The influence of CO2 accelerated carbonation on alkali-activated fly ash cement under elevated temperature and pressure

2018 ◽  
Vol 49 (4) ◽  
pp. 483-488 ◽  
Author(s):  
S. Ridha ◽  
R.A. Setiawan ◽  
A.I. Abd Hamid ◽  
A.R. Shahari
2017 ◽  
Vol 43 (15) ◽  
pp. 12490-12496 ◽  
Author(s):  
Nam Kon Lee ◽  
Kyung Taek Koh ◽  
Min Ook Kim ◽  
Gi Hong An ◽  
Gum Sung Ryu

Activated Slag (AAS) and Fly Ash (FA) based geopolymer concrete a new blended alkali-activated concrete that has been progressively studied over the past years because of its environmental benefits superior engineering properties. Geopolymer has many favorable characteristics in comparison to Ordinary Portland Cement. Many base materials could be utilized to make geopolymer with the convenient concentration of activator solution. In this study, the experimental program composed of two phases; phase on divided into four groups; Group one deliberated the effect of sodium hydroxide molarity and different curing condition on compressive strength. Group two studied the effect of alkali activated solution (NaOH and Na2SiO3) content on compressive strength and workability. The effect of sand replacement with slag on compressive strength and workability was explained in group three. Group four studied the effect of slag replacement with several base materials Fly Ash (FA), Ordinary Portland Cement (OPC), pulverized Red Brick (PRB), and Meta Kaolin (MK). Phase two contains three mixtures from phase one which had the highest compressive strength. For each mixture, the fresh concrete test was air content. In addition the hardened concrete tests were the compressive strength at 3, 7, 28, 90, 180, and 365 days, the flexural strength at 28, 90, and 365 days, and the young's modulus at 28, 90, and 365 days. Moreover; the three mixtures were exposed to elevated temperature at 100oC, 300oC, and 600oC to study the effect of elevated temperature on compressive and flexural strength.


2019 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Subhash Yaragal ◽  
Chethan Kumar B. ◽  
Manoj Uddavolu Abhinav

Purpose To reduce environmental impact caused by excessive use of ordinary Portland cement (OPC) and to mitigate scarcity of base materials such as natural coarse aggregate (NCA), industrial by-products can be carefully used as alternatives to OPC and NCA, in production of concrete. This paper aims to describe the performance of using ground granulated blast furnace slag (GGBS), fly ash (FA) as a complete replacement to OPC and ferrochrome slag (FCS) as replacement to NCA in production of novel FCS based alkali activated slag/fly ash concretes (AASFC) and evaluate their performance at elevated temperatures. Design/methodology/approach Two control factors with three levels each i.e. FA (0, 25 and 50 per cent by weight) and FCS (0, 50 and 100 per cent by volume) as a GGBS and NCA replacement, respectively, were adopted in AASFC mixtures. Further, AASFC mixture specimens were subjected to different levels of elevated temperature, i.e. 200°C, 400°C, 600°C and 800°C. Compressive strength and residual compressive strength were considered as responses. Three different optimization techniques i.e. gray relational analysis, technique for order preference by similarity to ideal solution and Desirability function approach were used to optimize AASFC mixtures subjected to elevated temperatures. Findings As FA replacement increases in FCS based AASFC mixtures, workability increases and compressive strength decreases. The introduction of FCS as replacement to NCA in AASFC mixture did not show any significant change in compressive strength under ambient condition. AASFC produced with 75 per cent GGBS, 25 per cent FA and 100 per cent FCS was found to have excellent elevated temperature enduring properties among all other AASFC mixtures studied. Originality/value Although several studies are available on using GGBS, FA and FCS in production of OPC-based concretes, present study reports the performance of novel FCS based AASFC mixtures subjected to elevated temperatures. Further, GGBS, FA and FCS used in the present investigation significantly reduces CO2 emission and environmental degradation associated with OPC production and NCA extraction, respectively.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 671
Author(s):  
Yuto Yamazaki ◽  
Jihoon Kim ◽  
Keisuke Kadoya ◽  
Yukio Hama

Alkali-activated cements prepared from aluminosilicate powders, such as blast furnace slag and fly ash, are rapidly attracting attention as alternatives to cement because they can significantly reduce CO2 emissions compared to conventional cement concrete. In this study, we investigated the relationship between the physical and chemical changes by accelerated carbonation conditions of alkali-activated cements. Alkali-activated cements were prepared from binders composed of blast furnace slag and fly ash as well as alkali activators sodium silicate and sodium hydroxide. Physical changes were analyzed from compressive strength, pH, and neutralization depth, and chemical changes were analyzed from XRD, TG-DTG, and 29Si MAS NMR. The C–(N)–A–S–H structure is noted to change via carbonation, and the compressive strength is observed to decrease. However, in the case of Na-rich specimens, the compressive strength does not decrease by accelerated carbonation. This work is expected to contribute to the field of alkali-activated cements in the future.


2022 ◽  
Vol 316 ◽  
pp. 125864
Author(s):  
Sasui Sasui ◽  
Gyuyong Kim ◽  
Jeongsoo Nam ◽  
Arie van Riessen ◽  
Marijana Hadzima-Nyarko ◽  
...  

2013 ◽  
Vol 53 ◽  
pp. 127-144 ◽  
Author(s):  
Susan A. Bernal ◽  
John L. Provis ◽  
Brant Walkley ◽  
Rackel San Nicolas ◽  
John D. Gehman ◽  
...  

2017 ◽  
Vol 864 ◽  
pp. 65-70 ◽  
Author(s):  
Syahrir Ridha ◽  
Muhammad Fareez Jamali ◽  
Riau Andriana Setiawan

This paper investigates the composition of geopolymer cement for thickening time under elevated temperature and pressure. Geopolymer based-cement becoming popular in construction industries because of its improved properties either chemically and physically as compared to Ordinary Portland Cement (OPC). At the same time, replacement of OPC with geopolymer cement able to eliminate CO2 emission due to calcination burning process. However, applications of geopolymer cement to oil and gas industry for cementing job are not well recorded. Fly ash based geopolymer cement with different percentages of slag from 0% to 10% were mixed using sodium hydroxide and sodium silicate as alkali activators. Density, fluid loss and compressive strengths were determined. The sample were cured at 3,000 psi and 65°C for 24 hours. Results show that the addition of slag reduces the thickening time from 30 minutes to just only 18 minutes with almost 40% reduction in time. In terms of density and compressive strength, an increment of slag is directly proportional as the value increased from 14.3 ppg to 15.0 ppg for density and 1,120 psi to 2,155 psi for compressive strength. For fluid loss test, increment of slag results in decrement of fluid loss from 0.64 ml to just only 0.38 ml.


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