ChemInform Abstract: HIGH TEMPERATURE THERMAL EXPANSION STUDIES OF PURE URANIUM DIOXIDE, GADOLINIUM OXIDE AND URANIUM DIOXIDE-1.5 W O GADOLINIUM OXIDE SOLID SOLUTION

1978 ◽  
Vol 9 (21) ◽  
Author(s):  
A. C. MOMIN ◽  
M. D. MATHEWS
Keyword(s):  
Solid Solution ◽  
Thermal Expansion ◽  
High Temperature ◽  
Uranium Dioxide ◽  
Gadolinium Oxide ◽  
Oxide Solid Solution

scholarly journals Coefficients of Thermal Expansion of Al- and Y-Substituted NaSICON Solid Solution Na3+2xAlxYxZr2−2xSi2PO12

Batteries ◽  
2018 ◽  
Vol 4 (3) ◽  
pp. 33 ◽  
Author(s):  
Sahir Naqash ◽  
Marie-Theres Gerhards ◽  
Frank Tietz ◽  
Olivier Guillon
Keyword(s):  
Solid Solution ◽  
Thermal Expansion ◽  
High Temperature ◽  
Sodium Content ◽  
Phase Changes ◽  
Central Metal ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sodium Batteries ◽  
The Difference

Because of an increasing interest in NaSICON materials as electrolyte materials in all-solid state sodium batteries, their thermal expansion was investigated in this study. The thermal expansion coefficient (CTE) of the Al and Y-substituted NaSICON compositions Na3+2xAlxYxZr2−2xSi2PO12 with 0 ≤ x ≤ 0.3 was obtained by dilatometry and compared to the CTE derived from the lattice parameters using high-temperature X-ray diffraction. The difference in CTE obtained from techniques, the influence of sodium content and central metal cation on CTE, as well as other observations such as phase changes are described and rationalized.

Thermal Expansion and Excess Properties of Åkermanite-Gehlenite Synthetic Solid Solution Series

2004 ◽  
Vol 443-444 ◽  
pp. 401-406 ◽  
Author(s):  
Marco Proverbio ◽  
Monica Dapiaggi ◽  
Gilberto Artioli
Keyword(s):  
Solid Solution ◽  
Thermal Expansion ◽  
High Temperature ◽  
Molar Volume ◽  
Excess Molar Volume ◽  
Room Temperature ◽  
Structural Features ◽  
Excess Properties ◽  
Heating And Cooling ◽  
First Time

Thermal expansion of some members of the synthetic solid solution åkermanite-gehlenite was measured (in the range 25-1200°C) for the very first time, with the aim of clarifying the behaviour of this solid solution both with respect to composition and temperature. The results confirmed the non-ideal behaviour at room temperature (negative excess molar volume), and showed a different non-ideal response at high temperature. In fact, excess molar volume is different during the heating and cooling stages: for Xak<0.5 it becomes, from almost ideal, strongly positive at high temperature, while for Xak>0.5 it is always negative. It can then be inferred that (i) lattice dimensions are very sensitive to cation diffusion activated by temperature, (ii) intra-crystalline partition mechanisms, and their effects on the structural features, vary as a function of composition in the solid solution studied.

High-Temperature Instability of A Cr2Nb-Nb(Cr) Microlaminate Composite

1996 ◽  
Vol 54 ◽  
pp. 374-375
Author(s):  
M. Larsen ◽  
R.G. Rowe ◽  
D.W. Skelly
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
High Temperature ◽  
Elevated Temperatures ◽  
Aircraft Engine ◽  
Lattice Parameter ◽  
Microstructural Stability ◽  
Elevated Temperature Strength ◽  
Cross Sectional ◽  
Bcc Structure

Microlaminate composites consisting of alternating layers of a high temperature intermetallic compound for elevated temperature strength and a ductile refractory metal for toughening may have uses in aircraft engine turbines. Microstructural stability at elevated temperatures is a crucial requirement for these composites. A microlaminate composite consisting of alternating layers of Cr2Nb and Nb(Cr) was produced by vapor phase deposition. The stability of the layers at elevated temperatures was investigated by cross-sectional TEM.The as-deposited composite consists of layers of a Nb(Cr) solid solution with a composition in atomic percent of 91% Nb and 9% Cr. It has a bcc structure with highly elongated grains. Alternating with this Nb(Cr) layer is the Cr2Nb layer. However, this layer has deposited as a fine grain Cr(Nb) solid solution with a metastable bcc structure and a lattice parameter about half way between that of pure Nb and pure Cr. The atomic composition of this layer is 60% Cr and 40% Nb. The interface between the layers in the as-deposited condition appears very flat (figure 1). After a two hour, 1200 °C heat treatment, the metastable Cr(Nb) layer transforms to the Cr2Nb phase with the C15 cubic structure. Grain coarsening occurs in the Nb(Cr) layer and the interface between the layers roughen. The roughening of the interface is a prelude to an instability of the interface at higher heat treatment temperatures with perturbations of the Cr2Nb grains penetrating into the Nb(Cr) layer.

ALTEMP HX

Alloy Digest ◽  
1993 ◽  
Vol 42 (10) ◽  
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Base Alloy ◽  
Heat Treating ◽  
Nickel Base Alloy ◽  
Temperature Performance ◽  
Nickel Base

Abstract ALTEMP HX is an austenitic nickel-base alloy designed for outstanding oxidation and strength at high temperatures. The alloy is solid-solution strengthened. Applications include uses in the aerospace, heat treatment and petrochemical markets. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness and creep. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, and joining. Filing Code: Ni-442. Producer or source: Allegheny Ludlum Corporation.

NILO ALLOY 36

Alloy Digest ◽  
1987 ◽  
Vol 36 (8) ◽  
Keyword(s):  
Thermal Expansion ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Surface Treatment ◽  
Constant Coefficient ◽  
Coefficient Of Thermal Expansion ◽  
Heat Treating ◽  
Temperature Performance ◽  
Iron Nickel

Abstract NILO alloy 36 is a binary iron-nickel alloy having a very low and essentially constant coefficient of thermal expansion at atmospheric temperatures. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Fe-79. Producer or source: Inco Alloys International Inc..

UNISPAN LR35

Alloy Digest ◽  
1971 ◽  
Vol 20 (1) ◽  
Keyword(s):  
Thermal Expansion ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Surface Treatment ◽  
Tensile Properties ◽  
Coefficient Of Thermal Expansion ◽  
Heat Treating ◽  
Temperature Performance ◽  
Operational Level

Abstract UNISPAN LR35 offers the lowest coefficient of thermal expansion of any alloy now available. It is a low residual modification of UNISPAN 36 for fully achieving the demanding operational level of precision equipment. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and surface treatment. Filing Code: Fe-46. Producer or source: Cyclops Corporation.

INCO ALLOY 330

Alloy Digest ◽  
1992 ◽  
Vol 41 (5) ◽  
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Heat Treating ◽  
High Temperature Alloy ◽  
Nickel Iron ◽  
Temperature Performance ◽  
Inco Alloy ◽  
Iron Chromium

Abstract INCO ALLOY 330 is a nickel/iron/chromium austenitic alloy, not hardenable by heat treatment. It is a solid solution strengthened high-temperature alloy. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-403. Producer or source: Inco Alloys International Inc..

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