An Attempt to Distinguish Thermal from Oxidative Ageing of Asphalt Binders by NRTFOT

2021 ◽  
pp. 207-213
Author(s):  
Ingrid Camargo ◽  
Bernhard Hofko ◽  
Johannes Mirwald ◽  
Hinrich Grothe
2011 ◽  
Vol 71-78 ◽  
pp. 1062-1067 ◽  
Author(s):  
Zhen Gang Feng ◽  
Jian Ying Yu ◽  
Heng Long Zhang ◽  
Dong Liang Kuang

The modified asphalt binders with various anti-ageing additives, including ultraviolet (UV) absorber, antioxidant and combination of them, were prepared, and the effects of UV absorber contents, antioxidant contents and combination of UV absorber and antioxidant on physical properties and ageing characteristics of the asphalt binder were investigated. Results show that the ductility of asphalt binder increases whereas the softening point and viscosity decrease with addition of anti-ageing additives. UV absorbers and antioxidants exhibit different influences on the ageing properties of asphalt binder. The thermal- and photo-oxidative ageing performance of asphalt binder can be simultaneously improved by the compound modification with UV absorber and antioxidant. The combination of UV326 and antioxidant 1010 shows synergistic effect in preventing the asphalt binder from thermal- and photo-oxidative ageing, which contributes to excellent ageing resistance of modified asphalt binder.


2014 ◽  
Vol 15 (sup1) ◽  
pp. 45-61 ◽  
Author(s):  
Farinaz Safaei ◽  
Jong-sub Lee ◽  
Luis Alberto Hermann do Nascimento ◽  
Cassie Hintz ◽  
Y. Richard Kim

2019 ◽  
Vol 32 (3) ◽  
pp. 306-315 ◽  
Author(s):  
Liang Xu ◽  
Yi He ◽  
Shaohua Ma ◽  
Li Hui

T800/high-temperature epoxy resin composites with different hole shapes were subjected to hygrothermal ageing and thermal-oxidative ageing, and the effects of these different ageing methods on the open-hole properties of the composites were investigated, including analyses of the mass changes, surface topography changes (before and after ageing), fracture morphologies, open-hole compressive performance, dynamic mechanical properties and infrared spectrum. The results showed that only physical ageing occurred under hygrothermal ageing (70°C and 85% relative humidity), and the equilibrium moisture absorption rate was only approximately 0.72%. In contrast, under thermal-oxidative ageing at 190°C, both physical ageing and chemical ageing occurred. After ageing, the open-hole compressive strength of the composite laminates with different hole shapes decreased significantly, but the open-hole compressive strength after thermal-oxidative ageing was greater than that after hygrothermal ageing. Among the aged and unaged laminates, the laminates with round holes exhibited the largest open-hole compressive strength, followed by those with the elliptical holes, square holes and diamond holes. The failure modes of the laminates were all through-hole failures. The unaged samples had a glass transition temperature ( T g) of 226°C, whereas the T g of the samples after hygrothermal ageing was 208°C, which is 18°C less than that of the unaged samples, and the T g of the samples after thermal-oxidative ageing was 253°C, which is 27°C greater than that of the unaged samples.


Environments ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 47
Author(s):  
Lim Min Khiong ◽  
Md. Safiuddin ◽  
Mohammad Abdul Mannan ◽  
Resdiansyah

This paper presents the results of a laboratory-based experimental investigation on the properties of asphalt binder and hot-mix asphalt (HMA) mixes modified by locally available crumb rubber, which was used as a partial replacement of asphalt by weight. In this study, fine crumb rubber with a particle size in the range of 0.3–0.6 mm, obtained from scrap tires, was added to the asphalt binder through the wet process. Crumb rubber contents of 5%, 10%, 15%, and 19% by weight of asphalt were added to the virgin binder in order to prepare the modified asphalt binder samples, while the unmodified asphalt binder was used as the control sample. The crumb rubber modified binder samples were examined for measuring viscosity indirectly using the penetration test, and temperature resistance using the softening point test. Later, both the modified and unmodified asphalt binders were used to produce HMA mixes. Two categories of HMA mix commonly used in Malaysia—namely, AC 14 (dense-graded) and SMA 14 (gap-graded)—were produced using the modified asphalt binders containing 5%, 10%, 15%, and 19% crumb rubber. Two AC 14 and SMA 14 control mixes were also produced, incorporating the unmodified asphalt binder (0% crumb rubber). All of the AC 14 and SMA 14 asphalt mixes were examined in order to determine their volumetric properties, such as bulk density, voids in total mix (VTM), voids in mineral aggregate (VMA), and voids filled with asphalt (VFA). In addition, the Marshall stability, Marshall flow, and stiffness of all of the AC 14 and SMA 14 mixes were determined. Test results indicated that the modified asphalt binders possessed higher viscosity and temperature resistance than the unmodified asphalt binder. The viscosity and temperature resistance of the asphalt binders increased with the increase in their crumb rubber content. The increased crumb rubber content also led to improvements in the volumetric properties (bulk density, VTM, VMA, and VFA) of the AC 14 and SMA 14 mixes. In addition, the performance characteristics of the AC 14 and SMA 14 mixes—such as Marshall stability, Marshall flow, and stiffness—increased with the increase in crumb rubber content. However, the AC 14 mixes performed much better than the SMA 14 mixes. The overall research findings suggest that crumb rubber can be used to produce durable and sustainable HMA mixes, with manifold environmental benefits, for use in flexible pavements carrying the heavy traffic load of highways.


2020 ◽  
Vol 13 (6) ◽  
pp. 697-706
Author(s):  
Yuhong Wang ◽  
Kecheng Zhao ◽  
Fangjin Li ◽  
Qi Gao ◽  
King Wai Chiu Lai

AbstractThe microscopic surface features of asphalt binders are extensively reported in existing literature, but relatively fewer studies are performed on the morphology of asphaltene microstructures and cross-examination between the surface features and asphaltenes. This paper reports the findings of investigating six types of asphalt binders at the nanoscale, assisted with atomic force microscopy (AFM) and scanning transmission electron microscopy (STEM). The surface features of the asphalt binders were examined by using AFM before and after being repetitively peeled by a tape. Variations in infrared (IR) absorbance at the wavenumber around 1700 cm−1, which corresponds to ketones, were examined by using an infrared s-SNOM instrument (scattering-type scanning near-field optical microscope). Thin films of asphalt binders were examined by using STEM, and separate asphaltene particles were cross-examined by using both STEM and AFM. In addition, connections between the microstructures and binder’s physicochemical properties were evaluated. The use of both microscopy techniques provide comprehensive and complementary information on the microscopic nature of asphalt binders. It was found that the dynamic viscosities of asphalt binders are predominantly determined by the zero shear viscosity of the corresponding maltenes and asphaltene content. Limited samples also suggest that the unique bee structures are likely related to the growth of asphaltene content during asphalt binder aging process, but more asphalt binders from different crude sources are needed to verify this finding.


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