Assessment of the Water-Extractable Genotoxic Potential of Soil Samples from Contaminated Sites

2000 ◽  
Vol 46 (1) ◽  
pp. 73-80 ◽  
Author(s):  
Heike Ehrlichmann ◽  
Wolfgang Dott ◽  
Adolf Eisentraeger
2007 ◽  
Vol 87 (1) ◽  
pp. 73-83 ◽  
Author(s):  
D. Kimaragamage ◽  
O O Akinremi ◽  
D. Flaten ◽  
J. Heard

Quantitative relationships between soil test phosphorus (STP) methods are needed to guide P management especially in manured soils with high P. Our objectives were: (i) to compare amounts of P extracted by different methods; (ii) to develop and verify regression equations to convert results among methods; and (iii) to establish environmental P thresholds for different methods, in manured and non-manured soils of Manitoba. We analyzed 214 surface soil samples (0–15 cm), of which 51 had previous manure application. Agronomic STP methods were Olsen (O-P), Mehlich-3 (M3-P), Kelowna-1 (original; K1-P), Kelowna-2 (modified; K2-P), Kelowna-3 (modified; K3-P), Bray-1 (B1-P) and Miller and Axley (MA-P), while environmental STP methods were water extractable (W-P), Ca Cl2 extractable (Ca-P) and iron oxide impregnated filter paper (FeO-P) methods. The different methods extracted different amounts of P, but were linearly correlated. For an O-P range of 0–30 mg kg-1, relationships between O-P and other STP were similar for manured and nonmanured soils, but the relationships diverged at higher O-P levels, indicating that one STP cannot be reliably converted to another using a single equation for manured and non-manured soils at environmentally critical P levels (0–100 mg kg-1 O-P). Suggested environmental soil P threshold ranges, in mg P kg-1, were 88–118 for O-P, 138–184 for K1-P, 108–143 for K2-P, 103–137 for K3-P, 96–128 for B1-P, 84–111 for MA-P, 15–20 for W-P, 5–8 for Ca-P and 85–111 for FeO-P. Key words: Phosphorus, soil test phosphorus, manured soils, non-manured soils, environmental threshold


Author(s):  
T. F. Jenkins ◽  
C. L. Grant ◽  
G. S. Brar ◽  
P. G. Thorne ◽  
P. W. Schumacher ◽  
...  

2021 ◽  
Author(s):  
Elizabeth Corriveau ◽  
Jay Clausen

Historically, researchers studying contaminated sites have used grab sampling to collect soil samples. However, this methodology can introduce error in the analysis because it does not account for the wide variations of contaminant concentrations in soil. An alternative method is the Incremental Sampling Methodology (ISM), which previous studies have shown more accurately captures the true concentration of contaminants over an area, even in heterogeneous soils. This report describes the methods and materials used with ISM to collect soil samples, specifically for the purpose of mapping subsurface contamination from site activities. The field data presented indicates that ISM is a promising methodology for collecting subsurface soil samples containing contaminants of concern, including metals and semivolatile organic compounds (SVOCs), for analysis. Ultimately, this study found ISM to be useful for supplying information to assist in the decisions needed for remediation activities.


HortScience ◽  
1993 ◽  
Vol 28 (12) ◽  
pp. 1166-1167 ◽  
Author(s):  
AK. Alva ◽  
T.A. Obreza

Deep aquifer water, which contains high levels of bicarbonate and Ca, is used predominantly for citrus irrigation. Changes in soil pH and Mehlich 1 extractable Ca concentrations were examined inside and outside the microsprinkler-wetted zone in 3- to 5-year-old citrus groves on three soils. Soil pH at 0 to 15 cm inside the wetted zone was 0.4, 0.9, and 1.3 pH units higher than that outside the wetted zone in Immokalee, Myakka, and Holopaw sands, respectively. This pH increase was due to the addition of bicarbonate in the irrigation water. Extractable Ca concentrations were also about two-fold higher inside compared to those outside the wetted zone at depths of O to 15 and 15 to 30 cm. With young trees, a majority of the roots are within the microsprinkler-wetted zone; therefore, soil samples should be taken inside the wetted zone for measuring soil pH and status of plant nutrients.


2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Chuang Yu ◽  
Raoping Liao ◽  
Chaopeng Zhu ◽  
Xiaoqing Cai ◽  
Jianjun Ma

Oil-contaminated soils have been paid much attention due to the reclamation of industrial lands in coastal cities of China. As known, oil-contaminated soils are inapplicable for construction due to their weak engineering properties, thus leading to the requirement of remediation and reclamation for oil-contaminated sites. This study presents an experimental investigation on the stabilization of contaminated soils with Portland cement. Investigations including the Atterberg limits, unconfined compressive strength, direct shear strength, and microstructure of cement-stabilized soils have been carried out, verifying the suitability of applying cement to improve engineering properties. Experimental results show that the geotechnical properties of contaminated soil are very poor. With the application of cement, the liquid limit and plasticity index of contaminated soil samples decrease dramatically, and the strength of treated soils has been improved. Experimental results from scanning electron microscope (SEM) indicate that cement-stabilized oil-contaminated soil is featured with a stable supporting microstructure, owing to the cementation between soil particles. This also confirms the applicability of cement to be served as an additive to treat oil-contaminated soils.


