Determination of patulin using dual-dummy templates imprinted electrochemical sensor with PtPd decorated N-doped porous carbon for amplification

2021 ◽  
Vol 188 (5) ◽  
Author(s):  
Xiaopeng Hu ◽  
Yide Xia ◽  
Yiwei Liu ◽  
Faqiong Zhao ◽  
Baizhao Zeng
Keyword(s):  
Electrochemical Sensor ◽  
Porous Carbon

MOF/PAN nanofiber-derived N-doped porous carbon materials with excellent electrochemical activity for the simultaneous determination of catechol and hydroquinone

2019 ◽  
Vol 43 (9) ◽  
pp. 3913-3920 ◽  
Author(s):  
Mengxin Zhang ◽  
Meishan Li ◽  
Wangui Wu ◽  
Junkun Chen ◽  
Xiuling Ma ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Simultaneous Determination ◽  
Porous Carbon ◽  
Carbon Materials ◽  
Electrochemical Activity ◽  
Porous Carbon Materials ◽  
One Step ◽  
Pan Nanofiber

In this work, the obtained C-ZIF-67/PAN via one-step pyrolysis of hybrid ZIF-67/PAN nanofibers were used to fabricate electrochemical sensor for the determination of benzenediol isomer.

High-performance electrochemical sensing platform based on sodium alginate-derived 3D hierarchically porous carbon for simultaneous determination of dihydroxybenzene isomers

2021 ◽  
Author(s):  
Liang Wei ◽  
Xinlong Huang ◽  
Xianqian Zhang ◽  
Xiande Yang ◽  
Jing Yang ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Simultaneous Determination ◽  
Porous Carbon ◽  
High Performance ◽  
Three Dimensional ◽  
Electrochemical Sensing ◽  
Dihydroxybenzene Isomers ◽  
Hierarchically Porous ◽  
Sensing Platform

A selective and sensitive electrochemical sensor based on three-dimensional hierarchically porous carbon was developed for simultaneous determination of dihydroxybenzene isomers.

Graphene Modified Molecular Imprinting Electrochemical Sensor for Determining the Content of Dopamine

2019 ◽  
Vol 15 (6) ◽  
pp. 628-634
Author(s):  
Rong Liu ◽  
Jie Li ◽  
Tongsheng Zhong ◽  
Liping Long
Keyword(s):  
Electrochemical Sensor ◽  
Molecular Imprinting ◽  
Neurological Disorders ◽  
Room Temperature ◽  
Low Cost ◽  
Differential Pulse ◽  
Current Response ◽  
Specific Selectivity ◽  
Pulse Voltammetry

Background: The unnatural levels of dopamine (DA) result in serious neurological disorders such as Parkinson’s disease. Electrochemical methods which have the obvious advantages of simple operation and low-cost instrumentation were widely used for determination of DA. In order to improve the measurement performance of the electrochemical sensor, molecular imprinting technique and graphene have always been employed to increase the selectivity and sensitivity. Methods: An electrochemical sensor which has specific selectivity to (DA) was proposed based on the combination of a molecular imprinting polymer (MIP) with a graphene (GR) modified gold electrode. The performance and effect of MIP film were investigated by differential pulse voltammetry (DPV) and cyclic voltammetry (CV) in the solution of 5.0 ×10-3 mol/L K3[Fe(CN)6] and K4[Fe(CN)6] with 0.2 mol/L KCl at room temperature. Results: This fabricated sensor has well repeatability and stability, and was used to determine the dopamine of urine. Under the optimized experiment conditions, the current response of the imprinted sensor was linear to the concentration of dopamine in the range of 1.0×10-7 ~ 1.0×10-5 mol/L, the linear equation was I (µA) = 7.9824+2.7210lgc (mol/L) with the detection limit of 3.3×10-8 mol/L. Conclusion: In this work, a highly efficient sensor for determination of DA was prepared with good sensitivity by GR and great selectivity of high special recognization ability by molecular imprinting membrane. This proposed sensor was used to determine the dopamine in human urine successfully.

scholarly journals Applicability of Cork as Novel Modifiers to Develop Electrochemical Sensor for Caffeine Determination

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 37
Author(s):  
Mayra K. S. Monteiro ◽  
Djalma R. Da Silva ◽  
Marco A. Quiroz ◽  
Vítor J. P. Vilar ◽  
Carlos A. Martínez-Huitle ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Linear Response ◽  
High Performance ◽  
Low Cost ◽  
Pharmaceutical Formulations ◽  
Caffeine Concentration ◽  
Real Samples ◽  
Wide Range ◽  
Potential Use

This study aims to investigate the applicability of a hybrid electrochemical sensor composed of cork and graphite (Gr) for detecting caffeine in aqueous solutions. Raw cork (RAC) and regranulated cork (RGC, obtained by thermal treatment of RAC with steam at 380 °C) were tested as modifiers. The results clearly showed that the cork-graphite sensors, GrRAC and GrRGC, exhibited a linear response over a wide range of caffeine concentration (5–1000 µM), with R2 of 0.99 and 0.98, respectively. The limits of detection (LOD), estimated at 2.9 and 6.1 µM for GrRAC and GrRGC, suggest greater sensitivity and reproducibility than the unmodified conventional graphite sensor. The low-cost cork-graphite sensors were successfully applied in the determination of caffeine in soft drinks and pharmaceutical formulations, presenting well-defined current signals when analyzing real samples. When comparing electrochemical determinations and high performance liquid chromatography measurements, no significant differences were observed (mean accuracy 3.0%), highlighting the potential use of these sensors to determine caffeine in different samples.

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