A Cost‐Effective D‐A‐D Type Hole‐Transport Material Enabling 20% Efficiency Inverted Perovskite Solar Cells

2021 ◽  
Author(s):  
Jiachen Huang ◽  
Jie Yang ◽  
Huiliang Sun ◽  
Kui Feng ◽  
Qiaogan Liao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport

scholarly journals Progress on the Synthesis and Application of CuSCN Inorganic Hole Transport Material in Perovskite Solar Cells

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2592 ◽  
Author(s):  
Funeka Matebese ◽  
Raymond Taziwa ◽  
Dorcas Mutukwa
Keyword(s):  
Solar Cells ◽  
Energy Levels ◽  
Perovskite Solar Cells ◽  
Hole Mobility ◽  
Cost Effective ◽  
Vital Role ◽  
Hole Transport ◽  
Recombination Processes ◽  
Short Synthesis ◽  
P Type

P-type wide bandgap semiconductor materials such as CuI, NiO, Cu2O and CuSCN are currently undergoing intense research as viable alternative hole transport materials (HTMs) to the spiro-OMeTAD in perovskite solar cells (PSCs). Despite 23.3% efficiency of PSCs, there are still a number of issues in addition to the toxicology of Pb such as instability and high-cost of the current HTM that needs to be urgently addressed. To that end, copper thiocyanate (CuSCN) HTMs in addition to robustness have high stability, high hole mobility, and suitable energy levels as compared to spiro-OMeTAD HTM. CuSCN HTM layer use affordable materials, require short synthesis routes, require simple synthetic techniques such as spin-coating and doctor-blading, thus offer a viable way of developing cost-effective PSCs. HTMs play a vital role in PSCs as they can enhance the performance of a device by reducing charge recombination processes. In this review paper, we report on the current progress of CuSCN HTMs that have been reported to date in PSCs. CuSCN HTMs have shown enhanced stability when exposed to weather elements as the solar devices retained their initial efficiency by a greater percentage. The efficiency reported to date is greater than 20% and has a potential of increasing, as well as maintaining thermal stability.

scholarly journals Electrochemical Impedance Spectroscopy Analysis of Hole Transporting Material Free Mesoporous and Planar Perovskite Solar Cells

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1635
Author(s):  
Sumayya M. Abdulrahim ◽  
Zubair Ahmad ◽  
Jolly Bahadra ◽  
Noora J. Al-Thani
Keyword(s):  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Large Area ◽  
The Future ◽  
Hole Transporting Material

The future photovoltaic technologies based on perovskite materials are aimed to build low tech, truly economical, easily fabricated, broadly deployable, and trustworthy solar cells. Hole transport material (HTM) free perovskite solar cells (PSCs) are among the most likely architectures which hold a distinctive design and provide a simple way to produce large-area and cost-effective manufacture of PSCs. Notably, in the monolithic scheme of the HTM-free PSCs, all layers can be printed using highly reproducible and morphology-controlled methods, and this design has successfully been demonstrated for industrial-scale fabrication. In this review article, we comprehensively describe the recent advancements in the different types of mesoporous (nanostructured) and planar HTM-free PSCs. In addition, the effect of various nanostructures and mesoporous layers on their performance is discussed using the electrochemical impedance spectroscopy (EIS) technique. We bring together the different perspectives that researchers have developed to interpret and analyze the EIS data of the HTM-free PSCs. Their analysis using the EIS tool, the limitations of these studies, and the future work directions to overcome these limitations to enhance the performance of HTM-free PSCs are comprehensively considered.

Polymeric, Cost-Effective, Dopant-Free Hole Transport Materials for Efficient and Stable Perovskite Solar Cells

2019 ◽  
Vol 141 (50) ◽  
pp. 19700-19707 ◽  
Author(s):  
Fuguo Zhang ◽  
Zhaoyang Yao ◽  
Yaxiao Guo ◽  
Yuanyuan Li ◽  
Jan Bergstrand ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Free Hole ◽  
Effective Dopant

A novel and cost effective CZTS hole transport material applied in perovskite solar cells

CrystEngComm ◽  
2018 ◽  
Vol 20 (47) ◽  
pp. 7677-7687 ◽  
Author(s):  
Siddhant B. Patel ◽  
Amar H. Patel ◽  
Jignasa V. Gohel
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Ambient Condition ◽  
Nano Particles

CZTS nano-particles are synthesized under ambient condition and applied as low-cost and sustainable inorganic HTM in Perovskite solar cells.

scholarly journals Quinoidal 2,2′,6,6′-Tetraphenyl-Dipyranylidene as a Dopant-Free Hole-Transport Material for Stable and Cost-Effective Perovskite Solar Cells

2017 ◽  
Vol 5 (10) ◽  
pp. 1852-1858 ◽  
Author(s):  
Chao Shen ◽  
Marc Courté ◽  
Anurag Krishna ◽  
Shasha Tang ◽  
Denis Fichou
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Free Hole

Cost-effective dopant-free star-shaped oligo-aryl amines for high performance perovskite solar cells

2019 ◽  
Vol 7 (23) ◽  
pp. 14209-14221 ◽  
Author(s):  
Jun-Ying Feng ◽  
Kuan-Wen Lai ◽  
Yuan-Shin Shiue ◽  
Ashutosh Singh ◽  
CH. Pavan Kumar ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Free Hole ◽  
Aryl Amines ◽  
Effective Dopant

Cost-effective imidazole-based star-shaped arylamines were used as dopant-free hole transport materials (HTMs) for high performance perovskite solar cells (17.47%).

Improved power conversion efficiency of perovskite solar cells using highly conductive WOx doped PEDOT:PSS

2018 ◽  
Vol 42 (19) ◽  
pp. 16075-16082 ◽  
Author(s):  
Anil Kanwat ◽  
V. Sandhya Rani ◽  
Jin Jang
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Styrene Sulfonate ◽  
Poly Styrene Sulfonate

Poly(3,4-thylenedioxythiophene):poly(styrene sulfonate), PEDOT:PSS, is a popular and cost effective conducting polymer for electrodes that can also be used as a hole transport layer (HTL) in optoelectronics.

Hole transport free flexible perovskite solar cells with cost-effective carbon electrodes

2020 ◽  
Vol 32 (10) ◽  
pp. 105205
Author(s):  
Haixia Xie ◽  
Xingtian Yin ◽  
Yuxiao Guo ◽  
Dan Liu ◽  
Tong Liang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Carbon Electrodes

Low cost and solution-processable zinc phthalocyanine as alternative hole transport material for perovskite solar cells

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 107723-107731 ◽  
Author(s):  
Shufang Wu ◽  
Ya Zheng ◽  
Qingwei Liu ◽  
Renjie Li ◽  
Tianyou Peng
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Zinc Phthalocyanine ◽  
Potential Cost ◽  
Solution Processable

A solution-processable and dopant-free ZnPc(tBu)4was used a potential cost-effective substitute for the expensive HTMs containing multifold dopants used in the current PSCs.

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