2000 ◽  
Vol 66 (7) ◽  
pp. 2842-2852 ◽  
Author(s):  
Vladimir S. Sentchilo ◽  
Alexander N. Perebituk ◽  
Alexander J. B. Zehnder ◽  
Jan Roelof van der Meer

ABSTRACT Twenty different Pseudomonas strains utilizingm-toluate were isolated from oil-contaminated soil samples near Minsk, Belarus. Seventeen of these isolates carried plasmids ranging in size from 78 to about 200 kb (assigned pSVS plasmids) and encoding the meta cleavage pathway for toluene metabolism. Most plasmids were conjugative but of unknown incompatibility groups, except for one, which belonged to the IncP9 group. The organization of the genes for toluene catabolism was determined by restriction analysis and hybridization with xyl gene probes of pWW0. The majority of the plasmids carried xyl-type genes highly homologous to those of pWW53 and organized in a similar manner (M. T. Gallegos, P. A. Williams, and J. L. Ramos, J. Bacteriol. 179:5024–5029, 1997), with two distinguishable metapathway operons, one upper pathway operon, and threexylS-homologous regions. All of these plasmids also possessed large areas of homologous DNA outside the catabolic genes, suggesting a common ancestry. Two other pSVS plasmids carried only onemeta pathway operon, one upper pathway operon, and one copy each of xylS and xylR. The backbones of these two plasmids differed greatly from those of the others. Whereas these parts of the plasmids, carrying the xyl genes, were mostly conserved between plasmids of each group, the noncatabolic parts had undergone intensive DNA rearrangements. DNA sequencing of specific regions near and within the xylTE and xylAgenes of the pSVS plasmids confirmed the strong homologies to thexyl genes of pWW53 and pWW0. However, several recombinations were discovered within the upper pathway operons of the pSVS plasmids and pWW0. The main genetic mechanisms which are thought to have resulted in the present-day configuration of thexyl operons are discussed in light of the diversity analysis carried out on the pSVS plasmids.


2007 ◽  
Vol 123 ◽  
pp. 111-121 ◽  
Author(s):  
Maria Dimitrova ◽  
Evgeniya Dimova ◽  
Zhana Mitrovska ◽  
Veneta Kapchina-Toteva ◽  
Stephka Chankova

2002 ◽  
Vol 11 (4) ◽  
pp. 371-379 ◽  
Author(s):  
T. PELTOVUORI

Samples taken from the plow layer (Ap horizon)and subsoil (B horizon)of six cultivated soil profiles were analyzed as original samples and as mixtures containing 25% or 50% material from the B horizon. Acid ammonium acetate extractable phosphorus, degree of phosphorus saturation (DPS), and a phosphorus Q/I-plot were determined for each sample and mixture to evaluate the effect of bulking of dissimilar materials on results and to assess the possibilities of reducing P solubility in P-enriched surface soils. The results obtained for the mixtures were compared with mass-weighed average results of the original samples. Measured values of DPS corresponded well and those of acetate-extractable P reasonably well to the estimated values, and the results were linearly correlated with the mass fraction of horizon B material in the mixed samples (r2>0.85).Water-extractable P behaved dissimilarly; the equilibrium P concentration (EPC) estimated from the Q/I-plots decreased dramatically when the fraction of highly sorptive horizon B material increased in the mixture. The marked effect of subsoil material on EPC values may provide a technique to reduce potential losses of soluble P by deep tillage.;


2018 ◽  
Vol 64 (No. 9) ◽  
pp. 455-462
Author(s):  
Kulhánek Martin ◽  
Černý Jindřich ◽  
Balík Jiří ◽  
Sedlář Ondřej ◽  
Suran Pavel

Mehlich 3 is an extractant used worldwide for extracting bioavailable nutrients in soils; however, its extraction abilities for sulfur (S) are still not well described. The aim of this preliminary study was to compare the results of Mehlich 3 determined soil S fraction (S<sub>M3</sub>) with the results of sulfur fractionation, mainly focusing on bioavailable S (S<sub>av</sub> – sum of water-extractable (S<sub>w</sub>) and adsorbed (S<sub>ads</sub>) sulfur). Air dried soil samples from commonly used agricultural soils were chosen for the analyses. The following S fractions were determined: (i) S<sub>w</sub>; (ii) S<sub>ads</sub>; (iii) S<sub>av</sub>; (iv) 1 mol/L HCl extractable (S<sub>HCl</sub>); (v) estersulfate (S<sub>es</sub>); (vi) organic (S<sub>org</sub>) and (vii) total (S<sub>tot</sub>). The median value of S<sub>M3</sub> (18.3 mg/kg) was similar to S<sub>av</sub> (17.9 mg/kg). From the correlation and regression analysis it is clear that S<sub>M3</sub> results are in close relationship with S<sub>av</sub> form. On the other hand, the relationships between S<sub>M3</sub> and organic S (including S<sub>HCl</sub>) were very weak. Based on the obtained results it can be concluded that Mehlich 3 method has a good potential to determine bioavailable sulfur in commonly used agricultural soils. However, especially the plant response should be further studied to confirm this theory.


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