Novel kinetics model for the crosslinking reaction of 1,2,3,4-butanetetracarboxylic acid with cellulose within cotton fabrics

Cellulose ◽  
2021 ◽  
Author(s):  
Hanchang Hu ◽  
Haoyang Xu ◽  
Xia Dong ◽  
Qiangqiang Zhao ◽  
Rongliang Wu ◽  
...  
Keyword(s):  
Cotton Fabrics ◽  
Kinetics Model ◽  
Crosslinking Reaction ◽  
Butanetetracarboxylic Acid

scholarly journals Improving the Dyeability and Anti-Wrinkle Properties of Cotton Fabric via Oxidized Raffinose

2021 ◽  
Vol 11 (10) ◽  
pp. 4641
Author(s):  
Jiangfei Lou ◽  
Jinfang Zhang ◽  
Dan Wang ◽  
Xuerong Fan
Keyword(s):  
Catalyst Concentration ◽  
Structural Characteristics ◽  
Cotton Fabrics ◽  
Difficult Problem ◽  
Curing Temperature ◽  
Dyeing Performance ◽  
Finishing Process ◽  
Combined Mechanism ◽  
Recovery Angle ◽  
Butanetetracarboxylic Acid

In the anti-wrinkle finishing of cotton fabrics, the decreased dyeability of the finished fabrics has always been a difficult problem. A new anti-wrinkle finishing mode was developed to solve this problem by changing the finishing sequence of fabric dyeing and anti-wrinkle. In this research, the partial oxidization of raffinose with sodium periodate generated multiple aldehydes, which acted as multifunctional cross-linkers and endowed cotton fabrics with anti-wrinkle and hydrophilic properties. The structural characteristics of oxyRa were analyzed by FTIR and 13C-NMR. Through response surface methodology (RSM), the finishing model of oxyRa was established from the influencing factors of catalyst concentration, pH, curing temperature and time, and the optimized finishing process: the catalyst concentration was 20.12 g/L, pH was 4.32, curing temperature was 150 °C and curing time was 120 s. Under this condition, the predicted wrinkle recovery angle (WRA) of the finished fabric was up to 249.76°, Tensile strength (TS) was 75.62%, Whiteness index (WI) was 70.69. Importantly, comparing the anti-wrinkle and dyeing performance of the fabric with anti-wrinkle and then dyeing and anti-wrinkle after dyeing, the oxyRa-treated fabrics showed better dyeing properties compared with previously reported dimethyldihydroxyethylene urea (DMDHEU), glutaraldehyde (GA), and 1,2,3,4-butanetetracarboxylic acid (BTCA). Analysis of the combined mechanism of different finishing agents and cellulose, demonstrated the reason why oxyRa can be used to change the order of dyeing and anti-wrinkle finishing.

Anti-ultraviolet properties of β-cyclodextrin-grafted cotton fabrics dyed by broadleaf holly leaf extract

2020 ◽  
Vol 90 (21-22) ◽  
pp. 2441-2453 ◽  
Author(s):  
Jinshu Liu ◽  
Xiaoyan Ma ◽  
Wenzhao Shi ◽  
Jianwei Xing ◽  
Chaoqun Ma ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Leaf Extract ◽  
Cotton Fabrics ◽  
Sodium Hypophosphite ◽  
Crosslinking Reaction ◽  
Ultraviolet Spectrophotometry ◽  
Protection Factor ◽  
Ultraviolet Protection Factor ◽  
Ultraviolet Protection ◽  
Macerated Extract

The aim of the study was to investigate the anti-ultraviolet properties of β-cyclodextrin-grafted cotton fabrics dyed with broadleaf holly leaf extract. Flavonoids were extracted from broadleaf holly leaf by maceration and a stoichiometry of 1:1 inclusion complex with β-cyclodextrin was formed. Characterized by the fluorescence spectrum and ultraviolet spectrophotometry, the fluorescence intensities and ultraviolet absorption of the macerated extract were enhanced by increasing the amount of cyclodextrin. Cotton fabrics were grafted with β-cyclodextrin through a crosslinking reaction based on citric acid in the presence of sodium hypophosphite then dyed with the macerated extract of broadleaf holly leaf used as a natural ultraviolet absorbent. The anti-ultraviolet property of fabrics dyed by a macerated extract was characterized in terms of the ultraviolet protection factor. It was noted that the cotton fabrics grafted with β-cyclodextrin exhibit enhanced anti-ultraviolet and wrinkle recovery properties compared to the unmodified samples and show an excellent durability against 30 washing cycles, accompanied by a loss of tensile strength.

Effects of butanetetracarboxylic acid and chitosan on the properties of formaldehyde free finish for cotton fabrics

Polimery ◽  
2005 ◽  
Vol 50 (06) ◽  
pp. 463-467
Author(s):  
ZYGMUNT HEHN ◽  
ANDRZEJ GAWDZIK ◽  
JOLANTA SAJEWICZ
Keyword(s):  
Cotton Fabrics ◽  
Butanetetracarboxylic Acid

SURFACE TREATMENT OF ANTI-CREASE FINISHED COTTON FABRIC BASED ON SOL–GEL TECHNOLOGY

2009 ◽  
Vol 16 (05) ◽  
pp. 715-721 ◽  
Author(s):  
CHAOXIA WANG ◽  
LI CHEN
Keyword(s):  
Tensile Strength ◽  
Physical Properties ◽  
Cotton Fabric ◽  
Coupling Agent ◽  
Abrasion Resistance ◽  
Sol Gel ◽  
Cotton Fabrics ◽  
Silica Sol ◽  
Recovery Angle ◽  
Butanetetracarboxylic Acid

