Exposure Assessment to Radiofrequency Electromagnetic Fields in Occupational Military Scenarios: A Review

(1) Background: Radiofrequency radiations are used in most devices in current use and, consequently, the assessment of the human exposure to the radiofrequency radiations has become an issue of strong interest. Even if in the military field there is wide use of radiofrequency devices, a clear picture on the exposure assessment to the electromagnetic field of the human beings in the military scenario is still missing. (2) Methods: a review of the scientific literature regarding the assessment of the exposure of the military personnel to the RF specific to the military environment, was performed. (3) Results: the review has been performed grouping the scientific literature by the typology of military devices to which the military personnel can be exposed to. The military devices have been classified in four main classes, according to their intended use: communication devices, localization/surveillance devices, jammers and EM directed-energy weapons. (4) Discussion and Conclusions: The review showed that in the exposure conditions here evaluated, there were only occasional situations of overexposure, whereas in the majority of the conditions the exposure was below the worker exposure limits. Nevertheless, the limited number of studies and the lack of exposure assessment studies for some devices prevent us to draw definitive conclusions and encourage further studies on military exposure assessment.

Mercury Contamination of Process and Pipeline Infrastructure - A Novel, All- Encompassing Solution for the Evaluation and Decontamination of Mercury from Pipelines and Topside Process Equipment to allow Safe Disposal

Mercury present in produced oil and gas will deposit onto the internal process infrastructure via a number of mechanisms including chemisorption and adsorption with the primary mechanism being through reaction with iron sulphide to form mercury sulphide. Due to the volumes of fluids produced and the length of time facilities are in production, even where the produced fluids have historically contained relatively low concentrations of mercury, pipeline scales containing percentage levels of mercury may be present. Thus, aged facilities and infrastructure that have reached the end of their operational life and are selected for either recycling or abandonment, may pose a serious risk to health and the environment if the decommissioning process is not managed correctly. Smelting, hot cutting or other thermal/abrasive surface preparations for example, can lead to significant release of elemental mercury, a worker exposure hazard. Alternatively, if sub-sea pipelines are abandoned in-situ, all mercury present will ultimately be transferred to the local ecosystems. Consequently, the oil and gas industry have the requirement for a complete mercury decontamination solution from initial evaluation, demonstrable cleaning efficacy through to a guarantee for the treatment and disposal of the mercury waste generated in an environmentally-friendly manner. In order to decide upon the most appropriate decontamination solution, an evaluation of the extent of mercury contamination should be undertaken. A novel approach that has recently been successfully implemented involved analysis of pipe sections by multiple analytical techniques, providing the mercury concentration in the scale/steel. From this, the total mass of mercury across the process or pipeline was approximated. Subsequently, the efficacy of the preferred chemical to remove mercury from the internal surfaces of pipework was evaluated by chemical treatment of the pipe sections under laboratory conditions. In-situ decontamination can be performed by a number of applications, including (i) the use of chemical pig trains in pipelines, (ii) closed loop circulation of chemical around topside process equipment and (iii) high pressure spraying of large surface areas such as storage tanks, FSO / FPSO vessels. The mercury waste generated is treated, on site or off site, to minimise the volume and disposed of in accordance with international regulations. An all-encompassing mercury decontamination solution is described. Trials involving the chemical treatment of steel sections have demonstrated that more than 97% of the mercury deposited can be removed from the internal surfaces of pipelines and safely disposed of, significantly reducing the risk of (i) mercury release to the environment and (ii) worker exposure to mercury during smelting activities.

Monitoring and Optimisation of Ag Nanoparticle Spray-Coating on Textiles

An automatic lab-scaled spray-coating machine was used to deposit Ag nanoparticles (AgNPs) on textile to create antibacterial fabric. The spray process was monitored for the dual purpose of (1) optimizing the process by maximizing silver deposition and minimizing fluid waste, thereby reducing suspension consumption and (2) assessing AgNPs release. Monitoring measurements were carried out at two locations: inside and outside the spray chamber (far field). We calculated the deposition efficiency (E), finding it to be enhanced by increasing the spray pressure from 1 to 1.5 bar, but to be lowered when the number of operating sprays was increased, demonstrating the multiple spray system to be less efficient than a single spray. Far-field AgNPs emission showed a particle concentration increase of less than 10% as compared to the background level. This finding suggests that under our experimental conditions, our spray-coating process is not a critical source of worker exposure.

Honey bee queen health is unaffected by contact exposure to pesticides commonly found in beeswax

Honey bee queen health is crucial for colony health and productivity, and pesticides have been previously associated with queen loss and premature supersedure. Prior research has investigated the effects of indirect pesticide exposure on queens via workers, as well as direct effects on queens during development. However, as adults, queens are in constant contact with wax as they walk on comb and lay eggs; therefore, direct pesticide contact with adult queens is a relevant but seldom investigated exposure route. Here, we conducted laboratory and field experiments to investigate the impacts of topical pesticide exposure on adult queens. We tested six pesticides commonly found in wax: coumaphos, tau-fluvalinate, atrazine, 2,4-DMPF, chlorpyriphos, chlorothalonil, and a cocktail of all six, each administered at 1, 4, 8, 16, and 32 times the concentrations typically found in wax. We found no effect of any treatment on queen mass, sperm viability, or fat body protein expression. In a field trial testing queen topical exposure of a pesticide cocktail, we found no impact on egg-laying pattern, queen mass, emergence mass of daughter workers, and no proteins in the spermathecal fluid were differentially expressed. These experiments consistently show that pesticides commonly found in wax have no direct impact on queen performance, reproduction, or quality metrics at the doses tested. We suggest that previously reported associations between high levels of pesticide residues in wax and queen failure are most likely driven by indirect effects of worker exposure (either through wax or other hive products) on queen care or queen perception.

Emissions from Metallic Powder and High Energy-Based Process – Thermal Spraying, Powder Atomization, and Additive Manufacturing – Knowledge Refresh

This paper addresses a need for information on nanoparticle emissions and related issues such as worker exposure, filtration efficiency, and dustiness. A survey has been conducted on the working conditions and safety measures used in thermal spray companies and the results compared to scientific literature and previous surveys. Responses to questions on matters of health and safety reveal a lack of information and awareness of the risks posed by the emissions of ultrafine particles generated by thermal spraying processes.

The ECETOC-Targeted Risk Assessment Tool for Worker Exposure Estimation in REACH Registration Dossiers of Chemical Substances—Current Developments

(1) Background: The ECETOC Targeted Risk Assessment (TRA) tool is widely used for estimation of worker exposure levels in the development of dossiers for REACH registration of manufactured or imported chemical substances in Europe. A number of studies have been published since 2010 in which the exposure estimates of the tool are compared with workplace exposure measurement results and in some instances an underestimation of exposure was reported. The quality and results of these studies are being reviewed by ECETOC. (2) Methods: Original exposure measurement data from published comparison studies for which six or more data points were available for each workplace scenario and a TRA estimate had been developed to create a curated database to examine under what conditions and for which applications the tool is valid or may need adaptation. (3) Results: The published studies have been reviewed for completeness and clarity and TRA estimates have been constructed based on the available information, following a set of rules. The full review findings are expected to be available in the course of 2021. (4) Conclusions: The ECETOC TRA tool developers periodically review the validity and limitations of their tool, in line with international recommendations.