Metalloporphyrins immobilized in styrene–trifluoroethylmethacrylate copolymer film as an optical oxygen sensing probe

2001 ◽  
Vol 05 (05) ◽  
pp. 433-438 ◽  
Author(s):  
YUTAKA AMAO ◽  
TOKUJI MIYASHITA ◽  
ICHIRO OKURA
Keyword(s):  
Oxygen Concentration ◽  
Response Times ◽  
Oxygen Sensing ◽  
Copolymer Film ◽  
The Other ◽  
Phosphorescence Quenching ◽  
Phosphorescence Intensity ◽  
Highly Sensitive ◽  
The Matrix ◽  
Composition Ratios

A series of new fluoropolymer, poly(styrene-co-trifluoroethylmethacrylate) ( poly - Sty n- co - TFEM m), with different composition ratios of Sty and TFEM units, is synthesized and applied to the matrix of an optical oxygen sensing probe using phosphorescence quenching of metalloporphyrins, platinum and palladium octaethylporphyrin ( PtOEP and PdOEP ), by oxygen. The phosphorescence intensity of PtOEP and PdOEP in poly - Sty n- co - TFEM m film decreased with increase of oxygen concentration. The ratio I 0/ I 100 is used as a sensitivity of the sensing film, where I 0 and I 100 represent the detected phosphorescence intensities from a film exposed to 100% argon and 100% oxygen, respectively. For PtOEP in poly - Sty n- co - TFEM m film, I 0/ I 100 ratios are more than 20.6 and large Stern–Volmer constants greater than 0.49%-1 are obtained compared with PtOEP in PS film. For PdOEP in poly - Sty n- co - TFEM m film, on the other hand, large I 0/ I 100 values greater than 188.7 are obtained. In both cases for PtOEP and PdOEP , I 0/ I 100 values increased with increase of the number of TFEM units in poly - Sty n- co - TFEM m. The response times of PtOEP and PdOEP immobilized in poly - Sty 1- co - TFEM 2.50 films are 5.5 and 3.0 s on going from argon to oxygen and 90.0 and 143 s from oxygen to argon, respectively. These results show that PtOEP and PdOEP immobilized in poly - Sty n- co - TFEM m films are highly sensitive devices for oxygen.

Novel optical oxygen sensing by phosphorescence quenching of palladium porphyrin self-assembled film on alumina plate

2000 ◽  
Vol 04 (02) ◽  
pp. 179-184 ◽  
Author(s):  
YUTAKA AMAO ◽  
KEISUKE ASAI ◽  
ICHIRO OKURA
Keyword(s):  
Oxygen Pressure ◽  
Oxygen Sensor ◽  
Response Times ◽  
Oxygen Sensing ◽  
Fast Response ◽  
Phosphorescence Quenching ◽  
Highly Sensitive ◽  
Optical Oxygen Sensor ◽  
Self Assembled ◽  
Quenching By Oxygen

An optical oxygen sensor based on the phosphorescence quenching of palladium tetrakis(4-carboxyphenyl)porphyrin (PdTCPP) self-assembled film (SAM) on alumina plate was developed. The phosphorescence intensity of PdTCPP film decreased with increasing oxygen pressure, indicating that the film can be used as an optical oxygen-sensing device based on phosphorescence quenching by oxygen. The ratio I0/I100 as a sensitivity measure of the sensing film is estimated to be 17.7, showing that the film is a highly sensitive device for oxygen pressure. The film obeyed Stern–Volmer plots with a multisite model and possessed good operational stability and a fast response. Response times are 36 s for deoxygenated to oxygenated conditions and 148 s for the reverse conditions.

Causal attribution and counterfactual thinking - when does performing one facilitate performance of the other

2003 ◽  
Vol 62 (4) ◽  
pp. 209-218
Author(s):  
A. N’gbala ◽  
N. R. Branscombe
Keyword(s):  
Response Times ◽  
Causal Attribution ◽  
Counterfactual Thinking ◽  
The Other

When do causal attribution and counterfactual thinking facilitate one another, and when do the two responses overlap? Undergraduates (N = 78) both explained and undid, in each of two orders, events that were described either with their potential causes or not. The time to perform either response was recorded. Overall, mutation response times were shorter when performed after an attribution was made than before, while attribution response times did not vary as a consequence of sequence. Depending on whether the causes of the target events were described in the scenario or not, respondents undid the actor and assigned causality to another antecedent, or pointed to the actor for both responses. These findings suggest that counterfactual mutation is most likely to be facilitated by attribution, and that mutation and attribution responses are most likely to overlap when no information about potential causes of the event is provided.