The silica sol was applied onto 1, 2, 3, 4-butanetetracarboxylic acid (BTCA) finished cotton fabrics with the attempt to improve the physical properties especially the tensile strength which had a big loss in the previous anti-crease finishing processing. The parameters including the dosage of the coupling agent, the concentration and pH of the sol and the processing methods were studied in detail. Compared to the sample finished with BTCA, 11.8% of the increase in the crease recovery angle and 18.6% of the enhancement in the tensile strength of the cotton fabric also treated with silica sol in the better selected conditions were obtained. The abrasion resistance was also improved.

scholarly journals Synthesis of a phosphoramidate flame retardant and its flame retardancy on cotton fabrics

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 550-560
Author(s):  
Huaifang Wang ◽  
Yingli Cai ◽  
Zhiming Jiang ◽  
Shengnan Guo ◽  
Ping Zhu
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Cotton Fabrics ◽  
Limiting Oxygen Index ◽  
Flammability Test ◽  
Peak Heat Release Rate ◽  
Structure Surface ◽  
Ft Ir ◽  
Butanetetracarboxylic Acid

AbstractA phosphoramidate flame retardant (dimethyl N,N-bis(2-hydroxyletheyl)phosphoramidate, DMBHP) was synthesized and applied to cotton fabrics for enhancing the flame retardancy. The structure of DMBHP was characterized by FT-IR and NMR. The flame retardancy and combustion behavior of the treated cotton fabrics were evaluated using the vertical flammability test (VFT), limiting oxygen index (LOI), and the cone calorimetric test. Moreover, to further analyze the flame retardant action of DMBHP in cotton fabrics, thermal degradability of the treated fabrics, as well as the chemical structure, surface morphology, and element contents of the char residue of the DMBHP-treated fabrics were also evaluated. The results show that, after treating with DMBHP, the cotton fabrics acquired a LOI value from 18.1 to 31.1 with the concentration increasing to 30% and self-extinguished in VFT tests when treated with up to 15% DMBHP. Besides, the total heat release and the peak heat release rate of DMBHP (30%)-treated fabric decreased obviously compared with the pure cotton along with more residue retained. TG, SEM, and EDS results of treated cotton fabric and the corresponding residue after burning showed that DMBHP has the capability of enhancing char formation. In addition, DMBHP will confer cotton fabrics a certain durability against washing with the help of 1,2,3,4-butanetetracarboxylic acid (BTCA) and citric acid (CA).

Crosslinking formulations based on novel reactive disperse dyes for printing cotton fabrics

2016 ◽  
Vol 87 (17) ◽  
pp. 2127-2132 ◽  
Author(s):  
Min Li ◽  
Aiqin Gao ◽  
Lingshuang Wu ◽  
Danna Fu ◽  
Kongliang Xie
Keyword(s):  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Cotton Fabrics ◽  
Hydroxyl Group ◽  
Disperse Dyes ◽  
Natural Material ◽  
Resonance Spectroscopy ◽  
Crosslinking Reaction ◽  
Light Fastness ◽  
Element Analysis

Cotton cellulose is an excellent natural material due to its outstanding characters. Five novel crosslinking reactive disperse dyes containing bi-functional groups, two 3-chloro-2-hydroxypropyl groups, were synthesized and characterized by infrared spectroscopy, proton magnetic resonance spectroscopy and element analysis. The solvent effect on the color of the dyes was assessed by the electronic absorption spectra. The crosslinking printing properties of the five dyes (D1–5) for cotton fabrics were investigated. The electronic absorption property exhibited larger bathochromic shifts in a stronger polar solvent than in the weaker polar solvents. The crosslinking reaction between two 3-chloro-2-hydroxypropylreactive groups and the hydroxyl group of cellulose could take place. The higher color yield and excellent fixation were obtained. The building up property was good for all the dyes on cotton fabric. The printed samples had excellent washing, perspiration and rubbing fastness. The light fastness for cotton fabrics was moderate.

scholarly journals A comparison between acrilic resin and butanetetracarboxylic acid used to bind TiO2 nanoparticles to cotton fabrics

Cellulose ◽  
2015 ◽  
Vol 22 (2) ◽  
pp. 1347-1354 ◽  
Author(s):  
M. Bonet ◽  
E. Bou-Belda ◽  
P. Monllor ◽  
J. Gisbert ◽  
P. Díaz ◽  
...  
Keyword(s):  
Tio2 Nanoparticles ◽  
Cotton Fabrics ◽  
Butanetetracarboxylic Acid

The Temperature Dependence of the Rate of Crosslinking with Formaldehyde and of the Hydrolysis of Cotton Cellulose

1976 ◽  
Vol 46 (12) ◽  
pp. 880-886 ◽  
Author(s):  
U. Meyer ◽  
K. Müller ◽  
H. Zollinger
Keyword(s):  
Aqueous Solution ◽  
Cotton Fabrics ◽  
Crosslinking Reaction ◽  
Reaction Enthalpy ◽  
Cure Process ◽  
Kinetic Measurements ◽  
Apparent Activation Energies ◽  
Recovery Angle ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of the crosslinking of cotton fabrics in aqueous solution with formaldehyde using hydrochloric acid as catalyst, and the acid degradation (hydrolysis) of cotton were measured simultaneously at 67.4°C, 77.6°C, and 87.0°C. Some related kinetic measurements of these two reactions were also carried out with the pad-dry-cure process, catalyzed by MgCl2, at 140°C, 160°C, and 180°C. The apparent activation energies of crosslinking and hydrolysis were calculated. They are discussed with reference to the improvement in the dry crease-recovery angle/tensile strength relation at lower reaction temperatures. For the reaction in aqueous solution the rate of degradation of the accessible as well as the highly-ordered fractions of cellulose were determined. Finally, the apparent reaction enthalpy of the crosslinking reaction was estimated.

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