBC with and without cytoplasm, and the corresponding membrane viscosity is [Formula: see text] and [Formula: see text] [Formula: see text], respectively. These values, for an RBC with cytoplasm, are closer to experimental data than those for an RBC without cytoplasm, lending support to the model with cytoplasm. Finally, parametric studies are conducted on the membrane elastic and bending moduli. The results show that the shape recovery time decreases with increasing the membrane elastic and bending moduli.