Abstract: the article presents the results of application of distributed deterministic hydrological model Hydrograph for estimation of maximum discharge values of different frequency at the ungauged catchment of the Khemchik River (Khemchik village, Tuva Republic). The catchment area is 1750 km2 , the average and maximum elevation — 2200 and 3600 m, respectively. Due to the lack of detailed information, a schematization of the catchment and the parameterization of the model are proposed, based on general ideas about the water balance and the processes of runoff formation of the main landscapes — rocky talus, coniferous forest and steppe. Parameters and algorithms are verified based on the results of streamflow modeling at two studied catchments: the Tapsy River — Kara-Khol (302 km2 ) and the Khemchik River — Iyme (25500 km2 ). Modelling of runoff formation processes with daily time step for the Khemchik River — Khemchik village was conducted for the period 1966–2012 using observational data at Teeli meteorological station. For the transition from daily to instant discharges, the dependence of the observed values of instant and daily streamflow at the studied gauges has been applied. On the basis of simulated discharge series, the frequency curve was built and the obtained curve was compared with the calculation data according to the standard methodology SP 33-101-2003 “Determination of the main calculated hydrological characteristics” using the analogue river. Simulated maximum instant discharges for entire frequency interval of up to 1% are 1.3–5 times higher than the values obtained by standard methodology SP 33-101-2003. The results of model calculations is indirectly confirmed by the evidences of regular flooding of the Khemchik village provided by the Ministry of Emergency Situations of the Tuva Republic, which is not predicted by the values obtained by the standard methods.