Development of Large Area, Low-Cost, Solar Cell Processing Sequence

Author(s):  
Sanjeev Chitre ◽  
Jérôme Donon
2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Utpal Gangopadhyay ◽  
Sukhendu Jana ◽  
Sayan Das

We present 11.7% efficient p-type crystalline silicon solar cells with a nanoscale textured surface and no dielectric antireflection coating. We propose nanocrystalline-like textured surface consisting of nanocrystalline columnar structures of diameters from 50 to 100 nm and depth of about 500 nm formed by reactive-ion etching (RIE) in multihollow cathode system. This novel nano textured surface acts as an antireflective absorbing surface of c-Si abbreviate as ARNAB (antireflective nanoabsorber). Light shining on the surface of RIE-etched silicon bounces back and forth between the spikes in such a way that most of it never comes back. Radio frequency (RF) hollow cathode discharge allows an improvement of plasma density by an order of magnitude in comparison to standard RF parallel-plate discharge. Desirable black silicon layer has been achieved when RF power of about 20 Watt per one hollow cathode glow is applied for our multihollow cathode system. The RF power frequency was 13.56 MHz. The antireflection property of ARNAB textured surface has been investigated and compared with wet-textured and PECVD coated silicon samples. Solar cell using low-cost spin-on coating technique has been demonstrated in this paper. We have successfully achieved 11.7% efficient large area (98 cm2) ARNAB textured crystalline silicon solar cell using low-cost spin-on coating (SOD) doping.


2010 ◽  
Vol 25 (12) ◽  
pp. 2426-2429 ◽  
Author(s):  
Guangjun Wang ◽  
Gang Cheng ◽  
Binbin Hu ◽  
Xiaoli Wang ◽  
Shaoming Wan ◽  
...  

In this paper, polycrystalline CuIn(SxSe1–x)2 thin films with tunable x and Eg (band gap) values were prepared by controlling the sulfurization temperature (T) of CuInSe2 thin films. X-ray diffraction indicated the CuIn(SxSe1–x)2 films exhibited a homogeneous chalcopyrite structure. When T increases from 150 to 500 °C, x increases from 0 to 1, and Eg increases from 0.96 to 1.43 eV. The relations between x and Eg and the sulfurization process of CuIn(SxSe1–x)2 thin films have been discussed. This work provides an easy and low-cost technique for preparing large area absorber layers of solar cell with tunable Eg.


2004 ◽  
Vol 5 (1) ◽  
pp. 1-6 ◽  
Author(s):  
U. Gangopadhyay ◽  
Kyung-Hea Kim ◽  
S.K. Dhungel ◽  
D. Mangalaraj ◽  
J.H. Park ◽  
...  

2015 ◽  
Vol 51 (79) ◽  
pp. 14696-14707 ◽  
Author(s):  
B. Susrutha ◽  
Lingamallu Giribabu ◽  
Surya Prakash Singh

Flexible thin-film photovoltaics facilitate the implementation of solar devices into portable, reduced dimension, and roll-to-roll modules. In this review, we describe recent developments in the fabrication of flexible perovskite solar cells that are low cost and highly efficient and can be used for the fabrication of large-area and lightweight solar cell devices.


2012 ◽  
Vol 131 (3) ◽  
pp. 600-604 ◽  
Author(s):  
Mahesh Chand Sharma ◽  
Balram Tripathi ◽  
Sumit Kumar ◽  
Subodh Srivastava ◽  
Y.K. Vijay

Micromachines ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 119
Author(s):  
Sangho Kim ◽  
Gwan Seung Jeong ◽  
Na Yeon Park ◽  
Jea-Young Choi

In this report, we present a process for the fabrication and tapering of a silicon (Si) nanopillar (NP) array on a large Si surface area wafer (2-inch diameter) to provide enhanced light harvesting for Si solar cell application. From our N,N-dimethyl-formamide (DMF) solvent-controlled spin-coating method, silica nanosphere (SNS in 310 nm diameter) coating on the Si surface was demonstrated successfully with improved monolayer coverage (>95%) and uniformity. After combining this method with a reactive ion etching (RIE) technique, a high-density Si NP array was produced, and we revealed that controlled tapering of Si NPs could be achieved after introducing a two-step RIE process using (1) CHF3/Ar gases for SNS selective etching over Si and (2) Cl2 gas for Si vertical etching. From our experimental and computational study, we show that an effectively tapered Si NP (i.e., an Si nanotip (NT)) structure could offer a highly effective omnidirectional and broadband antireflection effect for high-efficiency Si solar cell application.


