ChemInform Abstract: Reaction of the NO3Radical with CO: Determination of an Upper Limit for the Rate Constant Using FTIR Spectroscopy.

1986 ◽  
Vol 17 (44) ◽  
Author(s):  
J. HJORTH ◽  
G. OTTOBRINI ◽  
G. RESTELLI
Keyword(s):  
Ftir Spectroscopy ◽  
Rate Constant ◽  
Upper Limit

Quantitative Radioisotope Measurement of Duodenogastric Reflux in Patients with Ulcer or Gastrectomized for Ulcer

1985 ◽  
Vol 24 (03) ◽  
pp. 107-110
Author(s):  
M. Pääkkönen ◽  
S. Aukee ◽  
K. Korhonen ◽  
A. Pääkkönen ◽  
E. Länsimies ◽  
...  
Keyword(s):  
Gamma Camera ◽  
Background Activity ◽  
Bile Reflux ◽  
Duodenogastric Reflux ◽  
Upper Limit ◽  
Visual Evidence ◽  
Biochemical Measurement

SummaryIn this work the duodenogastric reflux was quantified as the amount of radioactivity entering the stomach after an i.v. administration of 99mmTc-HIDA in ulcer patients and in patients who had undergone BI gastrectomy. The results were compared with visual evidence of gastric activity in the gamma camera images and biochemical determination of gastric bile reflux. The method is useful in quantifying the reflux if the activity is above the background activity. It allows the determination of an upper limit for the reflux when the reflux is evident visually. Only two or three images are needed for the quantitation. No correlation was found between biochemical measurement of fasting bile reflux in the stomach and radioisotopic quantification.

Determination of rate constants of redox reactions of second order from current-less potential-time curves by a simplified graphical-numerical method

1983 ◽  
Vol 48 (5) ◽  
pp. 1358-1367 ◽  
Author(s):  
Antonín Tockstein ◽  
František Skopal
Keyword(s):  
Numerical Method ◽  
Explicit Form ◽  
Rate Constant ◽  
Optimization Algorithm ◽  
Rate Constants ◽  
Redox Reactions ◽  
Second Order ◽  
Wide Region ◽  
Recurrent Formula

A method for constructing curves is proposed that are linear in a wide region and from whose slopes it is possible to determine the rate constant, if a parameter, θ, is calculated numerically from a rapidly converging recurrent formula or from its explicit form. The values of rate constants and parameter θ thus simply found are compared with those found by an optimization algorithm on a computer; the deviations do not exceed ±10%.

Regeneration Mechanism Studied by Potential-Time Response to Sinusoidal Current-Time Function

1997 ◽  
Vol 62 (10) ◽  
pp. 1511-1526
Author(s):  
María-Luisa Alcaraz ◽  
Ángela Molina
Keyword(s):  
Kinetic Parameters ◽  
Rate Constant ◽  
Theoretical Study ◽  
Time Function ◽  
Time Response ◽  
Current Time ◽  
Regeneration Mechanism ◽  
Sinusoidal Current ◽  
Regeneration Processes

A theoretical study of the potential-time response to sinusoidal current applied to static and dynamic electrodes for regeneration processes is presented. Methods for determination of the regeneration fraction, rate constant of the chemical reaction and heterogeneous kinetic parameters are proposed.

scholarly journals X-Ray Determination of the Black-Hole Mass in Cygnus X-1

1998 ◽  
Vol 188 ◽  
pp. 388-389
Author(s):  
A. Kubota ◽  
K. Makishima ◽  
T. Dotani ◽  
H. Inoue ◽  
K. Mitsuda ◽  
...  
Keyword(s):  
Black Hole ◽  
Compact Object ◽  
Optical Observations ◽  
Black Hole Mass ◽  
X Ray ◽  
Upper Limit ◽  
Supergiant Star ◽  
X Ray Binaries ◽  
Two Bodies

About 10 X-ray binaries in our Galaxy and LMC/SMC are considered to contain black hole candidates (BHCs). Among these objects, Cyg X-1 was identified as the first BHC, and it has led BHCs for more than 25 years(Oda 1977, Liang and Nolan 1984). It is a binary system composed of normal blue supergiant star and the X-ray emitting compact object. The orbital kinematics derived from optical observations indicates that the compact object is heavier than ~ 4.8 M⊙ (Herrero 1995), which well exceeds the upper limit mass for a neutron star(Kalogora 1996), where we assume the system consists of only two bodies. This has been the basis for BHC of Cyg X-1.

