Influence of TiO2 conjunct with different g–C3N4 mass ratios on photocatalytic activity: visible and UV degradation of organic pollutant

Author(s):  
Yinying Jiang ◽  
Yizheng Wang ◽  
Kuan Zhou ◽  
Senxu Ding ◽  
Jiang Yu
RSC Advances ◽  
2015 ◽  
Vol 5 (87) ◽  
pp. 71035-71045 ◽  
Author(s):  
Shuquan Huang ◽  
Yuanguo Xu ◽  
Zhigang Chen ◽  
Meng Xie ◽  
Hui Xu ◽  
...  

A core–shell structured Ag/AgBr@Fe2O3 composite was prepared successfully. It has magnetic properties, highly efficient photocatalytic activity and antibacterial ability.


Chemosphere ◽  
2021 ◽  
pp. 131848
Author(s):  
Bablu Basumatary ◽  
Rajmoni Basumatary ◽  
Anjalu Ramchiary ◽  
Dimpul Konwar

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 437 ◽  
Author(s):  
Zhiming Sun ◽  
Fang Yuan ◽  
Xue Li ◽  
Chunquan Li ◽  
Jie Xu ◽  
...  

A novel kind of cyanuric-acid-modified graphitic carbon nitride (g-C3N4)/kaolinite (m-CN/KA) composite with enhanced visible light-driven photocatalytic performance was fabricated through a facile two-step process. Rhodamine B (RhB) was taken as the target pollutant to study the photocatalytic performance of the synthesized catalysts. It is indicated that the cyanuric acid modification significantly enhanced photocatalytic activity under visible light illumination in comparison with the other reference samples. The apparent rate constant of m-CN/KA is almost 1.9 times and 4.0 times those of g-C3N4/kaolinite and bare g-C3N4, respectively. The superior photocatalytic performance of m-CN/KA could be ascribed, not only to the generation of abundant pore structure and reactive sites, but also to the efficient separation of the photogenerated electron-hole pairs. Furthermore, the possible photocatalytic degradation mechanism of m-CN/KA was also presented in this paper. It could be anticipated that this novel and efficient, metal-free, mineral-based photocatalytic composite has great application prospects in organic pollutant degradation.


NANO ◽  
2016 ◽  
Vol 11 (05) ◽  
pp. 1650054 ◽  
Author(s):  
Bin Zeng ◽  
Yang Yin

CuS hexagonal nanosheet/graphene was fabricated by a facile one-pot microwave-thermal method. The samples possess excellent photocatalytic activity for degradation of organic pollutant under visible light. The high photocatalytic activity was attributed to the deposition of CuS hexagonal nanosheet onto graphene. CuS nanosheet serves as a transporter which efficiently inhibits the recombination of the photo-induced charge carriers in the nanocomposites. The developed method demonstrates a facile approach towards the synthesis of two-dimensional semiconductor-graphene nanocomposites with excellent photocatalytic performance under visible light.


Author(s):  
Nguyen Quang Long

For a few decades, Titanium Dioxide (TiO2) has been the most studied photocatalyst due to its significant optical property. In the paper, TiO2 pigment powder (Anatase form) was selected as a precursor to prepare a variety of Black-TiO2 samples, and the typical material was then evaluated for its photocatalytic activity in organic pollutant treatment. Some properties of Black-TiO2 were determined via common methods such as sensory analysis, X-Ray diffraction, and bandgap measurement obtained from UV-Vis spectroscopy. As a result, the material was successfully converted to more than 40% organic pollutant as Methyl Orange (C14H14N3NaO3S) for an hour, as two times higher than that of the amount converted by pristine TiO2. In addition, Black-TiO2 performed much better photocatalytic activity in an acidic medium in comparison with a neutral one, and the material also remained its activity as more than 90% after three time-continuous recycling operations.


Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1873
Author(s):  
Petronela Pascariu ◽  
Niculae Olaru ◽  
Aurelian Rotaru ◽  
Anton Airinei

A new type of material based on carbon/ZnO nanostructures that possesses both adsorption and photocatalytic properties was obtained in three stages: cellulose acetate butyrate (CAB) microfiber mats prepared by the electrospinning method, ZnO nanostructures growth by dipping and hydrothermal methods, and finally thermal calcination at 600 °C in N2 for 30 min. X-ray diffraction (XRD) confirmed the structural characteristics. It was found that ZnO possesses a hexagonal wurtzite crystalline structure. The ZnO nanocrystals with star-like and nanorod shapes were evidenced by scanning electron microscopy (SEM) measurements. A significant decrease in Eg value was found for carbon/ZnO hybrid materials (2.51 eV) as compared to ZnO nanostructures (3.21 eV). The photocatalytic activity was evaluated by studying the degradation of three dyes, Methylene Blue (MB), Rhodamine B (RhB) and Congo Red (CR) under visible-light irradiation. Therefore, the maximum color removal efficiency (both adsorption and photocatalytic processes) was: 97.97% of MB (C0 = 10 mg/L), 98.34% of RhB (C0 = 5 mg/L), and 91.93% of CR (C0 = 10 mg/L). Moreover, the value of the rate constant (k) was found to be 0.29 × 10−2 min−1. The novelty of this study relies on obtaining new photocatalysts based on carbon/ZnO using cheap and accessible raw materials, and low-cost preparation techniques.


RSC Advances ◽  
2020 ◽  
Vol 10 (23) ◽  
pp. 13722-13731 ◽  
Author(s):  
Satish Kasturi ◽  
Sri Ramulu Torati ◽  
Yun Ji Eom ◽  
Syafiq Ahmad ◽  
Byong-June Lee ◽  
...  

Herein, we have reported the real-time photodegradation of methylene blue, an organic pollutant, in the presence of sunlight at an ambient temperature using a platinum-decorated reduced graphene oxide (rGO/Pt) nanocomposite.


2019 ◽  
Vol 7 (18) ◽  
pp. 11408-11422 ◽  
Author(s):  
Ali Reza Amani-Ghadim ◽  
Fatemeh Khodam ◽  
Mir Saeed Seyed Dorraji

MIIZnAl-LDH/ZnS QD (MII = Co or Mn) nanocomposites were synthesized by assembling oppositely charged 2D LDH layers and ZnS QDs. The MIIZnAl-LDH/ZnS QDs exhibited enhanced visible light harvesting ability, considerable visible light photocatalytic activity and photostability.


2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Karina Bustos-Ramirez ◽  
Carlos Eduardo Barrera-Diaz ◽  
Miguel De Icaza ◽  
Ana Laura Martínez-Hernández ◽  
Carlos Velasco-Santos

Developing new materials or modifying the existing ones is an amply field studied in the world of research. Due to its outstanding physical and chemical properties, graphene is attractive material for new applications. The methodologies for obtaining graphene are diverse and have changed over time. Graphene oxide is a versatile form of graphene, due to the presence of oxygenated functional groups. Chemical oxidation of graphite and exfoliation by ultrasonic waves is one of the preferred methods to obtain graphene oxide; chemical oxidation time and the degassing effect in the ultrasonic bath are parameters that play an important role in the features and properties of graphene oxide. Thus, in this study, the conventional times used for the oxidation of graphite and degassing in an ultrasonic bath to obtain graphene oxide were modified. The structural changes in the carbon materials were evaluated based on their photocatalytic activity in the removal of an organic pollutant in water (removing up to 38% of phenol). The band gaps of the graphitic materials were obtained by UV-vis obtaining a value range of 1.5–4.7 eV and the structure and morphology of the carbon materials were characterized by infrared and Raman spectroscopies and transmission electron microscopy, respectively.


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