1999 ◽  
Vol 581 ◽  
Author(s):  
T.K. Gupta ◽  
L.J. Cirignano ◽  
K.S. Shah ◽  
L.P. Moy ◽  
D.J. Kelly ◽  
...  

ABSTRACTThe fabrication and testing of screen printed dye-sensitized large solar cell (15 cm × 15 cm) based on nanocrystalline TiO2 is described. It is the largest photo-electrochemical (PEC) cell that is based on the dye sensitization of thin (8-18 μm) films of TiO2 nanoparticles in contact with a non-aqueous liquid electrolyte. The cell has the potential to be a low cost, commercial, environmentally friendly, photovoltaic option. Surface as well as electrical characterization, of the nanostructured PEC cells have been performed. The efficiency of these large commercial cells are compared to the laboratory-made small PEC cells. Key words: Photoelectrochemical, solar cells, nanocrystalline, dye-sensitized


1992 ◽  
Vol 258 ◽  
Author(s):  
P. Chabloz ◽  
H. Keppner ◽  
V. Baertschi ◽  
A. Shah ◽  
D. Chatellard ◽  
...  

ABSTRACTIn spite of its low absorption coefficient for X-rays, amorphous Silicon can be an interesting alternative approach for X-ray detection because of its low cost, its potential for large-area deposition and the possibility to deposit on a curved surface. For this application, basically two approaches have been proposed up to now: either a thick solar cell type n-i-p structure (the i-layer as to be sufficiently thick i.e typically 50 μm or more), or a normal solar cell type n-i-p structure (with a relatively thin i-layer, i.e (typically 1 to 2 μm) together with a fluorescent layer emitting visible light composed e.g. of CsJ. In this paper, we present first results of a X-ray detectors with thick i-layers (15 to 100 μm) prepared by the high deposition rate VHF-GD technique introduced at our laboratory. Detectors with low leakage currents (<4nA/cm2) under high reverse bias voltages (about 100 V) could be fabricated at rates as high as 22 Å/s. As substrates, aluminium as well as TCO-coated glass substrates were used. The detectors have a n-i-p structure, where highly conductive (100 S/cm) n-doped μc-Si:H was first deposited. For the substrate preparation, a high energy Ar plasma was applied before the first deposition step; in this way excellent sticking conditions could be achieved, although in the thicker detectors considerable curvature due to the internal mechanical stress could be observed. A medical X-ray radiation source was used, where the detector was exposed to a continuous X-ray spectrum at acceleration voltages between 80 kV and 240 kV. The paper presents measurements on the linearity of the detector, as well as on the value of the reverse current in the dark, which must be as small as possible to have the best signal to noise ratio.


2007 ◽  
Vol 2007 ◽  
pp. 1-5 ◽  
Author(s):  
U. Gangopadhyay ◽  
K. Kim ◽  
S. K. Dhungel ◽  
H. Saha ◽  
J. Yi

The low-cost chemical bath deposition (CBD) technique is used to prepare CBD-ZnS films as antireflective (AR) coating for multicrystalline silicon solar cells. The uniformity of CBD-ZnS film on large area of textured multicrystalline silicon surface is the major challenge of CBD technique. In the present work, attempts have been made for the first time to improve the rate of deposition and uniformity of deposited film by controlling film stoichiometry and refractive index and also to minimize reflection loss by proper optimization of molar percentage of different chemical constituents and deposition conditions. Reasonable values of film deposition rate (12.13 Å′/min.), good film uniformity (standard deviation <1), and refractive index (2.35) along with a low percentage of average reflection (6-7%) on a textured mc-Si surface are achieved with proper optimization of ZnS bath. 12.24% efficiency on large area (125 mm × 125 mm) multicrystalline silicon solar cells with CBD-ZnS antireflection coating has been successfully fabricated. The viability of low-cost CBD-ZnS antireflection coating on large area multicrystalline silicon solar cell in the industrial production level is emphasized.


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