scholarly journals Sol?Gel Derived Organic and Inorganic Hybrid Materials for Photonic Applications: Contribution to the Correlation Between the Material Structure and the Transmission in the Near Infrared Region

2005 ◽  
Vol 33 (2) ◽  
pp. 241-248 ◽  
Author(s):  
M. Oubaha ◽  
P. Etienne ◽  
S. Calas ◽  
P. Coudray ◽  
J. M. Nedelec ◽  
...  
Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1964
Author(s):  
Yanxin Wang ◽  
Qiuyu Sun ◽  
Linjun Huang ◽  
Peng Lu ◽  
Xiaozhen Wang ◽  
...  

Tm3+ has obvious emission characteristics in the near-infrared band. Thulium ions combined with different organic ligands lead to different fluorescent properties. In the near-infrared region, Tm3+ is a down-conversion fluorescent material that is unstable under high temperature and acidic conditions. Moreover, in those complex environments, the fluorescence from Tm3+ complex is usually degraded. In this work, two kinds of near-infrared fluorescent complexes, Tm(TTA)3phen and Tm(DBM)3phen, were prepared, and the intensity of their fluorescence is compared. The fluorescence intensity at 802 nm is greatly improved compared with Tm(TTA)3phen, and the intensity of the emission at 1235 nm and 1400–1500 nm is also enhanced. Moreover, the emission lifetime of SiO2-Tm(TTA)3phen is 50.38 μs. Tm(TTA)3phen complex and SiO2-Tm(TTA)3phen hybrid materials have better fluorescence than Tm(DBM)3phen and SiO2-Tm(DBM)3phen. Therefore, HTTA is a better choice of organic ligands for Tm3+. The NIR-fluorescent hybrid materials prepared have stronger fluorescence after combining with nano-SiO2compared with pure Tm3+ complexes, and have stronger structural stability compared with pure nano-SiO2.


2000 ◽  
Vol 628 ◽  
Author(s):  
Guang-Way Jang ◽  
Ren-Jye Wu ◽  
Yuung-Ching Sheen ◽  
Ya-Hui Lin ◽  
Chi-Jung Chang

This work successfully prepared an UV curable organic-inorganic hybrid material consisting of organic modified colloidal silica. Applications of UV curable organic-inorganic hybrid materials include abrasion resistant coatings, photo-patternable thin films and waveguides. Colloidal silica containing reactive functional groups were also prepared by reacting organic silane and tetraethyl orthosilicate (TEOS) using sol-gel process. In addition, the efficiency of grafting organic moiety onto silica nanoparticles was investigated by applying TGA and FTIR techniques. Experimental results indicated a strong interdependence between surface modification efficiency and solution pH. Acrylate-SiO2 hybrid formation could result in a shifting of thermal degradation temperature of organic component from about 200°C to near 400°C. In addition, the stability of organic modified colloidal silica in UV curable formula and the physical properties of resulting coatings were discussed. Furthermore, the morphology of organic modified colloidal silica was investigated by performing TEM and SEM studies‥


2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...


Author(s):  
Cong Shen ◽  
Yan Qing Zhu ◽  
Zixiao Li ◽  
Jingling Li ◽  
Hong Tao ◽  
...  

InP quantum dots (QDs) are considered as the most promising alternative to Cd-based QDs with the lower toxicity and emission spectrum tunability ranging from visible to near-infrared region. Although high-quality...


LWT ◽  
2021 ◽  
Vol 143 ◽  
pp. 111092
Author(s):  
Jose Marcelino S. Netto ◽  
Fernanda A. Honorato ◽  
Patrícia M. Azoubel ◽  
Louise E. Kurozawa ◽  
Douglas F. Barbin

Nanoscale ◽  
2020 ◽  
Vol 12 (41) ◽  
pp. 21459-21459
Author(s):  
Charlotte Marshall

Retraction of ‘Water-soluble multidentate polymers compactly coating Ag2S quantum dots with minimized hydrodynamic size and bright emission tunable from red to second near-infrared region’ by Rijun Gui et al., Nanoscale, 2014, 6, 5467–5473, DOI: 10.1039/C4NR00282B.


2019 ◽  
Vol 10 (25) ◽  
pp. 6330-6335 ◽  
Author(s):  
Jinhu Wang ◽  
Yinhua Yang ◽  
Hua Li ◽  
Jun Gao ◽  
Ping He ◽  
...  

Preparation of color-tunable and stable plasmonic MoO3 nanomaterials remains challenging, due to the lack of an effective preparation strategy and surface protection in heavily doped MoO3.


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