The effect of melt flow index, melt flow rate, and particle size on the thermal degradation of commercial high density polyethylene powder

2013 ◽  
Vol 114 (3) ◽  
pp. 1333-1339 ◽  
Author(s):  
Mehrdad Seifali Abbas-Abadi ◽  
Mehdi Nekoomanesh Haghighi ◽  
Hamid Yeganeh ◽  
Babak Bozorgi
Keyword(s):  
Particle Size ◽  
Thermal Degradation ◽  
Flow Rate ◽  
High Density Polyethylene ◽  
Melt Flow Index ◽  
High Density ◽  
Flow Index ◽  
Melt Flow ◽  
Melt Flow Rate ◽  
Polyethylene Powder

Effect of the melt flow index and melt flow rate on the thermal degradation kinetics of commercial polyolefins

2012 ◽  
Vol 126 (5) ◽  
pp. 1739-1745 ◽  
Author(s):  
Mehrdad Seifali Abbas-Abadi ◽  
Mehdi Nekoomanesh Haghighi ◽  
Hamid Yeganeh
Keyword(s):  
Thermal Degradation ◽  
Flow Rate ◽  
Degradation Kinetics ◽  
Melt Flow Index ◽  
Thermal Degradation Kinetics ◽  
Flow Index ◽  
Melt Flow ◽  
Melt Flow Rate ◽  
Kinetics Of

scholarly journals Effect of Ground Tire Rubber (GTR) Particle Size and Content on the Morphological and Mechanical Properties of Recycled High-Density Polyethylene (rHDPE)/GTR Blends

Recycling ◽  
2021 ◽  
Vol 6 (3) ◽  
pp. 44
Author(s):  
Ali Fazli ◽  
Denis Rodrigue
Keyword(s):  
Particle Size ◽  
Thermal Properties ◽  
High Density Polyethylene ◽  
Thermoplastic Elastomer ◽  
Melt Flow Index ◽  
Mechanical Analysis ◽  
Particle Dispersion ◽  
High Density ◽  
Flow Index ◽  
The Matrix

This work investigates the effect of ground rubber tire (GRT) particle size and their concentration on the morphological, mechanical, physical, and thermal properties of thermoplastic elastomer (TPE) blends based on recycled high-density polyethylene (rHDPE). In our methodology, samples are prepared via melt blending (twin-screw extrusion followed by compression molding) to prepare different series of blends using GTR with three different particle sizes (0–250 μm, 250–500 μm, and 500–850 μm) for different GTR concentrations (0, 20, 35, 50, and 65 wt.%). The thermal properties are characterized by differential scanning calorimeter (DSC), and the morphology of the blends is studied by scanning electron microscopy (SEM). The mechanical and physical properties of the blends are investigated by quasi-static tensile and flexural tests, combined with impact strength and dynamic mechanical analysis (DMA). The SEM observations indicate some incompatibility and inhomogeneity in the blends, due to low interfacial adhesion between rHDPE and GTR (especially for GTR > 50 wt.%). Increasing the GTR content up to 65 wt.% leads to poor interphase (high interfacial tension) and agglomeration, resulting in the formation of voids around GTR particles and increasing defects/cracks in the matrix. However, introducing fine GTR particles (0–250 μm) with higher specific surface area leads to a more homogenous structure and uniform particle dispersion, due to improved physical/interfacial interactions. The results also show that for a fixed composition, smaller GTR particles (0–250 μm) gives lower melt flow index (MFI), but higher tensile strength/modulus/elongation at break and toughness compared to larger GTR particles (250–500 μm and 500–850 μm).

Effects of fluoropolymer and calcium stearate on melt flow index and mechanical properties of high-density polyethylene

2018 ◽  
Author(s):  
Mohamad Zaki Abdullah ◽  
Jad Safwan Jemsee ◽  
Muhammad Shazwan Mahmud ◽  
Hamdan Ya
Keyword(s):  
Mechanical Properties ◽  
High Density Polyethylene ◽  
Melt Flow Index ◽  
High Density ◽  
Calcium Stearate ◽  
Flow Index ◽  
Melt Flow

Effect of Powder Properties such as Particle Size, Density and Melt Flow Rate on the Properties of Flame Sprayed PE Coating

