Comparing centralized and point‐of‐use treatments of per‐ and polyfluoroalkyl substances

2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Taler S. Bixler ◽  
Cuihong Song ◽  
Weiwei Mo
2019 ◽  
Vol 1 (2) ◽  
pp. e1131 ◽  
Author(s):  
Craig Patterson ◽  
Jonathan Burkhardt ◽  
Donald Schupp ◽  
E. Radha Krishnan ◽  
Stephen Dyment ◽  
...  

2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Riley Mulhern ◽  
Nichole Bynum ◽  
Chamindu Liyanapatirana ◽  
Noelle J. DeStefano ◽  
Detlef R. U. Knappe ◽  
...  

2005 ◽  
Vol 84 (6) ◽  
pp. 48-48
Author(s):  
P. Tell
Keyword(s):  

TAPPI Journal ◽  
2018 ◽  
Vol 17 (11) ◽  
pp. 601-607
Author(s):  
Alan Rudie ◽  
Peter Hart

The use of 50% concentration and 10% concentration hydrogen peroxide were evaluated for chemical and mechanical pulp bleach plants at storage and at point of use. Several dangerous occurrences have been documented when the supply of 50% peroxide going into the pulping process was not stopped during a process failure. Startup conditions and leaking block valves during maintenance outages have also contributed to explosions. Although hazardous events have occurred, 50% peroxide can be stored safely with proper precautions and engineering controls. For point of use in a chemical bleach plant, it is recommended to dilute the peroxide to 10% prior to application, because risk does not outweigh the benefit. For point of use in a mechanical bleach plant, it is recommended to use 50% peroxide going into a bleach liquor mixing system that includes the other chemicals used to maintain the brightening reaction rate. When 50% peroxide is used, it is critical that proper engineering controls are used to mitigate any risks.


2020 ◽  
Author(s):  
Azhagiya Singam Ettayapuram Ramaprasad ◽  
Phum Tachachartvanich ◽  
Denis Fourches ◽  
Anatoly Soshilov ◽  
Jennifer C.Y. Hsieh ◽  
...  

Perfluoroalkyl and Polyfluoroalkyl Substances (PFASs) pose a substantial threat as endocrine disruptors, and thus early identification of those that may interact with steroid hormone receptors, such as the androgen receptor (AR), is critical. In this study we screened 5,206 PFASs from the CompTox database against the different binding sites on the AR using both molecular docking and machine learning techniques. We developed support vector machine models trained on Tox21 data to classify the active and inactive PFASs for AR using different chemical fingerprints as features. The maximum accuracy was 95.01% and Matthew’s correlation coefficient (MCC) was 0.76 respectively, based on MACCS fingerprints (MACCSFP). The combination of docking-based screening and machine learning models identified 29 PFASs that have strong potential for activity against the AR and should be considered priority chemicals for biological toxicity testing.


2018 ◽  
Author(s):  
Yoonjung Jang ◽  
Moonjeong Jang ◽  
Hyoeun Kim ◽  
Sang Jin Lee ◽  
Eunyeong Jin ◽  
...  

2002 ◽  
Vol 2 (5-6) ◽  
pp. 209-216
Author(s):  
R. Sublet ◽  
A. Boireau ◽  
V.X. Yang ◽  
M.-O. Simonnot ◽  
C. Autugelle

Two lead removal water filters were developed to lower lead levels in drinking water below 10 μg.L-1 in order to meet the new regulation given by the European Directive 98-83, applicable in December 2013. An appropriate adsorbent was selected through a stringent research program among a wide range of media, and is composed of a synthetic zeolite and an activated carbon. Two prototypes were developed: the first is a faucet-mounted filter which contains a fixed bed of the adsorbent and a hollow fiber bundle, while the second is an under-sink cartridge made of a porous extruded block of carbon and adsorbent. Both are able to treat at least 1,000 litres of any water containing on average 100 to 150 μg Pb.L-1, by lowering the lead concentration below 10 μg.L-1. Once their safety considerations were addressed by an independent laboratory according to the French Ministry of Health recommendations, 20 prototypes were installed at consumers' taps in northeastern France. Their performance in terms of lead removal, HPC control and bad taste and odor reduction was followed for 6 months. This field testing program resulted in the validation of both prototypes which meet the new French Ministry of Health recommendations and assures that the filtered water is fully ED 98-83 compliant. Their commercialization will be launched first in France in middle 2002.


1997 ◽  
Vol 35 (7) ◽  
pp. 243-250 ◽  
Author(s):  
Shigekazu Nakano ◽  
Tomoko Fukuhara ◽  
Masami Hiasa

It has been widely recognized that trihalomethanes (THMs) in drinking water pose a risk to human health. THMs can be removed to a certain extent by the conventional point-of-use (POU) unit which is composed of activated carbon (AC) and microfilter. But it's life on THMs is relatively shorter than on residual chlorine or musty odor. To extent the life of AC adsorber, pressure and thermal swing adsorption (PTSA) was applied by preferential regeneration of chloroform. PTSA was effective to remove THMs, especially chloroform. Adsorption isotherms of chloroform at 25 and 70°C showed a remarkable difference so that thermal swing was considered effective. Chloroform was also desorbed by reducing pressure. By vacuum heating at 70°C, chloroform was almost desorbed from AC and reversible adsorption was considered possible. A prototype of POU unit with PTSA was proposed. Regeneration mode would consist of dewatering, vacuum heating and cooling (backwashing). The unit was maintained in bacteriostatic condition and could be used for a long time without changing an AC cartridge.


2020 ◽  
Vol 1 (4) ◽  
Author(s):  
Peizeng Yang ◽  
Yaye Wang ◽  
Junhe Lu ◽  
Viktor Tishchenko ◽  
Qingguo Huang ◽  
...  

This study examined the degradation of perfluorooctanesulfonate (PFOS) in electrochemical oxidation (EO) processes in the presence of trichloroethylene (TCE). The EO experiment was performed in a gas-tight reactor using Magnéli phase titanium suboxide (Ti4O7) as the anode. The experimental data demonstrated that 75% of PFOS (2 μM) was degraded at 10 mA/cm2 current density in 30 min without TCE present in the solution, while the presence of 76 μM TCE apparently inhibited the degradation of PFOS, reducing its removal down to 53%. Defluorination ratio suggested that PFOS was significantly mineralized upon EO treatment, and it appeared to be not influenced by the presence of TCE. The respective pseudo-first order rate constants (kobs) of PFOS removal were 0.0471 and 0.0254 min-1 in the absence and presence of TCE. The degradation rates of both PFOS and TCE increased with current density rising from 2.5 to 20 mA/cm2. In the presence of TCE, chloride, chlorate, and perchlorate were formed that accounted for 79.7 %, 5.53%, and 1.51% of the total chlorine at 60 min. This work illustrates the promise of the Magnéli phase Ti4O7 electrode based electrochemical oxidation technology for degrading per- and polyfluoroalkyl substances (PFASs) and co-contaminants in groundwaters.


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