Phase Separation of Ice Crystals in Starch-Based Systems During Freezing and Effects on Moisture Content and Starch Glass Transition

Author(s):  
T. Tran ◽  
K. Piyachomkwan ◽  
K. Sriroth
RSC Advances ◽  
2016 ◽  
Vol 6 (35) ◽  
pp. 29326-29333 ◽  
Author(s):  
Abdul G. Al Lafi ◽  
James N. Hay

Thermal history and purification effects on the structural properties of PVK were investigated. Liquid–liquid phase separation is suggested to occur by separation of isotactic rich segments from a matrix which is predominantly atactic.


Author(s):  
Kobra Tajaddodi Talab ◽  
Mohd. Nordin Ibrahim ◽  
Sergey Spotar ◽  
Rosnita A. Talib ◽  
Kharidah Muhammad

Abstract Glass transition temperatures (Tg) of MR219 rice variety were measured by differential scanning calorimeter (DSC). State diagram was developed and used to evaluate drying process in this study. Glass transition temperatures range of 9.65- 61.79°C were observed for gains with moisture content of 26.8 – 7.4% (w.b.). For mechanical properties and milling test, statistical analysis was performed by using a two factor experiment in completely randomized design (CRD). Two selected factors were drying temperatures at 5 levels (40, 45, 50, 55, and 60°C) and final moisture content (FMC) at 4 levels (10-10.5, 11-11.5, 12-12.5 and 13-13.5%). Three–point bending test was applied to measure the mechanical properties of rice kernel. Generally, bending strength, apparent modulus of elasticity and fracture energy of brown rice kernel increased with decreasing the grain moisture content. Maximum bending strength was 35.69 and 33.64 MPa for 55, and 60°C, respectively. All samples that were dried at 55 and 60°C experienced to go through the glass transition line after reaching their temperature to the room temperature at the end of drying process. The effect of drying temperature, paddy FMC and their interactions on whole kernel percentage (WKP) and mechanical properties were significant (α = 0.05). An inverse relationship was observed between WKP and the percentage of strong kernels for all treatments.


2011 ◽  
Vol 83 (2) ◽  
pp. 934-939 ◽  
Author(s):  
Kiyoshi Kawai ◽  
Ken Fukami ◽  
Pariya Thanatuksorn ◽  
Chotika Viriyarattanasak ◽  
Kazuhito Kajiwara

Author(s):  
Neda Maftoonazad ◽  
Hosahalli S. Ramaswamy ◽  
Michele Marcotte

The moisture sorption behavior of pectin films formulated with different sorbitol content was evaluated and films with different equilibrium moisture contents were obtained. Different models were used to describe the moisture sorption isotherms (MSI) of pectin films, sorbitol and pectin powder. Based on changes observed in MSI, sorbitol was found to strongly interact with pectin polymers. Incorporation of sorbitol in pectin films resulted in lower equilibrium moisture contents at low to intermediate water activities (aw), but much higher moisture contents at aw > 0.53. Estimates of monolayer moisture values (1.53 – 3.81 g H2O kg-1 solids) were obtained by the application of Guggenheim-Anderson-DeBoer (GAB) model. A differential mechanical analyzer (DMA) was used for mechanical properties of formulated films while a differential scanning calorimeter (DSC) was used for thermal properties and glass transition temperature (Tg). With both DMA and DSC tests, the strong plasticizing action of water and sorbitol was evident. Tg vs. moisture content data were successfully fitted to the Fox empirical model. Multi-frequency DMA measurements provided estimates for the apparent activation energy (Ea) of the second glass transition in the range of 131-184 kJ/mol; the values for Ea decreased with increasing sorbitol concentration. Water vapor permeability (WVP) and mechanical properties of the films were also analyzed under varying sorbitol and moisture contents. Increasing moisture or addition of sorbitol to pectin films increased the elongation at break, but decreased the tensile strength, modulus of elasticity and Tg, and increased WVP of the films.


2006 ◽  
Vol 12 (3) ◽  
pp. 181-187 ◽  
Author(s):  
V. R. Nicoletti Telis ◽  
P. J. do Amaral Sobral ◽  
J. Telis-Romero

Differential scanning calorimetry (DSC) was used to determine phase transitions of freeze-dried plums. Samples at low and intermediate moisture contents, were conditioned by adsorption at various water activities (0.11≤aw≤0.90) at 25°C, whereas in the high moisture content region (aw>0.90) samples were obtained by direct water addition, with the resulting sorption isotherm being well described by the Guggenheim-Anderson-deBoer (GAB) model. Freeze-dried samples of separated plum skin and pulp were also analysed. At aw≤0.75, two glass transitions were visible, with the glass transition temperature (Tg) decreasing with increasing aw due to the water plasticising effect. The first Tg was attributed to the matrix formed by sugars and water. The second one, less visible and less plasticised by water, was probably due to macromolecules of the fruit pulp. The Gordon-Taylor model represented satisfactorily the matrix glass transition curve for aw≤0.90. In the higher moisture content range Tg remained practically constant around Tg′ (−57.5°C). Analysis of the glass transition curve and the sorption isotherm indicated that stability at a temperature of 25°C, would be attained by freeze dried plum at a water activity of 0.04, corresponding to a moisture content of 12.9% (dry basis).


2009 ◽  
Vol 58 (8) ◽  
pp. 5604
Author(s):  
Li Mei-Li ◽  
Fu Xing-Ye ◽  
Sun Hong-Ning ◽  
Zhao Hong-An ◽  
Li Cong ◽  
...  

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