High Specific Energy Li7La3Zr2O12 Solid Electrolyte Based Thermal Battery

Garnet-type Ta-doped Li7La3Zr2O12 (LLZTO) solid electrolyte has been widely investigated for secondary Li ionic or metal batteries at ambient temperature. Because of the increasing ionic conductivity of LLZTO with temperature, we applied the LLZTO solid electrolyte to thermal battery working at 550℃. The LLZTO presents ultrahigh specific energy as the discharge specific energy and specific power is 605 W h/kg and 2.74 kW/kg at 100 mA/cm2 with a cut-off voltage of 1.8 V, respectively. This is larger than the LiF–LiCl-LiBr electrolyte which is commonly used in thermal battery with a specific energy of 514 W h/kg. The internal resistance of the single cell reaches 0.65 Ω, but the specific energy remains at about 400 W h/kg as the current density increases to 400 mA/cm2. We report the application of LLZTO in thermal battery with high specific energy, large current, and high voltage discharge for the first time, broadening the application range of solid electrolytes.

The study of instabilities role of plasma in the high-voltage discharge formation initiated by optical radiation at high pressures in high-voltage optically triggered switches

The paper presents the experimental results of triggering a high-voltage gas gap by YAG: Nd3+ laser radiation. The gas gap was used as the primary switch of a high-current pulsed e-beam RADAN-type accelerator. As a result, an operating regime when the instability and delay time appeared to be minimal was experimentally found. The developed gas gap and the found operating regimes sustain the switching instability no more than 0.3 ns. The physical mechanisms determining the switch-on delay and the obtained level of instability are discussed.

Nanocomposite Obtained in the Plasma of a Pulsed High Voltage Discharge Using Nickel Electrodes and PTFE

In the plasma of pulsed high-voltage discharge, initiated between nickel electrodes in air, when the fluoroplastic is placed in the discharge gap, powder nanocomposite material has been synthesized. The nanocomposite contains NiF2 nanoparticles less than 5 nm in size, dispersed in a matrix consisting of carbon and fluorocarbon substances. The carbonaceous substance contains nanoscale disordered graphite-like regions. The fluorocarbon component of the composite contains fragments of PTFE molecules and fluorocarbon molecular fragments that differ in structure from PTFE molecule’s structure. After annealing the composite in air at 773 K, the initial nanocomposite is transformed into a nanocomposite containing nanosized PTFE and nanoparticles of NiF2 less than 5 nm in size, scattered in a matrix composed of nanographite and low-layer nanosized graphene, after aneling at 1173 K into a material containing NiO nanoparticles less than 10 nm in size. After annealing of the initial nanocomposite in argon atmosphere at 1073 K, the obtained nanocomposite contains Ni nanoparticles with sizes less than 5 nm and carbon and fluorocarbon components. The magnetic susceptibility of the unannealed nanocomposite is investigated. A transition to the antiferromagnetic phase at 73 K was detected. At T = 4K, exchange bias interaction of the AFM / FM type takes place in the composite. There is divergence of the FC and ZFC curves, which can be explained by the presence of a superparamagnetic phase or a spin glass phase in the sample. The field dependences of the magnetic susceptibility measured at T = 300 K show sharp changes that occur at certain values of the magnetic field. Elucidation of the nature of these changes requires additional research.

Explosive Stamping Goals and Objectives Historical Transformation (to the 70th Anniversary of KhAI Scientific School)

The sequence and development the impulse stamping goals and production objectives are described. A new idea development from a primitive “field” technology to modern integrated technologies that allow obtaining unique quality indicators of manufactured parts is shown. The article covers the description of pulse technologies for sheet stamping by the blasting agents explosion and an underwater high-voltage discharge.

Pulsed Discharge Plasma in High-Pressure Environment for Water Pollutant Degradation and Nanoparticle Synthesis

The application of high-voltage discharge plasma for water pollutant decomposition and the synthesis of nanoparticles under a high-pressure argon gas environment (~4 MPa) was demonstrated. The experiments were carried out in a batch-type system at room temperature with a pulsed DC power supply (15.4 to 18.6 kV) as a discharge plasma source. The results showed that the electrode materials, the pulsed repetition rates, the applied number of pulses, and the applied voltages had a significant effect on the degradation reactions of organic compounds. Furthermore, carbon solid materials from glycine decomposition were generated during the high-voltage discharge plasma treatment under high-pressure conditions, while Raman spectra and the HRTEM images indicated that titanium dioxide with a brookite structure and titanium carbide nanoparticles were also formed under these conditions. It was concluded that this process is applicable in practice and may lead to advanced organic compound decomposition and metal-based nanoparticle synthesis technologies.

The Effect of Gaseous Ozone Generated by Surface Dielectric Barrier Discharge on the Decay and Quality of Stored Onion Bulbs

An effective and eco-friendly technology is needed to prevent postharvest loss of onion bulbs during cold storage. This study investigated the effect of gaseous ozone on the decay and quality of onion bulbs during storage at 2 °C and 70% relative humidity for two months. Gaseous ozone was adjusted to a concentration of 1.27 ± 0.024 ppm in the storage room by generating a high voltage discharge in air. After two months of storage, gaseous ozone significantly reduced the counts of aerobic bacteria (e.g., Rahnella aquatilis) and fungi (e.g., yeast and mold) in the onion bulbs by 4 log (CFU g−1) and 0.92 log (CFU g−1) compared with those of an untreated control, respectively. The microbial reduction by gaseous ozone resulted in a lower rotten rate of the onion bulbs, which was less than 20.0% compared with that of the untreated control. Moreover, the ozone exposure extended the storage life of the onion bulbs by delaying its color change and softening during storage. Our results suggest that gaseous ozone can control the decay of onion bulbs safely during storage.

Study on the Damage Model of Coal Rock Caused by Hydraulic Pressure and Electrical Impulse in Borehole

The purpose of this study is to study the damage and fracturing effects of high-voltage discharge on coal-rock mass under the action of hydrostatic pressure. Based on the traditional damage evolution model and the change of the effective bearing area and stress around the microcrack of coal-rock mass on a microscopic scale, the expression of macroscopic damage variation of coal-rock mass under the action of electrohydraulic coupling was derived, and its damage constitutive relation was established. The high-voltage pulse water shock stress test of coal-rock mass under the conditions of different water pressures and voltages was carried out, and its damage numerical model was established by the ABAQUS/XFEM. The damage variable values of coal-rock mass with different electrohydraulic parameters were compared to characterize the generation and expansion of internal macroscopic cracks. From the results, it is shown that the damage variable based on the effective bearing area and stress around the crack can represent the morphology and expansion change of crack of coal-rock mass with different electrohydraulic parameters clearly and quantitatively. Different hydrostatic pressures and discharge voltages have influence on the damage variables of coal-rock mass, but different influencing degrees cause different damages on coal-rock mass. The damage of coal rock can be characterized by the change of the effective bearing area and stress around microcracks in coal body. So, stress testing and numerical simulation have verified the correctness of the damage model.