2000 ◽  
Author(s):  
E. Rajamäki ◽  
M. Leino ◽  
P. Vuoristo ◽  
P. Järvelä ◽  
T. Mäntylä
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Flow Rate ◽  
Heating Temperature ◽  
Steel Substrate ◽  
Great Influence ◽  
Hot Water ◽  
Melt Flow ◽  
Melt Flow Rate ◽  
Powder Properties

Abstract Three different types of polyethylene powders were flame sprayed onto pre-heated steel substrate previously coated by electrostatic spray system with a thin epoxy primer layer. Properties of the polyethylene (PE) powders, including powder density, particle size and melt flow rate (MFR) were measured in order to study their influence on the mechanical properties of the coating. The spray experiments started with optimization of spraying parameters. The main variables were pre-heating temperature of the substrate, temperature increase during spraying (influenced by the spraying distance), and thickness of the PE coatings. The laboratory tests performed for the coatings were coating characterization by microscopy and mechanical testing. Porosity and thickness of the coatings were determined by optical and stereo microscopy studies from polished cross-sectional samples. Hardness, impact strength, peel strength, and adhesive strength of the coatings were also investigated. Also some hot water sinking and heat cycling tests were performed. As a result from the present studies it can be concluded that powder properties have great influence on the mechanical properties of the final coating.

Thermal and Thermorheologic Characterization of Different Polyolefin Waste Fractions

2017 ◽  
Vol 907 ◽  
pp. 74-79
Author(s):  
Adela Lazar ◽  
Catalin Croitoru ◽  
Mircea Horia Tierean ◽  
Liana Sanda Baltes
Keyword(s):  
Molecular Mass ◽  
High Density Polyethylene ◽  
Melt Flow Index ◽  
Household Waste ◽  
Flow Index ◽  
Melt Flow ◽  
Polymer Waste ◽  
Lower Molecular Mass ◽  
Low Shear

In this study, melt flow index values from several household waste fractions containing mainly polypropylene and high-density polyethylene, were measured at 190 °C for polyethylene and 230 °C for polypropylene-rich fractions. High values of MFI (low shear viscosities) have been reported probably due to the lower molecular mass of the polymer waste and/or the presence of surfactant compounds on the surface of the polymer flakes. Also, by extruding the same batch in different cycles at the same temperature values, the number of processing cycles on which the polymer could be recycled has been determined.

PREDICTING THE FLOW PROPERTIES OF POLYAMIDE NANOCOMPOSITES BY USING VINOGRADOV-MALKIN MODEL

2015 ◽  
Vol 9 (3) ◽  
pp. 2446-2452
Author(s):  
Tomasz Mariusz Majka ◽  
Marcin Majka ◽  
Muhammad Kamrul Hasan
Keyword(s):  
Shear Rate ◽  
Flow Direction ◽  
Polymeric Materials ◽  
Melt Flow Index ◽  
Polyamide 6 ◽  
Flow Index ◽  
Melt Flow ◽  
Melt Flow Rate ◽  
Shear Rates ◽  
Different Temperatures

This article reports the prediction of the theoretical flow curves of polyamide composites by using Vinogradov-Malkin model. Determination of the melt flow index of polymeric materials is the first step to study viscosity-shear rate relationship. The viscosity of the composites at different temperatures were calculated by using the Williams, Landel'a and Ferry (WLF) equation. Other important rheological characteristics were calculated by using appropriate equations. One point method is employed to correlate the changes in viscosity with temperatures. As expected, it is found that incorporation of nanoclay to polyamide 6 (PA6) significantly decreases the Melt Flow Rate of the composites and hence, increases density. Addition of stabilizer further increases density of the PA6/nanoclay composites. The simulations of viscosity curves for PA6 composites were carried out at measurement temperature, 240°C and in the range of 180°C - 350°C with shear rate of 10-1 – 103 1/s. It is found that addition of nanoclay and stabilizer to PA6 decreases viscosity of the composites in the order of PA6/OMMT > PA6 > PA6/I1098 > PA6/OMMT/I1098 > PA6/MMT/I1098 > PA6/MMT. At higher shear rates, viscosity decreases in the same sequence as low shear rates. At further higher shear rates (> 1000 1/s), filler particles are arranged in the flow direction thus exerting no significant effect on viscosity of composites both with and without the stabilizer. During injection moulding in the shear rate ranging from 101 – 104 1/s at 240°C temperature, it is evident that viscosity decreases drastically with increase in shear rate.

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