Research of qualitative indicators of butter cookies using protein-mineral supplements

The results of researches of influence of protein-mineral supplements on quality indicators of butter cookies are presented. It is described, that the supplements are used as a multifunctional ingredient, which on the one hand enriches the finished product with digestible calcium compounds, on the other - performs a number of technological tasks and improves the consumer characteristics of butter cookies. The purpose of the study was to determine the effect of protein-mineral supplements on a number of physicochemical, consumer characteristics and safety indicators of butter cookies. The study of the following physicochemical parameters of the quality of butter cookies was conducted: mass fraction of moisture, wettability, alkalinity, calcium content, including total and protein-bound. It is established, that with the content of supplements up to 5.0% of the flour weight, all the above indicators meet the established requirements. With the content of suppements at the level of 6.0… 7.0%, there are limit values of such an indicator as wettability, which is undesirable to ensure the appropriate porous structure of the product. Based on the obtained data, it can be stated, that 5.0% of the use of supplements is the limit rational content in the composition of butter cookies. The organoleptic analysis proved the high characteristics of the developed products in comparison with traditional ones. In products with supplements, there was an improvement in the structure of the product in the cut and its color. This is ensured by the stabilization of the emulsion by the supplement during the manufacture of products and by peculiarities of its chemical composition. Studies of safety indicators allowed to establish less intensive dynamics of accumulation of primary oxidation products (peroxides) in samples of flour and butter products with supplements in comparison with control. The best microbiological stability of products with supplements is also proved. Due to the bacteriostatic effect of the supplements, less intensive accumulation of microflora during storage was achieved. On the basis of the conducted researches the expediency of using up to 5.0% of protein-mineral supplements in the composition of flour and butter products for enrichment of finished products with digestible calcium compounds, improvement of organoleptic characteristics and safety indicators have been established.

The Effects of Dietary Inclusion of Bilberry and Walnut Leaves in Laying Hens’ Diets on the Antioxidant Properties of Eggs

The purpose of this study was to examine the effects of dietary inclusion of walnut and bilberry leaves (WL and BL), as sources of natural antioxidants in poultry diets, on the enrichment of antioxidant nutrients in the egg yolk and on the susceptibility of the yolk to lipid peroxidation during storage. The experiment was conducted on 32-week-old TETRA SL LL laying hens, which were assigned to three dietary treatments with 30 birds each. Each treatment was replicated 10 times with three chicks per replicate pen. Experimental dietary treatments differed from control diet (C) by addition of 0.5% BL supplement or 1% WL supplement. The phytoadditives were not significant contributors to the productive parameters. The addition of BL and WL in laying hens’ diets significantly increased the total polyphenol content, and the zinc, lutein and zeaxanthin concentrations in the egg yolks. In regards to the oxidative stability parameters, a significant decrease in the concentrations of primary oxidation products formed in the egg yolk of experimental groups was seen, proving an efficient inhibition effect of the phytoadditives on peroxyl radical formation. A significant correlation was observed between primary oxidation products and total polyphenol content of the egg yolks, where zinc, lutein and zeaxanthin are the bioactive compounds that inhibit the formation of secondary oxidation products.

Poly (α-Dodecyl γ-Glutamate) (PAAG-12) and Polylactic Acid Films Charged with α-Tocopherol and Their Antioxidant Capacity in Food Models

Poly (α-dodecyl γ-glutamate) (PAAG-12) was successfully synthesized from poly(γ-glutamic acid) (PGGA) according to Nuclear Magnetic Resonance (NMR) analyses. PAAG-12 films were prepared and enriched with 5% α-tocopherol, with the aim of using them as novel antioxidant active packaging for food applications. Thermogravimetric Analysis (TGA) characterization determined that α-tocopherol improved thermal stability of films, which is beneficial for industrial processing. Polylactic Acid (PLA) films prepared with the same amount of α-tocopherol were used to set a comparative frame and both types of films were applied to two different food models to assess their protective action against oxidation. Water, 50% ethanol (EtOH) and 95% EtOH were used as food simulants and HPLC analyses were performed to determine diffusion and partition coefficients in PLA and the novel polymer, the latter exhibiting slower release rates. Primary oxidation was measured with peroxide value, which revealed that PAAG-12 films with α-tocopherol protected oil-in-water (O/W) emulsions up to 29 days, complying with the Codex Alimentarius.

Spectroscopic identification of the phenyltelluryl radical and its reactivity toward molecular oxygen

Phenyltelluryl radical and its primary oxidation products phenyltelluro peroxy and phenyl telluroyl radicals were generated and characterized spectroscopically in solid noble gas matrices for the first time.

The phenylselenyl radical and its reaction with molecular oxygen

The phenylselenyl radical and its primary oxidation products phenylselenyl peroxy and phenylselenoyl radicals were generated and subsequently isolated in solid noble gas matrices for the first time.