Pembobotan Berdasarkan Tingkat Kesamaan Semantik pada Metode Fuzzy Semi-Supervised Co-Clustering untuk Pengelompokkan Dokumen Teks

2014 ◽  
Vol 6 (2) ◽  
pp. 46-51
Author(s):  
Galang Amanda Dwi P. ◽  
Gregorius Edwadr ◽  
Agus Zainal Arifin
Keyword(s):  
Supervised Learning ◽  
Semantic Similarity ◽  
The Other ◽  
Classification Result ◽  
Document Similarity ◽  
The Matrix ◽  
Index Terms ◽  
Membership Value ◽  
Degree Of Similarity

Nowadays, a large number of information can not be reached by the reader because of the misclassification of text-based documents. The misclassified data can also make the readers obtain the wrong information. The method which is proposed by this paper is aiming to classify the documents into the correct group.  Each document will have a membership value in several different classes. The method will be used to find the degree of similarity between the two documents is the semantic similarity. In fact, there is no document that doesn’t have a relationship with the other but their relationship might be close to 0. This method calculates the similarity between two documents by taking into account the level of similarity of words and their synonyms. After all inter-document similarity values obtained, a matrix will be created. The matrix is then used as a semi-supervised factor. The output of this method is the value of the membership of each document, which must be one of the greatest membership value for each document which indicates where the documents are grouped. Classification result computed by the method shows a good value which is 90 %. Index Terms - Fuzzy co-clustering, Heuristic, Semantica Similiarity, Semi-supervised learning.

Driver Response Times to Side Road Path Intrusions from SHRP-2 Naturalistic Database

2020 ◽  
Vol 64 (1) ◽  
pp. 1525-1529
Author(s):  
Swaroop Dinakar ◽  
Jeffrey Muttart ◽  
Jeffrey Suway ◽  
J.S. Forensics ◽  
Jim Marr ◽  
...  
Keyword(s):  
Emergency Response ◽  
Response Times ◽  
Driver Behavior ◽  
The Other ◽  
Response Behavior ◽  
Driver Response ◽  
Emergency Events ◽  
Behavior Systems

In an age where all major manufacturers are trying to get a better understanding of when an emergency response should be triggered, it becomes imperative to learn how humans respond to emergency events. If one can understand driver behavior, systems can be designed around the user to either assist drivers where they fail to perform well or completely eliminate them from the accident avoidance maneuver. In this study, 169 crash and near crash events from the SHRP2 dataset were analyzed. The response behavior of drivers was measured in events where the through drivers’ path was intruded upon by another vehicle perpendicular to its path. Overall, drivers responded significantly faster when the other vehicle failed to stop, and at intersection locations.

Open class and closed class: Sentence-imitation experiments on intrasentential code-switching

1997 ◽  
Vol 18 (3) ◽  
pp. 257-276 ◽  
Author(s):  
Shoji Azuma ◽  
Richard P. Meier
Keyword(s):  
Response Times ◽  
Code Switching ◽  
The Other ◽  
Speech Errors ◽  
Sentence Repetition ◽  
Closed Class ◽  
Sentence Imitation ◽  
Open Class ◽  
Japanese English

ABSTRACTOne of the most striking facts about exchange errors in speech is that open class items are exchanged, but closed class items are not. This article argues that a pattern analogous to that in speech errors also appears in intrasentential code-switching. Intrasentential code-switching is the alternating use of two languages in a sentence by bilinguals. Studies of the spontaneous conversation of bilinguals have supported the claim that open class items may be codeswitched, but closed class items may not. This claim was tested by two sentence repetition experiments, one with Japanese/English bilinguals and the other with Spanish/English bilinguals. The results show that the switching of closed class items caused significantly longer response times and more errors than the switching of open class items.

Matrix-Mineral Relationships-A. Morphologist's Viewpoint

1979 ◽  
Vol 58 (2_suppl) ◽  
pp. 922-929 ◽  
Author(s):  
M.U. Nylen
Keyword(s):  
Organic Material ◽  
Crucial Role ◽  
Crystal Surface ◽  
Organic Matrix ◽  
The Other ◽  
Enamel Matrix ◽  
Initial Cell ◽  
Cell Product ◽  
Ultrastructural Morphology ◽  
The Matrix

The literature on the ultrastructural morphology of the enamel matrix and its relationship to the crystals is reviewed. Two morphological entities of the matrix are discussed: One is the so-called stippled material which may be the initial cell product; the other, variously described as fibrillar, lamellar, tubular or helical, is thought by many to play a crucial role in nucleation and orientation of the crystals. A number of observations, however, suggest that the latter structures form secondarily to the crystals and that in reality they represent organic material adsorbed to the crystal surface and maintained as independent structures upon removal of the mineral. The need for additional studies is stressed including systematic studies of interactions between constituents of the organic matrix and the apatite crystals.

