GISD30: global 30-m impervious surface dynamic dataset from 1985 to 2020 using time-series Landsat imagery on the Google Earth Engine platform

Accurately mapping impervious surface dynamics has great scientific significance and application value for urban sustainable development research, anthropogenic carbon emission assessment and global ecological environment modeling. In this study, a novel and accurate global 30 m impervious surface dynamic dataset (GISD30) for 1985 to 2020 was produced using the spectral generalization method and time-series Landsat imagery, on the Google Earth Engine cloud-computing platform. Firstly, the global training samples and corresponding reflectance spectra were automatically derived from prior global 30 m land-cover products after employing the multitemporal compositing method and relative radiometric normalization. Then, spatiotemporal adaptive classification models, trained with the migrated reflectance spectra of impervious surfaces from 2020 and pervious surface samples in the same epoch for each 5° × 5° geographical tile, were applied to map the impervious surface in each period. Furthermore, a spatiotemporal consistency correction method was presented to minimize the effects of independent classification errors and improve the spatiotemporal consistency of impervious surface dynamics. Our global 30 m impervious surface dynamic model achieved an overall accuracy of 91.5 % and a kappa coefficient of 0.866 using 18,540 global time-series validation samples. Cross-comparisons with four existing global 30 m impervious surface products further indicated that our GISD30 dynamic product achieved the best performance in capturing the spatial distributions and spatiotemporal dynamics of impervious surfaces in various impervious landscapes. The statistical results indicated that the global impervious surface has doubled in the past 35 years, from 5.116 × 105 km2 in 1985 to 10.871 × 105 km2 in 2020, and Asia saw the largest increase in impervious surface area compared to other continents, with a total increase of 2.946 × 105 km2. Therefore, it was concluded that our global 30 m impervious surface dynamic dataset is an accurate and promising product, and could provide vital support in monitoring regional or global urbanization as well as in related applications. The global 30 m impervious surface dynamic dataset from 1985 to 2020 generated in this paper is free to access at http://doi.org/10.5281/zenodo.5220816 (Liu et al., 2021b).

Retraction ATPase motors are promiscuous among type IVa pilus systems

Bacterial surface appendages called type IVa pili (T4aP) promote diverse activities including DNA uptake, twitching motility, and virulence. These activities rely on the ability of T4aP to dynamically extend and retract from the cell surface. Dynamic extension relies on a motor ATPase commonly called PilB. Most T4aP also rely on specific motor ATPases, commonly called PilT and PilU, to dynamically and forcefully retract. Here, we systematically assess whether motor ATPases from 4 distinct T4aP could functionally complement Vibrio cholerae mutants that lacked their endogenous motors. We found that the retraction ATPases PilT and PilU are highly promiscuous and promote retraction of the V. cholerae competence T4aP despite a high degree of sequence divergence. In contrast, orthologous extension ATPases were not able to mediate extension of the V. cholerae competence T4aP despite a similar degree of sequence divergence. Also, we show that one of the PilT orthologs characterized does not support PilU-dependent retraction and we attributed this loss of activity to the 3' end of the gene, which suggests that the C-terminus of PilT plays an important role in promoting PilU-dependent retraction. Together, our data suggest that retraction ATPases have maintained a high degree of promiscuity for promoting retraction of diverse T4aP, while extension ATPases have evolved to become highly specific for their cognate systems.

Single Entity Behavior of CdSe Quantum Dot Aggregates During Photoelectrochemical Detection

We demonstrate that colloidal quantum dots of CdSe and CdSe/ZnS are detected during the photooxidation of MeOH, under broad spectrum illumination (250 mW/cm2). The stepwise photocurrent vs. time response corresponds to single entities adsorbing to the Pt electrode surface irreversibly. The adsorption/desorption of the QDs and the nature of the single entities is discussed. In suspensions, the QDs behave differently depending on the solvent used to suspend the materials. For MeOH, CdSe is not as stable as CdSe/ZnS under constant illumination. The photocurrent expected for single QDs is discussed. The value of the observed photocurrents, > 1 pA is due to the formation of agglomerates consistent with the collision frequency and suspension stability. The observed frequency of collisions for the stepwise photocurrents is smaller than the diffusion-limited cases expected for single QDs colliding with the electrode surface. Dynamic light scattering and scanning electron microscopy studies support the detection of aggregates. The results indicate that the ZnS layer on the CdSe/ZnS material facilitates the detection of single entities by increasing the stability of the nanomaterial. The rate of hole transfer from the QD aggregates to MeOH outcompetes the dissolution of the CdSe core under certain conditions of electron injection to the Pt electrode and in colloidal suspensions of CdSe/ZnS.

An alternative approach to study irrotational periodic gravity water waves

We are concerned here with an analysis of the nonlinear irrotational gravity water wave problem with a free surface over a water flow bounded below by a flat bed. We employ a new formulation involving an expression (called flow force) which contains pressure terms, thus having the potential to handle intricate surface dynamic boundary conditions. The proposed formulation neither requires the graph assumption of the free surface nor does require the absence of stagnation points. By way of this alternative approach we prove the existence of a local curve of solutions to the water wave problem with fixed flow force and more relaxed assumptions.

Integration as a Process: Applying Iterative Multiple Correspondence Analysis to Surface Dynamic Findings

A defining characteristic of mixed methods research, integration receives considerable attention in the field, yet evidence suggests that the process of integration may be challenging in practice. Crossover analyses, in which methods typically used with one data type are applied to a different data type, can deepen integration. Using an example from the field of education, this article demonstrates the iterative application of multiple correspondence analysis as a crossover analysis through a four-stage integration process. Contributions to the field of mixed methods include (a) the utility and potential of multiple correspondence analysis to surface new dimensions of integrated findings, (b) considerations for rigor in the application of crossover methods, and (c) considerations for making sense of diffractive or dynamic findings.

Research on dynamic prediction model of surface subsidence in mining areas with thick unconsolidated layers

In order to improve the accuracy of the surface dynamic prediction model in mining areas with thick unconsolidated layers and improve Knothe time function, the influence coefficient was firstly changed into the coefficient in exponential form, and the influence coefficient of unconsolidated layer was added. Then, a subsidence basin prediction model for mining under thick unconsolidated layers was established. Next, the model was combined with the improved Knothe function, thus constructing a new mining subsidence prediction model. The new subsidence prediction model was applied in 1414 (1) working face in Huainan mining area. The results showed that the integrated model could better reflect the subsidence process, and the prediction values and the measured values agreed well.

Anisotropic Growth of ZnO Nanoparticles Driven by the Structure of Amine Surfactants: The Surface Dynamic on Nanocrystal Rules

Herein, we elucidate the key role of amine surfactants on the controlled anisotropic growth of ZnO nanoparticles that is achieved under mild conditions by organometallics hydrolysis. The structuring influence of...