The study covers coatings obtained on 40Kh steel substrates by electro-spark deposition (ESD) using TiC–NiCr and TiC–NiCr– Eu2O3 electrodes. Coatings were deposited by the Alier-Metal 303 unit in argon environment under the normal pressure using direct and opposite polarity. The structure, elemental and phase composition of electrodes and coatings were studied using X-ray phase analysis, scanning electron microscopy, energy dispersive spectroscopy, glow discharge optical emission spectroscopy, and optical profilometry. Mechanical and tribological properties of coatings were determined by nanoindentation and testing according to the «pin-disk» scheme including high-temperature conditions in the range of 20–500 °C. The tests conducted include abrasive wear tests using the Calowear tester, impact resistance tests using the CemeCon impact tester, and tests for gas and electrochemical corrosion resistance. Test results showed that electrodes contain titanium carbide, nickel-chromium solid solution, and europium oxide in case of a doped sample. Coatings exhibit the same phase composition but solid solution is formed on the iron base. Coatings with the Eu2O3 additive do not differ significantly in structural characteristics, hardness, friction coefficient, and exceed the base coatings in terms of their abrasive resistance, repeated impact resistance, heat and corrosion resistance. There was an increase in impact resistance by 1.2–2.0 times, a decrease in corrosion current by more than 20 times, and an oxidation index by almost 2 times during the transition to doped coatings.
Improving the microstructure and mechanical properties of laser cladded Ni-based alloy coatings by changing their composition: A review
