Formation of H2Ti2O5·H2O nanotube-based hybrid coating on bamboo fibre materials through layer-by-layer self-assembly method for an improved flame retardant performance

Cellulose ◽  
2019 ◽  
Vol 26 (4) ◽  
pp. 2729-2741
Author(s):  
Chenmin Zheng ◽  
Sili Wen ◽  
Ziling Teng ◽  
Chunlu Ye ◽  
Qiaoling Chen ◽  
...  
2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Chun Wei ◽  
Sihua Zeng ◽  
Yuyuan Tan ◽  
Wu Wang ◽  
Jian Lv ◽  
...  

The renewable cationic polyelectrolyte chitosan (CH) and anionic nanomontmorillonite (MMT) layers were alternately deposited on the surface of sisal fiber cellulose microcrystals (SFCM) via layer-by-layer (LBL) self-assembly method. The structure and properties of the composites were characterized by zeta potential, thermal gravimetric analysis (TGA), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectrometer (FTIR), microcalorimeter (MCC), and so forth. The zeta potential results show that the cellulose microcrystalline surface charge reversed due to the adsorption of CH and MMT nanoplatelets during multilayer deposition. MMT characteristic diffraction peaks appear in XRD patterns of SFCM(CH/MMT)5and SFCM(CH/MMT)10composites. Additionally, FESEM reveals that the SFCM(CH/MMT)10surface is covered with a layer of material containing Si, which has been verified by elemental analysis. TGA results show that the initial decomposition (weight loss of 5%) temperature of SFCM(CH/MMT)5is increased by 4°C compared to that of pure SFCM. On the other hand, carbon residue percentage of SFCM(CH/MMT)10is 25.1%, higher than that of pure SFCM (5.4%) by 19.7%. Eventually, it is testified by MCC measurement that CH/MMT coating can significantly reinforce the flame retardant performance of SFCM.


2008 ◽  
Vol 8 (6) ◽  
pp. 2996-3002 ◽  
Author(s):  
Liqin Ge ◽  
Xing Wang ◽  
Long Ba ◽  
Zhongze Gu

The hydrogen-bonding multilayered polyelectrolyte capsules with sizes around 6 μm were fabricated by layer-by-layer self-assembly method. The morphology of the obtained capsules was observed with Scanning Electron Microscope (SEM), Confocal Laser Scanning Microscope (CLSM) and Atomic Force Microscope (AFM), respectively. The elastic properties of the capsules were studied with AFM. The capsule was pressed by cantilever with different lengths, a glass bead glued at the end of the cantilever. The force curves were measured on the capsule in air. The Young's modulus of the capsule was obtained (E = 170 MPa for the loading). Results show that this model can predict the elastic deformation of the microcapsule. The accuracy of the elastic deformation of polymer capsule can be ensured using a cantilever of mediate stiffness. Our results show that the existence of the hydrogen-bonding layer makes the multilayered polyelectrolyte harder in comparison with the pure multilayered polyelectrolyte capsules.


RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 53625-53634 ◽  
Author(s):  
Ying Pan ◽  
Wei Wang ◽  
Haifeng Pan ◽  
Jing Zhan ◽  
Yuan Hu

Montmorillonite and titanate nanotube based coatings have been prepared through LbL self-assembly method, in order to enhance the thermal and thermal-oxidative stability, flame retardancy and UV protection of polyethylene terephthalate fabric.


2021 ◽  
Author(s):  
Xinhua Liu ◽  
Hailong Liu ◽  
Yinchun Fang

Abstract In this study, intumescent flame retardant coating of polyethylenimine/phytic acid (PEI/PA) with gradient structure was constructed on cotton fabric through facile layer-by-layer (LBL) assembly method. The LOI value of coated cotton fabric reached over 40% indicating excellent flame retardancy. Reasonable controlling the LBL assembly process of PEI/PA coating brought less influence to the physical properties of cotton fabrics. And the coated cotton fabric revealed good flame retardant washing durability. Thermogravimetric analysis results of coated cotton fabrics showed that PEI/PA flame retardant coating changed the thermal decomposition process and promoted char formation revealing the obviously condensed phase flame retardant action. SEM images of char residues revealed that PEI/PA flame retardant coating promoted to form the intumescent flame retardant (IFR) char layer showing obvious IFR action. This research provides novel strategy for the development of high-efficiency flame retardant cotton fabric with good durability and physical properties using simple LBL assembly method.


2017 ◽  
Vol 5 (31) ◽  
pp. 7746-7752 ◽  
Author(s):  
Xueliang Ye ◽  
Zhen Yuan ◽  
Huiling Tai ◽  
Weizhi Li ◽  
Xiaosong Du ◽  
...  

A novel strain sensor based on reduced graphene oxide with ultra-sensitive and ultra-durable performance was fabricated by the chemical layer-by-layer self-assembly method.


2020 ◽  
Vol 134 ◽  
pp. 140-148 ◽  
Author(s):  
Eduarda Freitas Diogo Januário ◽  
Natália de Camargo Lima Beluci ◽  
Taynara Basso Vidovix ◽  
Marcelo Fernandes Vieira ◽  
Rosângela Bergamasco ◽  
...  

2019 ◽  
Vol 7 (32) ◽  
pp. 4963-4972 ◽  
Author(s):  
Xiao-yan Xu ◽  
Yan-fang Chen ◽  
Qing-gang Tan ◽  
Zhi-jie Chen ◽  
Yan Li ◽  
...  

An antibacterial and antitumor coating for non-vascular stent was constructed via the layer-by-layer electrostatic self-assembly method.


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