A novel approach for the discrimination of culture medium from Vascular Endothelial Growth Factor (VEGF) overexpressing colorectal cancer cells

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Sinem Tunçer ◽  
Rafig Gurbanov
Keyword(s):  
Colorectal Cancer ◽  
Vascular Endothelial Growth Factor ◽  
Growth Factor ◽  
Ftir Spectroscopy ◽  
Cancer Cells ◽  
Lower Amount ◽  
Vascular Endothelial ◽  
Colorectal Cancer Cells ◽  
Endothelial Growth Factor

AbstractObjectivesThe expression level of Vascular Endothelial Growth Factor (VEGF) is assumed as a prognostic marker for several tumor types, including colorectal cancer. Therefore, the determination of pre- and post-therapy levels of VEGF appears to have great value in the assessment of tumor prognosis. Enzyme-Linked Immunosorbent Assay (ELISA) is commonly used for the determination of serum or plasma VEGF levels, but the method is costly and time-consuming. In this study, we aimed to describe a rapid and cost-effective analysis method to discriminate VEGF overexpressing colorectal cancer-derived conditioned medium (CM).MethodsAttenuated Total Reflection (ATR)-Fourier Transform Infrared (FTIR) spectroscopy, combined with Principal Component Analysis (PCA) and Linear Discriminant Analysis (LDA), was used to differentiate VEGF overexpressing colorectal cancer cell line CM from CM obtained from the corresponding control cells which express and secrete relatively lower amount of VEGF.ResultsSamples belong to VEGF overexpressing colorectal cancer cells were clearly distinguished from the control group with very high PC scores as PC1 + PC2 = 96%. Besides, a 100% accurate distinction between these two groups was achieved by the LDA analysis.ConclusionsATR-FTIR spectroscopy combined with pattern recognition techniques was able to discriminate CM of VEGF overexpressing colorectal cancer cells with high efficiency and accuracy.

scholarly journals Constraints on neutrino non-standard interactions from LHC data with large missing transverse momentum

2021 ◽  
Vol 2021 (2) ◽  
Author(s):  
DianYu Liu ◽  
ChuanLe Sun ◽  
Jun Gao
Keyword(s):  
Transverse Momentum ◽  
Neutral Current ◽  
Data Sets ◽  
Leading Order ◽  
Missing Transverse Momentum ◽  
Upper Limit ◽  
Theoretical Predictions ◽  
Parton Showering ◽  
Single Jet

Abstract The possible non-standard interactions (NSIs) of neutrinos with matter plays important role in the global determination of neutrino properties. In our study we select various data sets from LHC measurements at 13 TeV with integrated luminosities of 35 ∼ 139 fb−1, including production of a single jet, photon, W/Z boson, or charged lepton accompanied with large missing transverse momentum. We derive constraints on neutral-current NSIs with quarks imposed by different data sets in a framework of either effective operators or simplified Z′ models. We use theoretical predictions of productions induced by NSIs at next-to-leading order in QCD matched with parton showering which stabilize the theory predictions and result in more robust constraints. In a simplified Z′ model we obtain a 95% CLs upper limit on the conventional NSI strength ϵ of 0.042 and 0.0028 for a Z′ mass of 0.2 and 2 TeV respectively. We also discuss possible improvements from future runs of LHC with higher luminosities.

Direct determination of the rate constant for the reaction CO + N2O → CO2 + N2

1985 ◽  
Vol 122 (5) ◽  
pp. 489-492 ◽  
Author(s):  
Nobuyuki Fujii ◽  
Tomohisa Kakuda ◽  
Takeo Sugiyama ◽  
Hajime Miyama
Keyword(s):  
Rate Constant ◽  
Direct Determination
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