A Yield Criterion of Porous Materials With Anisotropy Caused by Geometry or Distribution of Pores

1991 ◽  
Vol 113 (4) ◽  
pp. 425-429 ◽  
Author(s):  
T. Hisatsune ◽  
T. Tabata ◽  
S. Masaki
Keyword(s):  
Velocity Field ◽  
Porous Materials ◽  
Upper Bound ◽  
Volume Fraction ◽  
Yield Criterion ◽  
Longitudinal Direction ◽  
Axisymmetric Deformation ◽  
The Other ◽  
The Matrix ◽  
Spherical Cells

Axisymmetric deformation of anisotropic porous materials caused by geometry of pores or by distribution of pores is analyzed. Two models of the materials are proposed: one consists of spherical cells each of which has a concentric ellipsoidal pore; and the other consists of ellipsoidal cells each of which has a concentric spherical pore. The velocity field in the matrix is assumed and the upper bound approach is attempted. Yield criteria are expressed as ellipses on the σm σ3 plane which are longer in longitudinal direction with increasing anisotropy and smaller with increasing volume fraction of the pore. Furthermore, the axes rotate about the origin at an angle α from the σm-axis, while the axis for isotropic porous materials is on the σm-axis.

NO, CO and H2S based pharmaceuticals in the mission of vision (eye health): a comprehensive review

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jan Mohammad Mir ◽  
Ram Charitra Maurya ◽  
Mohd Washid Khan
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Human Physiology ◽  
Hydrogen Sulfide ◽  
The Other ◽  
Normal Functioning ◽  
Comprehensive Review ◽  
Molecular Systems ◽  
Eye Health ◽  
Highly Sensitive

Abstract A set of well defined signaling molecules responsible for normal functioning of human physiology including nitric oxide along with carbon monoxide and hydrogen sulphide are referred as “gasotransmitters”. Due to their involvement in almost every system of a human body, the care of highly sensitive organs using these molecules as drugs represents highly fascinating area of research. In connection with these interesting aspects, the applied aspects of these gaseous molecules in maintaining healthy eye and vision have been targeted in this review. Several examples of eye-droppers including NORMs like latanoprost and nipradiol, CORMs like CORM-3 and CORM-A1, and Hydrogen sulfide releasing system like GYY4137 have been discussed in this context. Therefore the relation of these trio-gasotransmitters with the ophthalmic homeostasis on one hand, and de-infecting role on the other hand has been mainly highlighted. Some molecular systems capable of mimicking gasotransmitter action have also been introduced in connection with the titled theme.

Wounded by reality: emotional deprivation and unresolved trauma in psychoanalytical couple’s therapy

2021 ◽  
Vol 15 (2) ◽  
pp. 253-268
Author(s):  
Hélène Béïnoglou
Keyword(s):  
Romantic Relationships ◽  
Emotional Experience ◽  
Therapeutic Process ◽  
Clinical Work ◽  
The Other ◽  
The Matrix ◽  
Emotional Deprivation ◽  
Unresolved Trauma

In this article, I will focus on highly conflictual couples with extensive emotional deprivation and unresolved trauma, which prevents them from developing healthy romantic relationships and overcoming the challenges entailed in any intimate attachment. I will describe how everyday interactions are experienced as threatening or even lethal movements between the partners. The question which arises in the psychoanalytical therapeutic process is how to help the couple tolerate the sensory reminders of the unresolved trauma as a necessary precursor to any process of symbolisation. In order to provide a safe enough therapeutic attachment bond, extensive time is dedicated to the emotional experience of self and the other in the here-and-now of the session, which validates the emotional experience of the couple as well as contains it. The therapy focuses on the transferential and countertransferential movements inspired by the matrix of the victim, abuser, and uninvolved witness (Davies & Frawley, 1994) to elaborate the intertwining of the unresolved trauma with the couple’s form of attachment. In order to illustrate my argument, I present two examples: one from a fictional narration and another from my clinical work.

Concise Equations for Rotor Dynamics Analysis

1995 ◽  
Author(s):  
W. J. Chen
Keyword(s):  
Equations Of Motion ◽  
Rotor Dynamics ◽  
Memory Storage ◽  
The Other ◽  
Dynamics Analysis ◽  
Real Domain ◽  
The Matrix ◽  
System Equations ◽  
Ordering Algorithms ◽  
Matrix Bandwidth

Abstract Concise equations for rotor dynamics analysis are presented. Two coordinate ordering methods are introduced in the element equations of motion. One is in the real domain and the other is in the complex domain. The two proposed ordering algorithms lead to more compact element matrices. A station numbering technique is also proposed for the system equations during the assembly process. This numbering technique can minimize the matrix bandwidth, the memory storage and can increase the computational efficiency.

Sign in / Sign up

Export Citation Format

Share Document